PMID- 34826902
OWN - NLM
STAT- MEDLINE
DCOM- 20211130
LR  - 20211130
IS  - 1879-1298 (Electronic)
IS  - 0045-6535 (Linking)
VI  - 287
IP  - Pt 2
DP  - 2022 Jan
TI  - Visible light photodegradation of 2,4-dichlorophenol using nanostructured 
      NaBiS(2): Kinetics, cytotoxicity, antimicrobial and electrochemical studies of 
      the photocatalyst.
PG  - 132174
LID - S0045-6535(21)02646-1 [pii]
LID - 10.1016/j.chemosphere.2021.132174 [doi]
AB  - Removal of the hazardous and endocrine-disrupting 2,4-dichlorophenol (2,4-DCP) 
      from water bodies is crucial to maintain the sanctity of the ecosystem. As a low 
      bandgap material (1.37 eV), NaBiS(2) was hydrothermally prepared and used as a 
      potential photocatalyst to degrade 2,4-DCP under visible light irradiation. 
      NaBiS(2) appeared to be highly stable and remained structurally undeterred 
      despite thermal variations. With a surface area of 6.69 m(2)/g, NaBiS(2) has 
      enough surface-active sites to adsorb the reactive molecules and exhibit a 
      significant photocatalytic activity. In alkaline pH, the adsorption of 2,4-DCP on 
      NaBiS(2) appeared to decrease whereas, the acidic and neutral environments 
      favoured the degradation. An increase in the photocatalyst dosage enhanced the 
      degradation efficiency from 81 to 86 %, because of higher vacant adsorbent sites 
      and the electrostatic attraction between NaBiS(2) and 2,4-DCP. The dominant 
      scavengers degraded 2,4-DCP by forming a coordination bond between chlorine's 
      lone pair of electrons and the vacant orbitals of bismuth, following the order 
      hole> OH > singlet oxygen. Being non-toxic to both natural and aquatic systems, 
      NaBiS(2) exhibits antifungal properties at higher concentrations. Finally, the 
      electron-rich NaBiS(2) is an excellent electrocatalyst that effectively degrades 
      organic pollutants and is a promising material for industrial and environmental 
      applications.
CI  - Copyright (c) 2021 Elsevier Ltd. All rights reserved.
FAU - Kumar, V G Dileep
AU  - Kumar VGD
AD  - Centre for Incubation, Innovation, Research and Consultancy (CIIRC) and 
      Department of Chemistry, Jyothy Institute of Technology, Tataguni, Off Kanakapura 
      Road, Bangalore, 560082, Karnataka, India; Department of Chemistry, PES 
      University, 100 Ft. Ring Road, BSK 3rd Stage, Bangalore, 560085, Karnataka, 
      India.
FAU - Balaji, K R
AU  - Balaji KR
AD  - Centre for Incubation, Innovation, Research and Consultancy (CIIRC) and 
      Department of Chemistry, Jyothy Institute of Technology, Tataguni, Off Kanakapura 
      Road, Bangalore, 560082, Karnataka, India; Visvesvaraya Technological University, 
      Jnana Sangama, Belgaum, 590018, Karnataka, India.
FAU - Viswanatha, R
AU  - Viswanatha R
AD  - Centre for Incubation, Innovation, Research and Consultancy (CIIRC) and 
      Department of Chemistry, Jyothy Institute of Technology, Tataguni, Off Kanakapura 
      Road, Bangalore, 560082, Karnataka, India.
FAU - Ambika, G
AU  - Ambika G
AD  - Centre for Incubation, Innovation, Research and Consultancy (CIIRC) and 
      Department of Chemistry, Jyothy Institute of Technology, Tataguni, Off Kanakapura 
      Road, Bangalore, 560082, Karnataka, India.
FAU - Roopa, R
AU  - Roopa R
AD  - Centre for Incubation, Innovation, Research and Consultancy (CIIRC) and 
      Department of Chemistry, Jyothy Institute of Technology, Tataguni, Off Kanakapura 
      Road, Bangalore, 560082, Karnataka, India.
FAU - Basavaraja, B M
AU  - Basavaraja BM
AD  - Department of Chemistry, PES University, 100 Ft. Ring Road, BSK 3rd Stage, 
      Bangalore, 560085, Karnataka, India. Electronic address: bmbasavaraja@pes.edu.
FAU - Chennabasappa, Madhu
AU  - Chennabasappa M
AD  - Department of Physics, Siddaganga Institute of Technology, B.H. Road, Tumakuru, 
      572103, India.
FAU - Kumar, C R Ravi
AU  - Kumar CRR
AD  - Research Centre, Department of Science, East West Institute of Technology, 
      Bangalore, 560091, Karnataka, India.
FAU - Chen, Zhong
AU  - Chen Z
AD  - School of Materials Science and Engineering, Nanyang Technological University, 50 
      Nanyang Avenue, 639798, Singapore.
FAU - Bui, Xuan-Thanh
AU  - Bui XT
AD  - Faculty of Environment and Natural Resources, University of Technology, Vietnam 
      National University - Ho Chi Minh, Ho Chi Minh City, 700000, Viet Nam; Key 
      Laboratory for Advanced Waste Treatment Technology, Vietnam National University - 
      Ho Chi Minh, Ho Chi Minh City, 700000, Viet Nam.
FAU - Santosh, M S
AU  - Santosh MS
AD  - Coal and Mineral Processing Division, CSIR - Central Institute of Mining and Fuel 
      Research (CIMFR), Digwadih Campus, PO: FRI, Dhanbad, 828108, Jharkhand, India. 
      Electronic address: santoshms@cimfr.nic.in.
LA  - eng
PT  - Journal Article
DEP - 20210914
PL  - England
TA  - Chemosphere
JT  - Chemosphere
JID - 0320657
RN  - 0 (Anti-Infective Agents)
RN  - 0 (Chlorophenols)
RN  - R669TG1950 (2,4-dichlorophenol)
SB  - IM
MH  - *Anti-Infective Agents
MH  - Catalysis
MH  - Chlorophenols
MH  - *Ecosystem
MH  - Kinetics
MH  - Light
MH  - Photolysis
OTO - NOTNLM
OT  - 2,4-DCP
OT  - Kinetics
OT  - NaBiS2
OT  - Photodegradation
OT  - Visible light
EDAT- 2021/11/28 06:00
MHDA- 2021/12/01 06:00
CRDT- 2021/11/27 01:00
PHST- 2021/07/01 00:00 [received]
PHST- 2021/08/30 00:00 [revised]
PHST- 2021/09/03 00:00 [accepted]
PHST- 2021/11/27 01:00 [entrez]
PHST- 2021/11/28 06:00 [pubmed]
PHST- 2021/12/01 06:00 [medline]
AID - S0045-6535(21)02646-1 [pii]
AID - 10.1016/j.chemosphere.2021.132174 [doi]
PST - ppublish
SO  - Chemosphere. 2022 Jan;287(Pt 2):132174. doi: 10.1016/j.chemosphere.2021.132174. 
      Epub 2021 Sep 14.