PMID- 35236880
OWN - NLM
STAT- MEDLINE
DCOM- 20220413
LR  - 20220413
IS  - 2045-2322 (Electronic)
IS  - 2045-2322 (Linking)
VI  - 12
IP  - 1
DP  - 2022 Mar 2
TI  - Determination, residue analysis and risk assessment of thiacloprid and 
      spirotetramat in cowpeas under field conditions.
PG  - 3470
LID - 10.1038/s41598-022-07119-1 [doi]
LID - 3470
AB  - The dissipation and residue levels of thiacloprid, spirotetramat and its four 
      metabolites residues in cowpeas were investigated under field conditions. The 
      QuEChERS technique with high-performance liquid chromatography tandem mass 
      spectrometry (HPLC-MS/MS) was used to detect thiacloprid, spirotetramat and its 
      four metabolites residues content in cowpeas. The recoveries were 81.3-95.1% at a 
      spike level of 0.005-0.5 mg/kg, the relative standard deviations (RSDs) were 
      2.1-9.5%. The dissipation kinetics data showed that thiacloprid and spirotetramat 
      in cowpeas were degraded with the half-lives of 1.14-1.54 days and 
      1.25-2.79 days. The terminal residues of thiacloprid and spirotetramat were 
      0.0255-0.4570 mg kg(-1) and 0.0314-0.3070 mg kg(-1) after application 2 times 
      with a pre-harvest interval (PHI) of 3 days under the designed dosages. The 
      chronic and acute dietary exposure assessment risk quotient (RQ) values of 
      thiacloprid in cowpeas for different consumers were 2.44-4.41% and 8.72-15.78%, 
      respectively, and those of spirotetramat were 1.03-1.87% and 0.18-0.32%, 
      respectively, all of the RQ values were lower than 100%. The dietary risk of 
      thiacloprid through cowpeas to consumers was higher than spirotetramat. The 
      results from this study are important reference for Chinese governments to 
      develop criteria for the safe and rational use of thiacloprid and spirotetramat, 
      setting maximum residue levels (MRLs), monitoring the quality safety of 
      agricultural products and protecting consumer health.
CI  - (c) 2022. The Author(s).
FAU - Li, Kailong
AU  - Li K
AD  - Hunan Plant Protection Institute, Hunan Academy of Agricultural Science, 
      Changsha, 410125, Hunan, People's Republic of China. lannuolkl@foxmail.com.
FAU - Chen, Wuying
AU  - Chen W
AD  - Hunan Plant Protection Institute, Hunan Academy of Agricultural Science, 
      Changsha, 410125, Hunan, People's Republic of China.
FAU - Xiang, Wei
AU  - Xiang W
AD  - Crop Research Institute, Hunan Academy of Agricultural Science, Changsha, 410125, 
      Hunan, People's Republic of China.
FAU - Chen, Tongqiang
AU  - Chen T
AD  - Hunan Testing Institute of Product and Commodity Supervision, Changsha, 410017, 
      Hunan, People's Republic of China.
FAU - Zhang, Min
AU  - Zhang M
AD  - Hunan Plant Protection Institute, Hunan Academy of Agricultural Science, 
      Changsha, 410125, Hunan, People's Republic of China.
FAU - Ning, Ying
AU  - Ning Y
AD  - Hunan Plant Protection Institute, Hunan Academy of Agricultural Science, 
      Changsha, 410125, Hunan, People's Republic of China.
FAU - Liu, Yong
AU  - Liu Y
AD  - Hunan Plant Protection Institute, Hunan Academy of Agricultural Science, 
      Changsha, 410125, Hunan, People's Republic of China.
FAU - Chen, Ang
AU  - Chen A
AD  - Hunan Plant Protection Institute, Hunan Academy of Agricultural Science, 
      Changsha, 410125, Hunan, People's Republic of China. angchen2006@163.com.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20220302
PL  - England
TA  - Sci Rep
JT  - Scientific reports
JID - 101563288
RN  - 0 (Aza Compounds)
RN  - 0 (Neonicotinoids)
RN  - 0 (Pesticide Residues)
RN  - 0 (Spiro Compounds)
RN  - 0 (Thiazines)
RN  - 4G7KR034OX (spirotetramat)
RN  - DSV3A944A4 (thiacloprid)
SB  - IM
MH  - Aza Compounds
MH  - China
MH  - Half-Life
MH  - Neonicotinoids
MH  - *Pesticide Residues/analysis
MH  - Risk Assessment
MH  - Spiro Compounds
MH  - Tandem Mass Spectrometry/methods
MH  - Thiazines
MH  - *Vigna/chemistry
PMC - PMC8891356
COIS- The authors declare no competing interests.
EDAT- 2022/03/04 06:00
MHDA- 2022/04/14 06:00
PMCR- 2022/03/02
CRDT- 2022/03/03 05:33
PHST- 2021/10/08 00:00 [received]
PHST- 2022/02/14 00:00 [accepted]
PHST- 2022/03/03 05:33 [entrez]
PHST- 2022/03/04 06:00 [pubmed]
PHST- 2022/04/14 06:00 [medline]
PHST- 2022/03/02 00:00 [pmc-release]
AID - 10.1038/s41598-022-07119-1 [pii]
AID - 7119 [pii]
AID - 10.1038/s41598-022-07119-1 [doi]
PST - epublish
SO  - Sci Rep. 2022 Mar 2;12(1):3470. doi: 10.1038/s41598-022-07119-1.