PMID- 34897555 OWN - NLM STAT- MEDLINE DCOM- 20220228 LR - 20220228 IS - 1436-5073 (Electronic) IS - 0026-3672 (Linking) VI - 189 IP - 1 DP - 2021 Dec 11 TI - Fluorescent polydopamine based molecularly imprinted sensor for ultrafast and selective detection of p-nitrophenol in drinking water. PG - 25 LID - 10.1007/s00604-021-05106-3 [doi] AB - A highly effective fluorescent molecularly imprinted sensor (F-PDA-MIS) based on fluorescent polydopamine (F-PDA) was successfully synthesized for selective and ultrafast detection of p-nitrophenol (P-NP) in drinking water. F-PDA with abundant surface functional groups has been artfully modified to firstly serve as both fluorescent monomer and functional monomer in the synthesis of a uniform luminous F-PDA-MIS, which can greatly improve the detection efficiency. As expected, F-PDA-MIS had an obvious emission wavelength of 535 nm with the optimal excitation wavelength at 400 nm. Specially, F-PDA-MIS could detect P-NP in the range 100 to 1100 nM with much lower detection limit of 24.2 nM within 120 s compared with other conventional imprinted fluorescent sensors based on pure quantum dots (QDs) or dyes. This excellent test phenomenon is mainly ascribed to the rapid electron transfer between F-PDA and P-NP. Satisfactory recovery of 98.0-104% for mineral water and 98.6-106% for boiling water were obtained with relative standard deviations (RSDs) of 2.7-3.4% and 2.6-3.5% respectively. The detection reliability of F-PDA-MIS was verified by the comparison with high-performance liquid chromatography (HPLC-UV). Consequently, F-PDA as a fluorescence functional monomer has been shown to be a possible strategy to effectively improve the detection limit and shorten response time of the target determination in water.. CI - (c) 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Austria, part of Springer Nature. FAU - Xu, Yeqing AU - Xu Y AD - Institute of Green Chemistry and Chemical Technology, Advanced Chemical Engineering Laboratory of Green Materials and Energy of Jiangsu Province, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, China. FAU - Huang, Ting AU - Huang T AD - Institute of Green Chemistry and Chemical Technology, Advanced Chemical Engineering Laboratory of Green Materials and Energy of Jiangsu Province, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, China. FAU - Meng, Minjia AU - Meng M AD - Institute of Green Chemistry and Chemical Technology, Advanced Chemical Engineering Laboratory of Green Materials and Energy of Jiangsu Province, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, China. mmj@ujs.edu.cn. FAU - Yan, Yongsheng AU - Yan Y AD - Institute of Green Chemistry and Chemical Technology, Advanced Chemical Engineering Laboratory of Green Materials and Energy of Jiangsu Province, School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, China. yys@ujs.edu.cn. LA - eng GR - 21808089/National Natural Science Foundation of China/ GR - 51803080/National Natural Science Foundation of China/ GR - 2019M661750/China Postdoctoral Science Foundation/ GR - 2019T120400/China Postdoctoral Science Foundation/ GR - BK20190245/Natural Science Foundation of Jiangsu Province/ GR - 17KJA530003/Major projects of education department of Jiangsu province/ GR - 15JDG024/Programs of Senior Talent Foundation of Jiangsu University/ PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20211211 PL - Austria TA - Mikrochim Acta JT - Mikrochimica acta JID - 7808782 RN - 0 (Drinking Water) RN - 0 (Fluorescent Dyes) RN - 0 (Indoles) RN - 0 (Molecularly Imprinted Polymers) RN - 0 (Nitrophenols) RN - 0 (Polymers) RN - 0 (Water Pollutants, Chemical) RN - 0 (polydopamine) RN - Y92ZL45L4R (4-nitrophenol) SB - IM MH - Drinking Water/*analysis MH - Fluorescent Dyes/chemical synthesis/*chemistry MH - Indoles/chemical synthesis/*chemistry MH - Limit of Detection MH - Molecularly Imprinted Polymers/chemical synthesis/*chemistry MH - Nitrophenols/*analysis MH - Polymers/chemical synthesis/*chemistry MH - Spectrometry, Fluorescence MH - Water Pollutants, Chemical/*analysis OTO - NOTNLM OT - Fluorescent functional monomer OT - Fluorescent polydopamine OT - Molecularly imprinted technique OT - Rapid response OT - p-Nitrophenol EDAT- 2021/12/14 06:00 MHDA- 2022/03/01 06:00 CRDT- 2021/12/13 13:30 PHST- 2021/08/23 00:00 [received] PHST- 2021/11/08 00:00 [accepted] PHST- 2021/12/13 13:30 [entrez] PHST- 2021/12/14 06:00 [pubmed] PHST- 2022/03/01 06:00 [medline] AID - 10.1007/s00604-021-05106-3 [pii] AID - 10.1007/s00604-021-05106-3 [doi] PST - epublish SO - Mikrochim Acta. 2021 Dec 11;189(1):25. doi: 10.1007/s00604-021-05106-3.