PMID- 35013944 OWN - NLM STAT- MEDLINE DCOM- 20220503 LR - 20220531 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 29 IP - 21 DP - 2022 May TI - Atmospheric concentration, spatial variations, and source identification of persistent organic pollutants in urban and semi-urban areas using passive air samplers in Bursa, Turkey. PG - 32082-32092 LID - 10.1007/s11356-021-17987-1 [doi] AB - In this study, the concentration of ambient persistent organic pollutants (POPs) such as polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and organochlorine pesticides (OCPs) were measured for 12 months in urban and semi-urban areas using a passive air sampler. During the sampling period, a total of 14 PAH ( summation operator(14)PAH) concentrations measured in urban and semi-urban areas were found to be 54.4 +/- 22.6 ng/m(3) and 51.7 +/- 34.3 ng/m(3), respectively. Molecular diagnostic ratios (MDRs) were used to determine PAH sources. According to the MDR values, combustion sources were the most important PAH sources in both sampling areas. However, since the urban area is close to the industrial zone, the combustion sources occurred at high temperatures (> 800 degrees C), while the sources in the semi-urban area generally consisted of petrogenic fuel combustion. summation operator(50)PCB concentrations measured in the urban and semi-urban areas were found to be 522.5 +/- 196.9 pg/m(3) and 439.5 +/- 166.6 pg/m(3), respectively. Homologous group distributions were used to determine the source of PCBs. According to the homologous group distributions, tri-, tetra-, and penta-chlorinated PCBs were dominant in both sampling areas. summation operator(10)OCP concentrations measured in urban and semi-urban areas were found as 242.5 +/- 104.6 pg/m(3) and 275.9 +/- 130.9 pg/m(3), respectively. Also, alpha-HCH/gamma-HCH and beta-/(alpha + gamma)-HCH ratios were used to determine the source of OCPs. Lindane was the predominant OCP in both sampling areas. CI - (c) 2021. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. FAU - Sari, Mehmet Ferhat AU - Sari MF AD - Department of Environmental Engineering, Faculty of Engineering, Bursa Uludag University, 16059, Nilufer/Bursa, Turkey. FAU - Esen, Fatma AU - Esen F AUID- ORCID: 0000-0002-1445-0868 AD - Department of Environmental Engineering, Faculty of Engineering, Bursa Uludag University, 16059, Nilufer/Bursa, Turkey. payan@uludag.edu.tr. LA - eng GR - 116Y208/turkiye bilimsel ve teknolojik arastirma kurumu/ GR - OUAP (MH)-2020/8/uludag universitesi/ PT - Journal Article DEP - 20220111 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - 0 (Air Pollutants) RN - 0 (Hydrocarbons, Chlorinated) RN - 0 (Pesticides) RN - 0 (Polycyclic Aromatic Hydrocarbons) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - *Air Pollutants/analysis MH - Environmental Monitoring MH - *Hydrocarbons, Chlorinated/analysis MH - Persistent Organic Pollutants MH - *Pesticides/analysis MH - *Polychlorinated Biphenyls/analysis MH - *Polycyclic Aromatic Hydrocarbons/analysis MH - Turkey OTO - NOTNLM OT - OCPs OT - PAHs OT - PCBs OT - Passive air samplers OT - Spatial variation EDAT- 2022/01/12 06:00 MHDA- 2022/05/04 06:00 CRDT- 2022/01/11 06:58 PHST- 2021/06/30 00:00 [received] PHST- 2021/12/03 00:00 [accepted] PHST- 2022/01/12 06:00 [pubmed] PHST- 2022/05/04 06:00 [medline] PHST- 2022/01/11 06:58 [entrez] AID - 10.1007/s11356-021-17987-1 [pii] AID - 10.1007/s11356-021-17987-1 [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2022 May;29(21):32082-32092. doi: 10.1007/s11356-021-17987-1. Epub 2022 Jan 11.