PMID- 34939749
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220225
IS  - 2198-3844 (Electronic)
IS  - 2198-3844 (Linking)
VI  - 9
IP  - 5
DP  - 2022 Feb
TI  - White Emissions Containing Room Temperature Phosphorescence from Different 
      Excited States of a D-pi-A Molecule Depending on the Aggregate States.
PG  - e2104539
LID - 10.1002/advs.202104539 [doi]
LID - 2104539
AB  - Development of pure organic molecular materials with room temperature 
      phosphorescence (RTP) and their applications for white emitters have received 
      significant attentions recently. Herein, a D-pi-A molecule (DMACPPY) which can 
      realize white emitting under ambient conditions both in the crystal state and the 
      doped-film state by combining RTP with two fluorescent emissions is reported. The 
      white emission from the crystalline sample of DMACPPY consists fluorescence from 
      S(2) (the second excited singlet state) and S(1) (the first excited singlet 
      state) along with RTP from T(1) (the first excited triplet state), namely, 
      SST-type white light. While, the white emission from the poly methyl methacrylate 
      (PMMA) film doped with DMACPPY contains fluorescences from S(2) and S(1) , and 
      RTP from T(2) (the second excited triplet state) rather than T(1) (STS type). 
      DMACPPY cannot exhibit white spectrum within alternative crystalline state since 
      inferior RTP intensity despite similar ternary emissions. The results demonstrate 
      that the emissive properties for excited states of DMACPPY can be tuned by 
      changing the aggregate state from crystalline to dispersion state in PMMA film. 
      This new RTP emitter fulfills the talent for white emitting and achieves 
      dual-mode white emissions, invisibly, expands the application range for pure 
      organic and heavy atom-free RTP materials.
CI  - (c) 2021 The Authors. Advanced Science published by Wiley-VCH GmbH.
FAU - Du, Mingxu
AU  - Du M
AD  - Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic 
      Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. 
      R. China.
FAU - Shi, Yuhao
AU  - Shi Y
AD  - University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
AD  - Department of Chemistry, Yanbian University, Jilin, 133002, China.
FAU - Zhou, Qi
AU  - Zhou Q
AD  - Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic 
      Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. 
      R. China.
AD  - University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
FAU - Yin, Zheng
AU  - Yin Z
AD  - Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic 
      Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. 
      R. China.
AD  - University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
FAU - Chen, Liangliang
AU  - Chen L
AD  - Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic 
      Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. 
      R. China.
AD  - University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
FAU - Shu, Yilin
AU  - Shu Y
AD  - Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic 
      Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. 
      R. China.
AD  - University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
FAU - Sun, Guang-Yan
AU  - Sun GY
AD  - Department of Chemistry, Yanbian University, Jilin, 133002, China.
FAU - Zhang, Guanxin
AU  - Zhang G
AD  - Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic 
      Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. 
      R. China.
AD  - University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
FAU - Peng, Qian
AU  - Peng Q
AD  - University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
FAU - Zhang, Deqing
AU  - Zhang D
AUID- ORCID: 0000-0002-5709-6088
AD  - Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Organic 
      Solids, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, P. 
      R. China.
AD  - University of Chinese Academy of Sciences, Beijing, 100049, P. R. China.
LA  - eng
GR  - GJTD-2020-02/Chinese Academy of Sciences/
GR  - 21973099/National Natural Science Foundation of China/
GR  - 2019BMS20007/BMS JUNIOR FELLOW/
GR  - CAS-Croucher Funding Scheme/
PT  - Journal Article
DEP - 20211223
PL  - Germany
TA  - Adv Sci (Weinh)
JT  - Advanced science (Weinheim, Baden-Wurttemberg, Germany)
JID - 101664569
SB  - IM
PMC - PMC8844470
OTO - NOTNLM
OT  - aggregate state
OT  - room temperature phosphorescence
OT  - triplet state
OT  - white emission
COIS- The authors declare no conflict of interest.
EDAT- 2021/12/24 06:00
MHDA- 2021/12/24 06:01
PMCR- 2021/12/23
CRDT- 2021/12/23 08:54
PHST- 2021/11/21 00:00 [revised]
PHST- 2021/10/13 00:00 [received]
PHST- 2021/12/24 06:00 [pubmed]
PHST- 2021/12/24 06:01 [medline]
PHST- 2021/12/23 08:54 [entrez]
PHST- 2021/12/23 00:00 [pmc-release]
AID - ADVS3384 [pii]
AID - 10.1002/advs.202104539 [doi]
PST - ppublish
SO  - Adv Sci (Weinh). 2022 Feb;9(5):e2104539. doi: 10.1002/advs.202104539. Epub 2021 
      Dec 23.