PMID- 34842431
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20211229
IS  - 1936-086X (Electronic)
IS  - 1936-0851 (Linking)
VI  - 15
IP  - 12
DP  - 2021 Dec 28
TI  - Emerging Two-Dimensional Covalent and Coordination Polymers for Stable Lithium 
      Metal Batteries: From Liquid to Solid.
PG  - 19026-19053
LID - 10.1021/acsnano.1c09194 [doi]
AB  - Lithium metal anodes (LMAs) have attracted much attention in recent years because 
      of their high theoretical capacity (3860 mAh g(-1)) and low electrochemical 
      potential (-3.040 V vs standard hydrogen electrode). Lithium metal can be coupled 
      with various cathodes to construct high-energy-density lithium metal batteries 
      (LMBs) which hold great promise for next-generation batteries. However, the 
      unstable solid electrolyte interphases (SEIs) and the uncontrollable lithium 
      dendrite growth severely hinder the commercial development of LMAs. The emerging 
      2D polymers (2DPs), which possess high mechanical flexibility, high specific 
      surface area, abundant surface chemistry, and rich chemical modification 
      characteristics, have shown great advantages in addressing the inherent issues of 
      LMAs. Herein, the current progress of 2DPs for stable and dendrite-free LMAs in 
      liquid- and solid-based batteries is comprehensively reviewed. Some perspectives 
      for the application of 2DPs in LMBs are also discussed. It is believed that the 
      emerging 2DPs will provide insights into developing high-energy-density LMBs and 
      beyond.
FAU - Wang, Jiwei
AU  - Wang J
AD  - School of Engineering, Westlake University, Hangzhou 310024, Zhejiang Province, 
      China.
AD  - Northeast Center for Chemical Energy Storage (NECCES), Binghamton University, 
      Binghamton, New York 13902, United States.
FAU - Wang, Kaixi
AU  - Wang K
AD  - School of Engineering, Westlake University, Hangzhou 310024, Zhejiang Province, 
      China.
AD  - Joint Key Laboratory of the Ministry of Education, Institute of Applied Physics 
      and Materials Engineering, University of Macau, Avenida da Universidade, Taipa, 
      Macau SAR 999078, China.
FAU - Xu, Yuxi
AU  - Xu Y
AUID- ORCID: 0000-0003-0318-8515
AD  - School of Engineering, Westlake University, Hangzhou 310024, Zhejiang Province, 
      China.
LA  - eng
PT  - Journal Article
DEP - 20211129
PL  - United States
TA  - ACS Nano
JT  - ACS nano
JID - 101313589
SB  - IM
OTO - NOTNLM
OT  - 2D polymers
OT  - covalent organic frameworks
OT  - liquid-electrolyte-based batteries
OT  - lithium dendrite
OT  - lithium metal anode protection
OT  - lithium metal batteries
OT  - metal organic frameworks
OT  - solid electrolyte interphase
OT  - solid electrolyte-based batteries
EDAT- 2021/11/30 06:00
MHDA- 2021/11/30 06:01
CRDT- 2021/11/29 12:18
PHST- 2021/11/30 06:00 [pubmed]
PHST- 2021/11/30 06:01 [medline]
PHST- 2021/11/29 12:18 [entrez]
AID - 10.1021/acsnano.1c09194 [doi]
PST - ppublish
SO  - ACS Nano. 2021 Dec 28;15(12):19026-19053. doi: 10.1021/acsnano.1c09194. Epub 2021 
      Nov 29.