PMID- 34953834 OWN - NLM STAT- MEDLINE DCOM- 20220202 LR - 20220202 IS - 1879-1026 (Electronic) IS - 0048-9697 (Linking) VI - 812 DP - 2022 Mar 15 TI - Distribution of organophosphate esters influenced by human activities and fluvial-tidal interactions in the Dong Nai River System, Vietnam. PG - 152649 LID - S0048-9697(21)07727-5 [pii] LID - 10.1016/j.scitotenv.2021.152649 [doi] AB - Limited information is known about organophosphate esters (OPEs) in sediments of the Dong Nai River System (DNRS) in Vietnam and the influences of complex hydro-sedimentary dynamics on their fate. In this study, 48 surface sediment samples were collected from the Dong Nai-Soai Rap River and its tributary Vam Co River for the determination of 11 target OPEs, together with grain size and total organic carbon (TOC). The total concentrations of OPEs were in the range of 39.4 ng/g dw-373 ng/g dw (mean: 128 ng/g dw), and tris(1-chloro-2-propyl) phosphate (TCPP) was the predominant one with an average contribution of 81%, followed by tri-n-butyl phosphate (TNBP), tris(2-ethylhexyl) phosphate (TEHP). The composition profiles of OPEs at different locations of the DNRS showed no significant differences (p > 0.05). In addition, the distribution of OPEs had been influenced by both human activities and the fluvial-tidal interactions. The highly frequent and various human activities in Ho Chi Minh City (HCMC) leaded to the highest total concentration of OPEs in the midstream site. Based on our dataset, TOC content and grain size of sediments had significant correlation with certain OPEs (p < 0.05), and sediments with higher TOC content and finer grain size in the DNRS were more likely to be deposited in the downstream reach, contributing to the estuary of the DNRS was identified as another hotspot with the second highest concentration of OPEs. Furthermore, the distribution of OPEs in the transects had distinct characteristics, which reflected the joint influence of the human activities and fluvial-tidal interaction as well. However, the mechanism of their influence needed further investigation. CI - Copyright (c) 2021 Elsevier B.V. All rights reserved. FAU - Ma, Yu AU - Ma Y AD - College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China. FAU - Saito, Yoshiki AU - Saito Y AD - Estuary Research Center, Shimane University, Matsue 6908504, Japan; Geological Survey of Japan, AIST, Tsukuba 305-8567, Japan. FAU - Ta, Thi Kim Oanh AU - Ta TKO AD - HCMC Institute of Resources Geography, VAST, Ho Chi Minh City, Viet Nam. FAU - Li, Yue AU - Li Y AD - State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai 200062, China. Electronic address: yli@sklec.ecnu.edu.cn. FAU - Yao, Qinglu AU - Yao Q AD - College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China. FAU - Yang, Chao AU - Yang C AD - College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China; State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092, China. Electronic address: yangchao_env@tongji.edu.cn. FAU - Nguyen, Van Lap AU - Nguyen VL AD - HCMC Institute of Resources Geography, VAST, Ho Chi Minh City, Viet Nam. FAU - Gugliotta, Marcello AU - Gugliotta M AD - Faculty of Geosciences, University of Bremen, 28359 Bremen, Germany; MARUM, University of Bremen, 28359 Bremen, Germany. FAU - Wang, Zhanghua AU - Wang Z AD - State Key Laboratory of Estuarine and Coastal Research, East China Normal University, Shanghai 200062, China. FAU - Chen, Ling AU - Chen L AD - College of Environmental Science and Engineering, Tongji University, Shanghai 200092, China; State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai 200092, China. LA - eng PT - Journal Article DEP - 20211223 PL - Netherlands TA - Sci Total Environ JT - The Science of the total environment JID - 0330500 RN - 0 (Esters) RN - 0 (Flame Retardants) RN - 0 (Organophosphates) SB - IM MH - China MH - Environmental Monitoring MH - Esters MH - *Flame Retardants/analysis MH - Human Activities MH - Humans MH - Organophosphates MH - Vietnam OTO - NOTNLM OT - Fluvial-tidal interactions OT - Organophosphate esters OT - Sediment OT - Spatial distribution COIS- Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2021/12/27 06:00 MHDA- 2022/02/03 06:00 CRDT- 2021/12/26 20:32 PHST- 2021/10/13 00:00 [received] PHST- 2021/12/18 00:00 [revised] PHST- 2021/12/19 00:00 [accepted] PHST- 2021/12/27 06:00 [pubmed] PHST- 2022/02/03 06:00 [medline] PHST- 2021/12/26 20:32 [entrez] AID - S0048-9697(21)07727-5 [pii] AID - 10.1016/j.scitotenv.2021.152649 [doi] PST - ppublish SO - Sci Total Environ. 2022 Mar 15;812:152649. doi: 10.1016/j.scitotenv.2021.152649. Epub 2021 Dec 23.