PMID- 34797060
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20211208
IS  - 1520-510X (Electronic)
IS  - 0020-1669 (Linking)
VI  - 60
IP  - 23
DP  - 2021 Dec 6
TI  - Multi-interactive Coordination Network Featuring a Ligand with Topologically 
      Isolated p Orbitals.
PG  - 17858-17864
LID - 10.1021/acs.inorgchem.1c02468 [doi]
AB  - A tridentate 3-pyridyl-based ligand containing a hexaazaphenalene skeleton 
      (3-TPHAP(-)) with topologically isolated p orbitals was prepared by a one-pot 
      reaction. It was successfully reacted with a Co(2+) salt and a 
      1,4-benzenedicarboxylic acid co-ligand to give a porous coordination network. In 
      the structure, the hexaazaphenalene skeleton interacts with water to form an 
      internal hydrogen bonding network, allowing the entire pore space to be revealed 
      by single-crystal X-ray diffraction (SXRD). The network structure consists of 
      dimeric Co clusters featuring labile sites occupied by solvent molecules. Several 
      guest molecules, namely, anthracene, triphenylene, and iodine, were incorporated 
      inside the network. The resultant encapsulated structures were elucidated by 
      SXRD, revealing unusual host-guest interactions with a subtle structural 
      modulation.
FAU - Wada, Yuki
AU  - Wada Y
AD  - Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1 
      Ookayama, Meguro-ku, Tokyo 152-8550, Japan.
FAU - Ohtsu, Hiroyoshi
AU  - Ohtsu H
AUID- ORCID: 0000-0002-2911-3151
AD  - Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1 
      Ookayama, Meguro-ku, Tokyo 152-8550, Japan.
FAU - Usov, Pavel M
AU  - Usov PM
AD  - Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1 
      Ookayama, Meguro-ku, Tokyo 152-8550, Japan.
FAU - Chan, Bun
AU  - Chan B
AUID- ORCID: 0000-0002-0082-5497
AD  - Graduate School of Engineering, Nagasaki University, Bunkyo 1-14, Nagasaki-shi, 
      Nagasaki 852-8521, Japan.
FAU - Deekomwong, Krittanun
AU  - Deekomwong K
AD  - Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1 
      Ookayama, Meguro-ku, Tokyo 152-8550, Japan.
FAU - Kawano, Masaki
AU  - Kawano M
AUID- ORCID: 0000-0001-9886-4226
AD  - Department of Chemistry, School of Science, Tokyo Institute of Technology, 2-12-1 
      Ookayama, Meguro-ku, Tokyo 152-8550, Japan.
LA  - eng
PT  - Journal Article
DEP - 20211119
PL  - United States
TA  - Inorg Chem
JT  - Inorganic chemistry
JID - 0366543
SB  - IM
EDAT- 2021/11/20 06:00
MHDA- 2021/11/20 06:01
CRDT- 2021/11/19 12:09
PHST- 2021/11/20 06:00 [pubmed]
PHST- 2021/11/20 06:01 [medline]
PHST- 2021/11/19 12:09 [entrez]
AID - 10.1021/acs.inorgchem.1c02468 [doi]
PST - ppublish
SO  - Inorg Chem. 2021 Dec 6;60(23):17858-17864. doi: 10.1021/acs.inorgchem.1c02468. 
      Epub 2021 Nov 19.