PMID- 35124317 OWN - NLM STAT- MEDLINE DCOM- 20220222 LR - 20220222 IS - 1095-8630 (Electronic) IS - 0301-4797 (Linking) VI - 308 DP - 2022 Apr 15 TI - The environmental impact of historical Pb-Zn mining waste deposits in Slovenia. PG - 114580 LID - S0301-4797(22)00153-0 [pii] LID - 10.1016/j.jenvman.2022.114580 [doi] AB - Mining waste deposits (MWDs) represent significant and constant pollution source for the environment worldwide, thus it is very important to identify and diminish their environmental impacts. The aim of this study was to determine long-term environmental impacts and their temporal variations of MWDs in Pb-Zn mining districts in Slovenia and assess stability of potentially harmful element (PHE)-bearing phases in stream water. The results showed that investigated MWDs are important source of PHEs in stream sediments and that PHEs mostly occur as fine-grained and liberated PHE-bearing ore minerals. MWDs have generally stronger impact on sediments of smaller streams draining MWDs and main streams close to their confluences, however, fine-grained PHE-bearing material is transported along major watercourses over long distances causing regional pollution. Main ore minerals are mostly soluble in stream water. However, measured PHE leaching potential of MWDs is negligible. PHE levels in stream waters are thus low, demonstrating that drainage of MWDs predominantly contributes to PHE pollution in solid particulate form. Possible long-term remediation solution that would reduce environmental impact is recovery of metals from fine grain size fractions of MWDs, which could become an effective practice in sustainable management of historical MWDs. However, further studies of MWDs' secondary resource potential, processing technology and evaluation of environmental aspects of extraction are needed. CI - Copyright (c) 2022 The Authors. Published by Elsevier Ltd.. All rights reserved. FAU - Miler, Milos AU - Miler M AD - Geological Survey of Slovenia, Dimiceva ulica 14, SI-1000 Ljubljana, Slovenia. Electronic address: milos.miler@geo-zs.si. FAU - Bavec, Spela AU - Bavec S AD - Geological Survey of Slovenia, Dimiceva ulica 14, SI-1000 Ljubljana, Slovenia. Electronic address: spela.bavec@geo-zs.si. FAU - Gosar, Mateja AU - Gosar M AD - Geological Survey of Slovenia, Dimiceva ulica 14, SI-1000 Ljubljana, Slovenia. Electronic address: mateja.gosar@geo-zs.si. LA - eng PT - Journal Article DEP - 20220203 PL - England TA - J Environ Manage JT - Journal of environmental management JID - 0401664 RN - 0 (Metals, Heavy) RN - 0 (Water Pollutants, Chemical) RN - 2P299V784P (Lead) RN - J41CSQ7QDS (Zinc) SB - IM MH - Environmental Monitoring/methods MH - Geologic Sediments MH - Lead MH - *Metals, Heavy/analysis MH - Mining MH - Rivers MH - Slovenia MH - *Water Pollutants, Chemical/analysis MH - Zinc/analysis OTO - NOTNLM OT - Characterisation OT - Metals OT - Mineral solubility OT - Stream sediment OT - Stream water EDAT- 2022/02/07 06:00 MHDA- 2022/02/23 06:00 CRDT- 2022/02/06 20:32 PHST- 2021/10/07 00:00 [received] PHST- 2022/01/04 00:00 [revised] PHST- 2022/01/19 00:00 [accepted] PHST- 2022/02/07 06:00 [pubmed] PHST- 2022/02/23 06:00 [medline] PHST- 2022/02/06 20:32 [entrez] AID - S0301-4797(22)00153-0 [pii] AID - 10.1016/j.jenvman.2022.114580 [doi] PST - ppublish SO - J Environ Manage. 2022 Apr 15;308:114580. doi: 10.1016/j.jenvman.2022.114580. Epub 2022 Feb 3.