PMID- 35160448 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20220219 IS - 2073-4360 (Electronic) IS - 2073-4360 (Linking) VI - 14 IP - 3 DP - 2022 Jan 24 TI - Copper Oxide-Antimony Oxide Entrapped Alginate Hydrogel as Efficient Catalyst for Selective Reduction of 2-Nitrophenol. LID - 10.3390/polym14030458 [doi] LID - 458 AB - Copper oxide-antimony oxide (Cu(2)O-Sb(2)O(3)) was prepared and entrapped inside Na-alginate hydrogel (Alg@Cu(2)O-Sb(2)O(3)). The developed Alg@Cu(2)O-Sb(2)O(3) was used as catalytic reactor for the reduction of 4-nitrophenol (4-NP), 2-nitrophenol (2-NP), 2,6-dinitrophenol (2,6-DNP), methyl orange (MO), congo red (CR), acridine orange (AO), methylene blue (MB) and potassium ferricyanide (K(3)[Fe(CN)(6)]). Alg@Cu(2)O-Sb(2)O(3) was found to be selective and more efficient for the reduction of 2-NP among all the pollutants. Therefore, 2-NP was selected for a detailed study to optimize various parameters, e.g., the catalyst amount, reducing agent concentration, 2-NP concentration and recyclability. Alg@Cu(2)O-Sb(2)O(3) was found to be very stable and easily recyclable for the reduction of 2-NP. The Alg@Cu(2)O-Sb(2)O(3) nanocatalyst reduced 2-NP in 1.0 min, having a rate constant of 3.8187 min(-1). FAU - Khan, Sher Bahadar AU - Khan SB AUID- ORCID: 0000-0001-9635-7175 AD - Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia. AD - Center of Excellence for Advanced Materials Research, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia. FAU - Bakhsh, Esraa M AU - Bakhsh EM AD - Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia. FAU - Akhtar, Kalsoom AU - Akhtar K AD - Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia. FAU - Kamal, Tahseen AU - Kamal T AD - Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia. AD - Center of Excellence for Advanced Materials Research, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia. FAU - Shen, Yan AU - Shen Y AD - Wuhan National Laboratory for Optoelectronics, Huazhong University of Science and Technology, Luoyu Road 1037, Wuhan 430074, China. FAU - Asiri, Abdullah M AU - Asiri AM AD - Chemistry Department, Faculty of Science, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia. AD - Center of Excellence for Advanced Materials Research, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia. LA - eng PT - Journal Article DEP - 20220124 PL - Switzerland TA - Polymers (Basel) JT - Polymers JID - 101545357 PMC - PMC8839609 OTO - NOTNLM OT - Na-alginate OT - catalytic reduction OT - dyes OT - environmental applications OT - hydrogel wrapped copper oxide-antimony oxide OT - nitrophenols OT - potassium ferricyanide OT - water treatment COIS- The authors declare no conflict of interest. EDAT- 2022/02/16 06:00 MHDA- 2022/02/16 06:01 PMCR- 2022/01/24 CRDT- 2022/02/15 01:08 PHST- 2021/11/28 00:00 [received] PHST- 2022/01/06 00:00 [revised] PHST- 2022/01/13 00:00 [accepted] PHST- 2022/02/15 01:08 [entrez] PHST- 2022/02/16 06:00 [pubmed] PHST- 2022/02/16 06:01 [medline] PHST- 2022/01/24 00:00 [pmc-release] AID - polym14030458 [pii] AID - polymers-14-00458 [pii] AID - 10.3390/polym14030458 [doi] PST - epublish SO - Polymers (Basel). 2022 Jan 24;14(3):458. doi: 10.3390/polym14030458.