PMID- 34866388
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20211216
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 13
IP  - 49
DP  - 2021 Dec 15
TI  - High Mass Loading Asymmetric Micro-supercapacitors with Ultrahigh Areal Energy 
      and Power Density.
PG  - 58486-58497
LID - 10.1021/acsami.1c16248 [doi]
AB  - High mass loading asymmetric micro-supercapacitors (MSCs) are key components for 
      the development of high-performance energy and power supply systems. Here, a 
      concept for achieving high mass loading electrodes is presented and applied to 
      high mass loading micro-supercapacitors with ultrahigh areal energy and power 
      density. The positive electrode is made from porous carbon with birnessite 
      coverage and multiwalled carbon nanotubes (CNTs) as conducting additives 
      (PIC-CNTs-MnO(2)). The negative electrode is prepared from hierarchically porous 
      active carbon mixed with CNTs (PICK-CNTs). Both positive and negative electrode 
      materials are tailored to ensure a high content of macro- and mesopores. MSCs 
      with an optimized mass loading of 13.9 mg.cm(-2) (maximum: 23.6 mg.cm(-2)) 
      provide an ultrahigh areal capacitance of 1.13 F.cm(-2) (volumetric capacitance: 
      22.6 F.cm(-3)), an outstanding energy of 627.8 muWh.cm(-2), and a maximum power 
      density of 64 mW.cm(-2). About 85% of the initial capacitance remained after 5000 
      cycles. Moreover, shunt and tandem device testing confirmed a high uniformity of 
      these MSCs, meeting the requirements of adjustable output currents and voltages 
      in microchips.
FAU - Zhu, Shijin
AU  - Zhu S
AUID- ORCID: 0000-0001-5792-5651
AD  - Polymer Chemistry, Chemnitz University of Technology, Chemnitz 09107, Germany.
AD  - Center for Materials, Architectures and Integration of Nanomembranes (MAIN), 
      Chemnitz University of Technology, Chemnitz 09126, Germany.
FAU - Li, Tianming
AU  - Li T
AD  - Center for Materials, Architectures and Integration of Nanomembranes (MAIN), 
      Chemnitz University of Technology, Chemnitz 09126, Germany.
AD  - Material Systems for Nanoelectronics, Chemnitz University of Technology, Chemnitz 
      09107, Germany.
AD  - Institute for Integrative Nanosciences, Leibniz IFW Dresden, Dresden 01069, 
      Germany.
FAU - Bandari, Vineeth K
AU  - Bandari VK
AD  - Center for Materials, Architectures and Integration of Nanomembranes (MAIN), 
      Chemnitz University of Technology, Chemnitz 09126, Germany.
AD  - Material Systems for Nanoelectronics, Chemnitz University of Technology, Chemnitz 
      09107, Germany.
AD  - Institute for Integrative Nanosciences, Leibniz IFW Dresden, Dresden 01069, 
      Germany.
FAU - Schmidt, Oliver G
AU  - Schmidt OG
AD  - Center for Materials, Architectures and Integration of Nanomembranes (MAIN), 
      Chemnitz University of Technology, Chemnitz 09126, Germany.
AD  - Material Systems for Nanoelectronics, Chemnitz University of Technology, Chemnitz 
      09107, Germany.
AD  - Institute for Integrative Nanosciences, Leibniz IFW Dresden, Dresden 01069, 
      Germany.
FAU - Gruschwitz, Markus
AU  - Gruschwitz M
AD  - Institute of Physics, Chemnitz University of Technology, 09107 Chemnitz, Germany.
FAU - Tegenkamp, Christoph
AU  - Tegenkamp C
AUID- ORCID: 0000-0003-0453-0765
AD  - Institute of Physics, Chemnitz University of Technology, 09107 Chemnitz, Germany.
FAU - Sommer, Michael
AU  - Sommer M
AUID- ORCID: 0000-0002-2377-5998
AD  - Polymer Chemistry, Chemnitz University of Technology, Chemnitz 09107, Germany.
AD  - Center for Materials, Architectures and Integration of Nanomembranes (MAIN), 
      Chemnitz University of Technology, Chemnitz 09126, Germany.
FAU - Choudhury, Soumyadip
AU  - Choudhury S
AUID- ORCID: 0000-0002-3794-8263
AD  - Polymer Chemistry, Chemnitz University of Technology, Chemnitz 09107, Germany.
AD  - Center for Materials, Architectures and Integration of Nanomembranes (MAIN), 
      Chemnitz University of Technology, Chemnitz 09126, Germany.
AD  - Rubber Technology Centre, Indian Institute of Technology, Kharagpur 721302, 
      India.
LA  - eng
PT  - Journal Article
DEP - 20211206
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
SB  - IM
OTO - NOTNLM
OT  - areal energy density
OT  - birnessite
OT  - high mass loading
OT  - micro-supercapacitors
OT  - porous carbons
EDAT- 2021/12/07 06:00
MHDA- 2021/12/07 06:01
CRDT- 2021/12/06 08:43
PHST- 2021/12/07 06:00 [pubmed]
PHST- 2021/12/07 06:01 [medline]
PHST- 2021/12/06 08:43 [entrez]
AID - 10.1021/acsami.1c16248 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2021 Dec 15;13(49):58486-58497. doi: 
      10.1021/acsami.1c16248. Epub 2021 Dec 6.