PMID- 34928584
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220113
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 14
IP  - 1
DP  - 2022 Jan 12
TI  - Regulated Electrodeposition of Na Metal in Monolithic ZIF-Pillared Graphene 
      Anodes.
PG  - 1203-1211
LID - 10.1021/acsami.1c21841 [doi]
AB  - Sodium (Na) metal batteries receive increasing attention because of their high 
      energy densities and low costs that are enabled by the abundant Na resources. 
      However, dendritic growth and low efficiency of Na-metal anodes limit the 
      practical applications of Na-metal batteries. Here, we propose a 
      three-dimensionally pillared structure in which carbonized nanoparticles of 
      zeolite imidazolate framework-8 (ZIF-8) are sandwiched between reduced graphene 
      oxide (rGO) sheets (ZIF-8-C@rGO). Such a pillared structure enables two 
      advantages over rGO. First, the sodiation products of ZIF-8 (NaZn(13), Na(2)O, 
      and N-doped carbon) have a strong chemical affinity to Na metal, thereby inducing 
      favorable nucleation of Na metal to guide Na deposition. Second, the pillared 
      structure could facilitate the diffusion of Na ions through rGO sheets and help 
      homogenize the current distribution, leading to a uniform deposition of Na metal. 
      As a result, ZIF-8-C@rGO exhibits a dendrite-free morphology during Na 
      plating/stripping and excellent cycling stability with high Coulombic efficiency 
      of over 99.8% for at least 2000 h. A symmetric cell could maintain more than 4000 
      h with a stable average overpotential of only 30 mV at a capacity of 1 mA h 
      cm(-2). This work demonstrates that the design of a ZIF-pillared structure could 
      combine thermodynamic and kinetic regulating factors to offer an alternative 
      solution to the development of durable Na electrodes for high-performance 
      Na-metal batteries.
FAU - He, Qiya
AU  - He Q
AD  - Shaanxi Key Laboratory of Degradable Biomedical Materials, Shaanxi R&D Center of 
      Biomaterials and Fermentation Engineering, School of Chemical Engineering, 
      Northwest University, Taibai North Road 229, Xi'an, Shaanxi 710069, China.
AD  - State Key Laboratory of Multiphase Complex Systems, Institute of Process 
      Engineering, Chinese Academy of Sciences, Beijing 100190, China.
FAU - Jin, Xin
AU  - Jin X
AD  - National Laboratory of Solid State Microstructures, Collaborative Innovation 
      Center of Advanced Microstructures, and College of Engineering and Applied 
      Sciences, Nanjing University, Nanjing 210093, China.
FAU - Li, Zhonghua
AU  - Li Z
AD  - National Laboratory of Solid State Microstructures, Collaborative Innovation 
      Center of Advanced Microstructures, and College of Engineering and Applied 
      Sciences, Nanjing University, Nanjing 210093, China.
FAU - Cai, Ziqiang
AU  - Cai Z
AD  - National Laboratory of Solid State Microstructures, Collaborative Innovation 
      Center of Advanced Microstructures, and College of Engineering and Applied 
      Sciences, Nanjing University, Nanjing 210093, China.
FAU - Tian, Jiaming
AU  - Tian J
AD  - National Laboratory of Solid State Microstructures, Collaborative Innovation 
      Center of Advanced Microstructures, and College of Engineering and Applied 
      Sciences, Nanjing University, Nanjing 210093, China.
FAU - Hui, Junfeng
AU  - Hui J
AD  - Shaanxi Key Laboratory of Degradable Biomedical Materials, Shaanxi R&D Center of 
      Biomaterials and Fermentation Engineering, School of Chemical Engineering, 
      Northwest University, Taibai North Road 229, Xi'an, Shaanxi 710069, China.
FAU - Zhang, Huigang
AU  - Zhang H
AUID- ORCID: 0000-0002-4722-5384
AD  - Shaanxi Key Laboratory of Degradable Biomedical Materials, Shaanxi R&D Center of 
      Biomaterials and Fermentation Engineering, School of Chemical Engineering, 
      Northwest University, Taibai North Road 229, Xi'an, Shaanxi 710069, China.
AD  - State Key Laboratory of Multiphase Complex Systems, Institute of Process 
      Engineering, Chinese Academy of Sciences, Beijing 100190, China.
AD  - National Laboratory of Solid State Microstructures, Collaborative Innovation 
      Center of Advanced Microstructures, and College of Engineering and Applied 
      Sciences, Nanjing University, Nanjing 210093, China.
LA  - eng
PT  - Journal Article
DEP - 20211220
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
SB  - IM
OTO - NOTNLM
OT  - dendrites
OT  - deposition regulation
OT  - interlayer plating
OT  - sodium-metal anodes, Na-ion batteries
EDAT- 2021/12/21 06:00
MHDA- 2021/12/21 06:01
CRDT- 2021/12/20 17:11
PHST- 2021/12/21 06:00 [pubmed]
PHST- 2021/12/21 06:01 [medline]
PHST- 2021/12/20 17:11 [entrez]
AID - 10.1021/acsami.1c21841 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2022 Jan 12;14(1):1203-1211. doi: 
      10.1021/acsami.1c21841. Epub 2021 Dec 20.