PMID- 34973576
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220131
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 427
DP  - 2022 Apr 5
TI  - Solar light photocatalytic transformation of heptachlorobiphenyl (PCB 180) using 
      g-C(3)N(4) based magnetic porous photocatalyst.
PG  - 128105
LID - S0304-3894(21)03074-0 [pii]
LID - 10.1016/j.jhazmat.2021.128105 [doi]
AB  - A novel porous core-shell magnetic beta-cyclodextrin/graphitic carbon nitride 
      photocatalyst (Mbeta-CD/GCN) was synthesized and employed in a solar light driven 
      catalytic system for the degradation of polychlorinated biphenyls (PCBs). The 
      Mbeta-CD/GCN display superior photocatalytic performance on account of porous 
      structure and ultrathin GCN nanosheets design, the former improves the 
      utilization of visible light by multiple scattering and reflection of incident 
      light, and the latter accelerates electron transfer. The ultrahigh specific 
      surface area (1255 m(2) g(-1)) of Mbeta-CD/GCN provided a large number of active 
      sites for adsorption and degradation of the target pollution. The pseudo-first 
      order reaction rate constant (k(obs)) for the degradation of PCB180 by Mbeta-CD/GCN 
      was 0.021 min(-1), which improved 3.23 times than the bulk GCN. Additionally, the 
      effects of various reaction parameters and water matrices were studied on the 
      degradation of PCB180. Three possible degradation pathways and mechanism of 
      PCB180 were speculated according to the identification of reaction intermediates 
      and detection of reactive species. The solar light driven Mbeta-CD/GCN catalytic 
      technology is a promising method not only for the control of persistent organic 
      pollutants (POPs), but also the catalyst could be recovered and reused through 
      simple magnetic separation.
CI  - Copyright (c) 2021 Elsevier B.V. All rights reserved.
FAU - Wang, Hui
AU  - Wang H
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of 
      Technology, Harbin 150090, China; Heilongjiang Provincial Key Laboratory of Polar 
      Environment and Ecosystem, Harbin Institute of Technology, Harbin 150090, China.
FAU - Zhang, Chenyu
AU  - Zhang C
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of 
      Technology, Harbin 150090, China.
FAU - Kong, Lingru
AU  - Kong L
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of 
      Technology, Harbin 150090, China.
FAU - Wang, Yi
AU  - Wang Y
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of 
      Technology, Harbin 150090, China.
FAU - Zhang, Sijia
AU  - Zhang S
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of 
      Technology, Harbin 150090, China.
FAU - Zhang, Xiulian
AU  - Zhang X
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of 
      Technology, Harbin 150090, China.
FAU - Ding, Jie
AU  - Ding J
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of 
      Technology, Harbin 150090, China. Electronic address: dingjie123@hit.edu.cn.
FAU - Ren, Nanqi
AU  - Ren N
AD  - State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of 
      Technology, Harbin 150090, China. Electronic address: rnq@hit.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20211229
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
SB  - IM
OTO - NOTNLM
OT  - GCN nanosheets
OT  - PCB180
OT  - Photocatalyst
OT  - Porous structure
OT  - Solar light driven
EDAT- 2022/01/02 06:00
MHDA- 2022/01/02 06:01
CRDT- 2022/01/01 20:19
PHST- 2021/10/27 00:00 [received]
PHST- 2021/12/14 00:00 [revised]
PHST- 2021/12/15 00:00 [accepted]
PHST- 2022/01/02 06:00 [pubmed]
PHST- 2022/01/02 06:01 [medline]
PHST- 2022/01/01 20:19 [entrez]
AID - S0304-3894(21)03074-0 [pii]
AID - 10.1016/j.jhazmat.2021.128105 [doi]
PST - ppublish
SO  - J Hazard Mater. 2022 Apr 5;427:128105. doi: 10.1016/j.jhazmat.2021.128105. Epub 
      2021 Dec 29.