PMID- 34848802
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20220111
LR  - 20220111
IS  - 2045-2322 (Electronic)
IS  - 2045-2322 (Linking)
VI  - 11
IP  - 1
DP  - 2021 Nov 30
TI  - Synthesis and characterization of genistein magnetic molecularly imprinted 
      polymers and their application in soy sauce products.
PG  - 23183
LID - 10.1038/s41598-021-02625-0 [doi]
LID - 23183
AB  - In this study, a novel method based on genistein magnetic molecularly imprinted 
      polymers (Gen-MMIPs) was developed utilizing a surface molecular imprinting 
      technique, in which genistein was used as the template molecule and Fe(3)O(4) was 
      used as the carrier. The synthesis of Gen-MMIPs was characterized by using 
      scanning electron microscopy (SEM) and transmission electron microscopy (TEM), 
      which indicated that the diameter of the Gen-MMIPs was approximately 500 nm. Via 
      analysis with a vibrating sample magnetometer (VSM), the saturation magnetization 
      of Gen-MMIPs was determined to be 24.79 emu g(-1). Fourier transform infrared 
      (FT-IR) spectroscopy showed that polymer groups were on the surface of the 
      magnetic carrier. Adsorption experiments suggested that the genistein adsorption 
      capability of Gen-MMIPs was 5.81 mg g(-1), and adsorption equilibrium was 
      achieved within 20 min. Gen-MMIPs as dispersive solid-phase extraction (dSPE) 
      adsorbents combined with HPLC were used to selectively separate genistein in soy 
      sauce samples, and the recoveries ranged from 85.7 to 88.5% with relative 
      standard deviations (RSDs) less than 5%, which proved that this method can be 
      used for the detection of genistein residues in real samples.
CI  - (c) 2021. The Author(s).
FAU - Xie, Ziqi
AU  - Xie Z
AD  - Beijing Key Laboratory of Environmental and Viral Oncology, Faculty of 
      Environment and Life, Beijing University of Technology, No. 100, Pingleyuan, 
      Chaoyang District, Beijing, 100124, China.
FAU - Luo, Yunjing
AU  - Luo Y
AUID- ORCID: 0000-0002-8915-369X
AD  - Beijing Key Laboratory of Environmental and Viral Oncology, Faculty of 
      Environment and Life, Beijing University of Technology, No. 100, Pingleyuan, 
      Chaoyang District, Beijing, 100124, China. luoyj@bjut.edu.cn.
FAU - Na, Zhen
AU  - Na Z
AD  - Beijing Key Laboratory of Environmental and Viral Oncology, Faculty of 
      Environment and Life, Beijing University of Technology, No. 100, Pingleyuan, 
      Chaoyang District, Beijing, 100124, China.
FAU - Zhang, Wei
AU  - Zhang W
AD  - Beijing Key Laboratory of Environmental and Viral Oncology, Faculty of 
      Environment and Life, Beijing University of Technology, No. 100, Pingleyuan, 
      Chaoyang District, Beijing, 100124, China.
FAU - Zong, Yufei
AU  - Zong Y
AD  - Beijing Key Laboratory of Environmental and Viral Oncology, Faculty of 
      Environment and Life, Beijing University of Technology, No. 100, Pingleyuan, 
      Chaoyang District, Beijing, 100124, China.
LA  - eng
PT  - Journal Article
DEP - 20211130
PL  - England
TA  - Sci Rep
JT  - Scientific reports
JID - 101563288
SB  - IM
PMC - PMC8633317
COIS- The authors declare no competing interests.
EDAT- 2021/12/02 06:00
MHDA- 2021/12/02 06:01
PMCR- 2021/11/30
CRDT- 2021/12/01 06:39
PHST- 2021/08/02 00:00 [received]
PHST- 2021/11/18 00:00 [accepted]
PHST- 2021/12/01 06:39 [entrez]
PHST- 2021/12/02 06:00 [pubmed]
PHST- 2021/12/02 06:01 [medline]
PHST- 2021/11/30 00:00 [pmc-release]
AID - 10.1038/s41598-021-02625-0 [pii]
AID - 2625 [pii]
AID - 10.1038/s41598-021-02625-0 [doi]
PST - epublish
SO  - Sci Rep. 2021 Nov 30;11(1):23183. doi: 10.1038/s41598-021-02625-0.