PMID- 34823860
OWN - NLM
STAT- MEDLINE
DCOM- 20220118
LR  - 20220118
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 239
DP  - 2022 Mar 1
TI  - Magnetic molecularly imprinted polymer for the simultaneous selective extraction 
      of phenoxy acid herbicides from environmental water samples.
PG  - 123082
LID - S0039-9140(21)01004-3 [pii]
LID - 10.1016/j.talanta.2021.123082 [doi]
AB  - A selective magnetic molecularly imprinted polymer (MMIP) was synthetized with 
      4-chloro-2-methylphenoxyacetic acid as template and 4-vinylpiridine as monomer in 
      presence of vinylized magnetite nanoparticles. Scanning electron microscopy, 
      nitrogen adsorption-desorption isotherms, Fourier transform infrared spectrometry 
      and vibrating sample magnetometry were applied to characterize the resulting 
      material. The synthesized MMIP was applied as sorbent in magnetic molecularly 
      imprinted solid-phase extraction (MMISPE) for selective extraction of a mixture 
      of the five herbicides 4-chloro-2-methylphenoxyacetic acid (MCPA), 
      4-(4-chloro-2-methylphenoxy)butyric acid (MCPB), mecoprop (MCPP), fenoxaprop 
      (FEN) and haloxyfop (HAL). Several parameters affecting the extraction conditions 
      were optimized to achieve the best extraction performance. The best MMISPE 
      combined with HPLC-DAD gave detection and quantification limits between 0.33 and 
      0.71 mug L(-1) and 1.1-2.4 mug L(-1), respectively, were obtained. The precision of 
      the whole method provided RSD values below 7.3%, and the accuracy was 
      demonstrated by the analysis of several water samples of different origins, with 
      recoveries ranged from 77 to 98%. Moreover, a remarkable re-usability of the MMIP 
      sorbent, more than 65 uses without losses in extraction capacity, was obtained.
CI  - Copyright (c) 2021 The Authors. Published by Elsevier B.V. All rights reserved.
FAU - Meseguer-Lloret, Susana
AU  - Meseguer-Lloret S
AD  - Institut d'Investigacio per a la Gestio Integrada de Zones Costaneres, Campus de 
      Gandia, Universitat Politecnica de Valencia, C/ Paranimf 1, 46730, Grao de 
      Gandia, Valencia, Spain. Electronic address: sumello@qim.upv.es.
FAU - Torres-Cartas, Sagrario
AU  - Torres-Cartas S
AD  - Institut d'Investigacio per a la Gestio Integrada de Zones Costaneres, Campus de 
      Gandia, Universitat Politecnica de Valencia, C/ Paranimf 1, 46730, Grao de 
      Gandia, Valencia, Spain.
FAU - Gomez-Benito, Carmen
AU  - Gomez-Benito C
AD  - Institut d'Investigacio per a la Gestio Integrada de Zones Costaneres, Campus de 
      Gandia, Universitat Politecnica de Valencia, C/ Paranimf 1, 46730, Grao de 
      Gandia, Valencia, Spain.
FAU - Herrero-Martinez, Jose Manuel
AU  - Herrero-Martinez JM
AD  - Department of Analytical Chemistry, University of Valencia, Dr. Moliner 50, 
      46100, Burjassot, Valencia, Spain. Electronic address: jmherrer@uv.es.
LA  - eng
PT  - Journal Article
DEP - 20211119
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
RN  - 0 (Herbicides)
RN  - 0 (Molecularly Imprinted Polymers)
RN  - 0 (Polymers)
RN  - 059QF0KO0R (Water)
SB  - IM
MH  - Adsorption
MH  - *Herbicides
MH  - Magnetic Phenomena
MH  - *Molecular Imprinting
MH  - Molecularly Imprinted Polymers
MH  - Polymers
MH  - Solid Phase Extraction
MH  - Water
OTO - NOTNLM
OT  - HPLC
OT  - Magnetic molecularly imprinted solid-phase extraction
OT  - Magnetic nanoparticles
OT  - Molecularly imprinted polymer
OT  - Phenoxyacid herbicides
OT  - Water samples
EDAT- 2021/11/27 06:00
MHDA- 2022/01/19 06:00
CRDT- 2021/11/26 05:46
PHST- 2021/10/15 00:00 [received]
PHST- 2021/11/16 00:00 [revised]
PHST- 2021/11/17 00:00 [accepted]
PHST- 2021/11/27 06:00 [pubmed]
PHST- 2022/01/19 06:00 [medline]
PHST- 2021/11/26 05:46 [entrez]
AID - S0039-9140(21)01004-3 [pii]
AID - 10.1016/j.talanta.2021.123082 [doi]
PST - ppublish
SO  - Talanta. 2022 Mar 1;239:123082. doi: 10.1016/j.talanta.2021.123082. Epub 2021 Nov 
      19.