PMID- 34771914 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20211118 IS - 1996-1944 (Print) IS - 1996-1944 (Electronic) IS - 1996-1944 (Linking) VI - 14 IP - 21 DP - 2021 Oct 25 TI - Muntingia calabura Leaves Mediated Green Synthesis of CuO Nanorods: Exploiting Phytochemicals for Unique Morphology. LID - 10.3390/ma14216379 [doi] LID - 6379 AB - In this study, phytochemical assisted nanoparticle synthesis was performed using Muntingia calabura leaf extracts to produce copper oxide nanoparticles (CuO NPs) with interesting morphology. Scanning electron microscope (SEM) and transmission electron microscope (TEM) analysis of the biosynthesized CuO NPs reveal formation of distinct, homogeneous, and uniform sized CuO nanorods structure with thickness and length of around 23 nm and 79 nm, respectively. Based on Fourier-transform infrared (FTIR) analysis, the unique combinations of secondary metabolites such as flavonoid and polyphenols in the plant extract are deduced to be effective capping agents to produce nanoparticles with unique morphologies similar to conventional chemical synthesis. X-ray diffraction (XRD) analysis verified the monoclinical, crystalline structure of the CuO NPs. The phase purity and chemical identity of the product was consolidated via X-Ray photoelectron spectroscopy (XPS) and Raman spectroscopic data which indicate the formation of a single phase CuO without the presence of other impurities. The direct and indirect optical band gap energies of the CuO nanorods were recorded to be 3.65 eV and 1.42 eV. FAU - Selvanathan, Vidhya AU - Selvanathan V AD - Solar Energy Research Institute (SERI), Universiti Kebangsaan Malaysia (UKM), Bangi 43600, Malaysia. FAU - Aminuzzaman, Mohammod AU - Aminuzzaman M AD - Department of Chemical Science, Faculty of Science, Universiti Tunku Abdul Rahman (UTAR), Perak Campus, Jalan Universiti, Bandar Barat, Kampar 31900, Malaysia. AD - Centre for Photonics and Advanced Materials Research (CPAMR), Universiti Tunku Abdul Rahman (UTAR), Jalan Sungai Long, Bandar Sungai Long, Kajang 43000, Malaysia. FAU - Tey, Lai-Hock AU - Tey LH AUID- ORCID: 0000-0001-8669-1479 AD - Department of Chemical Science, Faculty of Science, Universiti Tunku Abdul Rahman (UTAR), Perak Campus, Jalan Universiti, Bandar Barat, Kampar 31900, Malaysia. FAU - Razali, Syaza Amira AU - Razali SA AD - Solar Energy Research Institute (SERI), Universiti Kebangsaan Malaysia (UKM), Bangi 43600, Malaysia. FAU - Althubeiti, Khaled AU - Althubeiti K AD - Department of Chemistry, College of Science, Taif University, P.O. Box 11099, Taif 21944, Saudi Arabia. FAU - Alkhammash, Hend Ibraheem AU - Alkhammash HI AD - Department of Electrical Engineering, College of Engineering, Taif University, Taif 21944, Saudi Arabia. FAU - Guha, Samar Kumar AU - Guha SK AUID- ORCID: 0000-0001-5063-1300 AD - Department of Arts and Sciences, Faculty of Engineering, Ahsanullah University of Science and Technology, 141-142, Love Road, Tejgaon I/A, Dhaka 1208, Bangladesh. FAU - Ogawa, Sayaka AU - Ogawa S AD - Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, Sendai 980-8577, Japan. FAU - Watanabe, Akira AU - Watanabe A AD - Institute of Multidisciplinary Research for Advanced Materials (IMRAM), Tohoku University, Sendai 980-8577, Japan. FAU - Shahiduzzaman, Md AU - Shahiduzzaman M AUID- ORCID: 0000-0002-3092-7793 AD - Nanomaterials Research Institute (NanoMaRi), Kanazawa University, Kakuma, Kanazawa 920-1192, Japan. FAU - Akhtaruzzaman, Md AU - Akhtaruzzaman M AUID- ORCID: 0000-0002-7891-6321 AD - Solar Energy Research Institute (SERI), Universiti Kebangsaan Malaysia (UKM), Bangi 43600, Malaysia. LA - eng GR - Modal Insan Fellowship/Universiti Kebangsaan Malaysia/ GR - TURSP-2020/241/Taif University/ PT - Journal Article DEP - 20211025 PL - Switzerland TA - Materials (Basel) JT - Materials (Basel, Switzerland) JID - 101555929 PMC - PMC8585435 OTO - NOTNLM OT - Muntingia calabura OT - copper oxide OT - green synthesis OT - nanorods COIS- The authors declare no conflict of interest. EDAT- 2021/11/14 06:00 MHDA- 2021/11/14 06:01 PMCR- 2021/10/25 CRDT- 2021/11/13 01:16 PHST- 2021/08/21 00:00 [received] PHST- 2021/10/03 00:00 [revised] PHST- 2021/10/11 00:00 [accepted] PHST- 2021/11/13 01:16 [entrez] PHST- 2021/11/14 06:00 [pubmed] PHST- 2021/11/14 06:01 [medline] PHST- 2021/10/25 00:00 [pmc-release] AID - ma14216379 [pii] AID - materials-14-06379 [pii] AID - 10.3390/ma14216379 [doi] PST - epublish SO - Materials (Basel). 2021 Oct 25;14(21):6379. doi: 10.3390/ma14216379.