PMID- 34974046
OWN - NLM
STAT- MEDLINE
DCOM- 20220302
LR  - 20220302
IS  - 1879-1298 (Electronic)
IS  - 0045-6535 (Linking)
VI  - 293
DP  - 2022 Apr
TI  - Facile synthesis of Mn, Ce co-doped g-C(3)N(4) composite for peroxymonosulfate 
      activation towards organic contaminant degradation.
PG  - 133472
LID - S0045-6535(21)03946-1 [pii]
LID - 10.1016/j.chemosphere.2021.133472 [doi]
AB  - Peroxymonosulfate (PMS)-based advanced oxidation processes for wastewater 
      treatment have received extensive attention in the past years. Here, a novel Mn, 
      Ce co-modified g-C(3)N(4) (MnCe-CN) composite was successfully synthesized by 
      one-step pyrolysis for activating PMS. The physical and chemical characterization 
      of MnCe-CN/PMS was conducted, indicating that Mn and Ce were evenly distributed 
      on g-C(3)N(4) and existed in the form of Mn-N structure and CeO(2), respectively. 
      The MnCe-CN/PMS system could effectively degrade pollutants such as acetaminophen 
      (ACT), methylparaben (MeP), p-nitrophenol (PNP), and 2,4-dichlorophenol 
      (2,4-DCP). Among them, 2,4-DCP could be rapidly degraded, reaching 100% within 
      30 min. The masking experiments and electrochemical testing results revealed that 
      2,4-DCP was degraded via superoxide radicals (O(2) -), singlet oxygen ((1)O(2)), 
      and electron transfer path. The cyclic experiments and real water treatment 
      experiments testified that the oxidative system had excellent stability and 
      applicability. This study provides a facile synthetic method to fabricate 
      bimetallic co-modified g-C(3)N(4) for the enhancement of PMS activation.
CI  - Copyright (c) 2022 Elsevier Ltd. All rights reserved.
FAU - Lai, Cui
AU  - Lai C
AD  - College of Environmental Science and Engineering, Hunan University, Changsha, 
      410082, PR China; Key Laboratory of Environmental Biology and Pollution Control, 
      Hunan University, Ministry of Education, Changsha, 410082, PR China. Electronic 
      address: laicui@hnu.edu.cn.
FAU - Yan, Huchuan
AU  - Yan H
AD  - College of Environmental Science and Engineering, Hunan University, Changsha, 
      410082, PR China; Key Laboratory of Environmental Biology and Pollution Control, 
      Hunan University, Ministry of Education, Changsha, 410082, PR China.
FAU - Wang, Dongbo
AU  - Wang D
AD  - College of Environmental Science and Engineering, Hunan University, Changsha, 
      410082, PR China; Key Laboratory of Environmental Biology and Pollution Control, 
      Hunan University, Ministry of Education, Changsha, 410082, PR China. Electronic 
      address: dongbowang@hnu.edu.cn.
FAU - Liu, Shiyu
AU  - Liu S
AD  - College of Environmental Science and Engineering, Hunan University, Changsha, 
      410082, PR China; Key Laboratory of Environmental Biology and Pollution Control, 
      Hunan University, Ministry of Education, Changsha, 410082, PR China.
FAU - Zhou, Xuerong
AU  - Zhou X
AD  - College of Environmental Science and Engineering, Hunan University, Changsha, 
      410082, PR China; Key Laboratory of Environmental Biology and Pollution Control, 
      Hunan University, Ministry of Education, Changsha, 410082, PR China.
FAU - Li, Xiaopei
AU  - Li X
AD  - College of Environmental Science and Engineering, Hunan University, Changsha, 
      410082, PR China; Key Laboratory of Environmental Biology and Pollution Control, 
      Hunan University, Ministry of Education, Changsha, 410082, PR China.
FAU - Zhang, Mingming
AU  - Zhang M
AD  - College of Environmental Science and Engineering, Hunan University, Changsha, 
      410082, PR China; Key Laboratory of Environmental Biology and Pollution Control, 
      Hunan University, Ministry of Education, Changsha, 410082, PR China.
FAU - Li, Ling
AU  - Li L
AD  - College of Environmental Science and Engineering, Hunan University, Changsha, 
      410082, PR China; Key Laboratory of Environmental Biology and Pollution Control, 
      Hunan University, Ministry of Education, Changsha, 410082, PR China.
FAU - Fu, Yukui
AU  - Fu Y
AD  - College of Environmental Science and Engineering, Hunan University, Changsha, 
      410082, PR China; Key Laboratory of Environmental Biology and Pollution Control, 
      Hunan University, Ministry of Education, Changsha, 410082, PR China.
FAU - Xu, Fuhang
AU  - Xu F
AD  - College of Environmental Science and Engineering, Hunan University, Changsha, 
      410082, PR China; Key Laboratory of Environmental Biology and Pollution Control, 
      Hunan University, Ministry of Education, Changsha, 410082, PR China.
FAU - Yang, Xiaofeng
AU  - Yang X
AD  - College of Environmental Science and Engineering, Hunan University, Changsha, 
      410082, PR China; Key Laboratory of Environmental Biology and Pollution Control, 
      Hunan University, Ministry of Education, Changsha, 410082, PR China.
FAU - Huo, Xiuqin
AU  - Huo X
AD  - College of Environmental Science and Engineering, Hunan University, Changsha, 
      410082, PR China; Key Laboratory of Environmental Biology and Pollution Control, 
      Hunan University, Ministry of Education, Changsha, 410082, PR China.
LA  - eng
PT  - Journal Article
DEP - 20211230
PL  - England
TA  - Chemosphere
JT  - Chemosphere
JID - 0320657
RN  - 0 (Peroxides)
RN  - 11062-77-4 (Superoxides)
RN  - 17778-80-2 (Singlet Oxygen)
RN  - 22047-43-4 (peroxymonosulfate)
SB  - IM
MH  - Oxidation-Reduction
MH  - *Peroxides/chemistry
MH  - *Singlet Oxygen
MH  - Superoxides
OTO - NOTNLM
OT  - CeO(2)
OT  - Mn-N bond
OT  - Peroxymonosulfate
OT  - Singlet oxygen
OT  - Superoxide radical
EDAT- 2022/01/03 06:00
MHDA- 2022/03/03 06:00
CRDT- 2022/01/02 20:21
PHST- 2021/09/25 00:00 [received]
PHST- 2021/12/27 00:00 [revised]
PHST- 2021/12/28 00:00 [accepted]
PHST- 2022/01/03 06:00 [pubmed]
PHST- 2022/03/03 06:00 [medline]
PHST- 2022/01/02 20:21 [entrez]
AID - S0045-6535(21)03946-1 [pii]
AID - 10.1016/j.chemosphere.2021.133472 [doi]
PST - ppublish
SO  - Chemosphere. 2022 Apr;293:133472. doi: 10.1016/j.chemosphere.2021.133472. Epub 
      2021 Dec 30.