PMID- 34957590
OWN - NLM
STAT- MEDLINE
DCOM- 20220419
LR  - 20220419
IS  - 1099-0801 (Electronic)
IS  - 0269-3879 (Linking)
VI  - 36
IP  - 5
DP  - 2022 May
TI  - Simultaneous determination of pinoxaden, cloquintocet-mexyl, clodinafop-propargyl 
      ester and its major metabolite in barley products and soil using QuEChERS 
      modified with multi-walled carbon nanotubes coupled with LC-MS/MS.
PG  - e5303
LID - 10.1002/bmc.5303 [doi]
AB  - Herein, a modified quick, easy, cheap, effective, rugged, and safe (QuEChERS) 
      method with multi-walled carbon nanotube (MWCNT) as a dispersive solid-phase 
      extraction was developed for simultaneous determination of pinoxaden (PXD), 
      cloquintocet-mexyl (CLM), clodinafop-propargyl ester (CPE) and its major 
      metabolite (clodinafop, CP) in barley grass powder, barley grain, and soil using 
      liquid chromatography-tandem mass spectrometry (LC-MS/MS). We found that MWCNT as 
      an absorbent could improve the recoveries of the tested analytes, particularly 
      CP, in complex matrices. Under the optimum conditions, the established 
      MWCNT-modified QuEChERS coupled with LC-MS/MS method exhibited excellent 
      linearity (R(2) ) of >/=0.9912, low limits of detection (LODs) and quantification 
      (LOQs) of 0.02-0.07 and 0.29-1.26 mug kg(-1) , and acceptable recoveries of 
      80-130% with intra- and inter-day relative standard deviations (RSDs) < 10.5%. No 
      strong matrix effect (ME) has been observed on the respective samples. The method 
      was successfully applied to monitor the tested analytes in the representative 
      field incurred samples. Conclusively, the proposed method is sensitive and 
      reliable and could be used to monitor the residues of PDX, CLM, CPE, and CP in 
      complicated agro-products and soil matrices.
CI  - (c) 2021 John Wiley & Sons, Ltd.
FAU - Li, Ning
AU  - Li N
AD  - State Key Laboratory of Animal Nutrition, Institute of Animal Sciences of Chinese 
      Academy of Agricultural Sciences, Beijing, China.
AD  - Scientific Observing and Experiment Station of Animal Genetic Resources and 
      Nutrition in North China of Ministry of Agriculture and Rural Affairs, Institute 
      of Animal Sciences of Chinese Academy of Agricultural Sciences, Beijing, China.
AD  - Institute of Apicultural Research, Chinese Academy of Agricultural Sciences, 
      Beijing, China.
FAU - Han, Danhe
AU  - Han D
AD  - Institute of Quality Standard and Testing Technology for Agro-Products, Chinese 
      Academy of Agricultural Sciences, Beijing, China.
FAU - Ma, Xuefeng
AU  - Ma X
AD  - Institute of Quality Standard and Testing Technology for Agro-Products, Chinese 
      Academy of Agricultural Sciences, Beijing, China.
FAU - Qiu, Cheng
AU  - Qiu C
AD  - Institute of Quality Standard and Testing Technology for Agro-Products, Chinese 
      Academy of Agricultural Sciences, Beijing, China.
FAU - Qin, Yuchang
AU  - Qin Y
AD  - State Key Laboratory of Animal Nutrition, Institute of Animal Sciences of Chinese 
      Academy of Agricultural Sciences, Beijing, China.
AD  - Scientific Observing and Experiment Station of Animal Genetic Resources and 
      Nutrition in North China of Ministry of Agriculture and Rural Affairs, Institute 
      of Animal Sciences of Chinese Academy of Agricultural Sciences, Beijing, China.
FAU - Yao, Ting
AU  - Yao T
AD  - State Key Laboratory of Animal Nutrition, Institute of Animal Sciences of Chinese 
      Academy of Agricultural Sciences, Beijing, China.
AD  - Scientific Observing and Experiment Station of Animal Genetic Resources and 
      Nutrition in North China of Ministry of Agriculture and Rural Affairs, Institute 
      of Animal Sciences of Chinese Academy of Agricultural Sciences, Beijing, China.
FAU - Wang, Shanshan
AU  - Wang S
AD  - Institute of Quality Standard and Testing Technology for Agro-Products, Chinese 
      Academy of Agricultural Sciences, Beijing, China.
FAU - She, Yongxin
AU  - She Y
AUID- ORCID: 0000-0001-7055-4808
AD  - Institute of Quality Standard and Testing Technology for Agro-Products, Chinese 
      Academy of Agricultural Sciences, Beijing, China.
FAU - Hacimuftuoglu, Fazil
AU  - Hacimuftuoglu F
AD  - Department of Soil Science and Plant Nutrition, Faculty of Agriculture, Ataturk 
      University, Erzurum, Turkey.
FAU - Abd El-Aty, A M
AU  - Abd El-Aty AM
AUID- ORCID: 0000-0001-6596-7907
AD  - Department of Pharmacology, Faculty of Veterinary Medicine, Cairo University, 
      Giza, Egypt.
AD  - Department of Medical Pharmacology, Medical Faculty, Ataturk University, Erzurum, 
      Turkey.
LA  - eng
GR  - 31772071/National Natural Science Foundation of China/
GR  - 05A-03/National Natural Science Foundation of China/
GR  - Y2021XK21/National Natural Science Foundation of China/
PT  - Journal Article
DEP - 20220206
PL  - England
TA  - Biomed Chromatogr
JT  - Biomedical chromatography : BMC
JID - 8610241
RN  - 0 (Esters)
RN  - 0 (Heterocyclic Compounds, 2-Ring)
RN  - 0 (Nanotubes, Carbon)
RN  - 0 (Propionates)
RN  - 0 (Pyridines)
RN  - 0 (Quinolines)
RN  - 0 (Soil)
RN  - 99W15EH2M3 (cloquintocet-mexyl)
RN  - QEH394TY6Y (clodinafop-propargyl)
RN  - U55GLF9LV9 (pinoxaden)
SB  - IM
MH  - Chromatography, High Pressure Liquid
MH  - Chromatography, Liquid/methods
MH  - Esters
MH  - Heterocyclic Compounds, 2-Ring
MH  - *Hordeum
MH  - Limit of Detection
MH  - *Nanotubes, Carbon/chemistry
MH  - Propionates
MH  - Pyridines
MH  - Quinolines
MH  - Soil
MH  - Solid Phase Extraction/methods
MH  - Tandem Mass Spectrometry/methods
EDAT- 2021/12/28 06:00
MHDA- 2022/04/20 06:00
CRDT- 2021/12/27 06:47
PHST- 2021/11/30 00:00 [revised]
PHST- 2021/10/09 00:00 [received]
PHST- 2021/12/02 00:00 [accepted]
PHST- 2021/12/28 06:00 [pubmed]
PHST- 2022/04/20 06:00 [medline]
PHST- 2021/12/27 06:47 [entrez]
AID - 10.1002/bmc.5303 [doi]
PST - ppublish
SO  - Biomed Chromatogr. 2022 May;36(5):e5303. doi: 10.1002/bmc.5303. Epub 2022 Feb 6.