PMID- 35012196 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20220113 IS - 2073-4360 (Electronic) IS - 2073-4360 (Linking) VI - 14 IP - 1 DP - 2022 Jan 2 TI - Selective Recognition of Gallic Acid Using Hollow Magnetic Molecularly Imprinted Polymers with Double Imprinting Surfaces. LID - 10.3390/polym14010175 [doi] LID - 175 AB - Gallic acid is widely used in the field of food and medicine due to its diversified bioactivities. The extraction method with higher specificity and efficiency is the key to separate and purify gallic acid from complex biological matrix. Herein, using self-made core-shell magnetic molecularly imprinted polymers (MMIP) with gallic acid as template, a hollow magnetic molecularly imprinted polymer (HMMIP) with double imprinting/adsorption surfaces was prepared by etching the mesoporous silica intermediate layer of MMIP. The characterization and adsorption research showed that the HMMIP had larger specific surface area, higher magnetic response strength and a more stable structure, and the selectivity and saturated adsorption capacity (2.815 mmol/g at 318 K) of gallic acid on HMMIP were better than those of MMIP. Thus, in addition to MMIP, the improved HMMIP had excellent separation and purification ability to selectively extract gallic acid from complex matrix with higher specificity and efficiency. FAU - Li, Jiawei AU - Li J AD - College of Sciences, Central South University of Forestry and Technology, Changsha 410004, China. FAU - Zhou, Xinji AU - Zhou X AD - College of Sciences, Central South University of Forestry and Technology, Changsha 410004, China. FAU - Yan, Yu AU - Yan Y AD - College of Sciences, Central South University of Forestry and Technology, Changsha 410004, China. FAU - Shen, Dianling AU - Shen D AD - College of Sciences, Central South University of Forestry and Technology, Changsha 410004, China. FAU - Lu, Danqing AU - Lu D AD - College of Sciences, Central South University of Forestry and Technology, Changsha 410004, China. FAU - Guo, Yaping AU - Guo Y AD - College of Sciences, Central South University of Forestry and Technology, Changsha 410004, China. FAU - Xie, Lianwu AU - Xie L AUID- ORCID: 0000-0002-9387-4123 AD - College of Sciences, Central South University of Forestry and Technology, Changsha 410004, China. FAU - Deng, Bin AU - Deng B AD - College of Chemistry Biology and Environmental Engineering, Xiangnan University, Chenzhou 423043, China. LA - eng GR - 2020NK2019/the Provincial Key Research and Development Plan in Hunan, China/ GR - 22004132/the National Natural Science Foundation for Young Scientists of China/ GR - 2020JJ4940/the Hunan Provincial Natural Science Fund/ GR - 2019XGJSKFJJ01/the Hunan Provincial Key Laboratory of Xiangnan Rare-Precious Metals Compounds and Applications/ GR - 18A465/the Construction Program of the Key Discipline of the Education Department in Hunan Province/ PT - Journal Article DEP - 20220102 PL - Switzerland TA - Polymers (Basel) JT - Polymers JID - 101545357 PMC - PMC8747617 OTO - NOTNLM OT - adsorption OT - double imprinting surfaces OT - gallic acid OT - hollow magnetic molecularly imprinted polymers OT - selective recognition COIS- The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. EDAT- 2022/01/12 06:00 MHDA- 2022/01/12 06:01 PMCR- 2022/01/02 CRDT- 2022/01/11 01:17 PHST- 2021/12/09 00:00 [received] PHST- 2021/12/27 00:00 [revised] PHST- 2021/12/30 00:00 [accepted] PHST- 2022/01/11 01:17 [entrez] PHST- 2022/01/12 06:00 [pubmed] PHST- 2022/01/12 06:01 [medline] PHST- 2022/01/02 00:00 [pmc-release] AID - polym14010175 [pii] AID - polymers-14-00175 [pii] AID - 10.3390/polym14010175 [doi] PST - epublish SO - Polymers (Basel). 2022 Jan 2;14(1):175. doi: 10.3390/polym14010175.