PMID- 35302750
OWN - NLM
STAT- MEDLINE
DCOM- 20231026
LR  - 20231026
IS  - 1520-5126 (Electronic)
IS  - 0002-7863 (Linking)
VI  - 144
IP  - 12
DP  - 2022 Mar 30
TI  - Fluorescent TPE Macrocycle Relayed Light-Harvesting System for Bright 
      Customized-Color Circularly Polarized Luminescence.
PG  - 5389-5399
LID - 10.1021/jacs.1c12767 [doi]
AB  - Artificial systems for sequential chirality transmission/amplification and energy 
      relay are perpetual topics that entail learning from nature. However, engineering 
      chiral light-harvesting supramolecular systems remains a challenge. Here, we 
      developed new chiral light-harvesting systems with a sequential Forster resonance 
      energy transfer process where a designed blue-violet-emitting BINOL 
      (1,1'-Bi-2-naphthol) compound, BINOL-di-octadecylamide (BDA), functions as an 
      initiator of chirality and light absorbance, a new green-emitting hexagonal 
      tetraphenylethene-based macrocycle (TPEM) with aggregation-induced emission 
      serves as a conveyor, and Nile red (NiR) or/and a near-infrared dye, 
      tetraphenylethene (TPE)-based benzoselenodiazole (TPESe), are the terminal 
      acceptors. Benefiting from the close contact and large optical overlap between 
      donors and acceptors at each level, triad and tetrad relaying systems 
      sequentially and efficiently furnish chirality transmission/amplification and 
      energy transfer along the cascaded line BDA-TPEM-NiR (or/and TPESe), leading to 
      bright customized-color circularly polarized luminescence (CPL) and bright 
      white-light-emitting CPL (CIE coordinates: 0.33, 0.34) with an amplified 
      dissymmetry factor (g(lum)) of 3.5 x 10(-2) over a wide wavelength range. This 
      work provides a new direction for the construction of chiral light-harvesting 
      systems for a broad range of applications in chiroptical physics and chemistry.
FAU - Yuan, Ying-Xue
AU  - Yuan YX
AD  - Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan 
      International Joint Laboratory of Tumor Theranostical Cluster Materials, Green 
      Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou 
      450001, China.
AD  - Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry 
      of Education, School of Chemistry and Chemical Engineering, Huazhong University 
      of Science and Technology, Wuhan 430074, China.
FAU - Jia, Jing-Hui
AU  - Jia JH
AD  - Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan 
      International Joint Laboratory of Tumor Theranostical Cluster Materials, Green 
      Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou 
      450001, China.
FAU - Song, Yu-Pan
AU  - Song YP
AD  - Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan 
      International Joint Laboratory of Tumor Theranostical Cluster Materials, Green 
      Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou 
      450001, China.
FAU - Ye, Feng-Ying
AU  - Ye FY
AD  - Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry 
      of Education, School of Chemistry and Chemical Engineering, Huazhong University 
      of Science and Technology, Wuhan 430074, China.
FAU - Zheng, Yan-Song
AU  - Zheng YS
AUID- ORCID: 0000-0002-1807-4580
AD  - Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry 
      of Education, School of Chemistry and Chemical Engineering, Huazhong University 
      of Science and Technology, Wuhan 430074, China.
FAU - Zang, Shuang-Quan
AU  - Zang SQ
AUID- ORCID: 0000-0002-6728-0559
AD  - Henan Key Laboratory of Crystalline Molecular Functional Materials, Henan 
      International Joint Laboratory of Tumor Theranostical Cluster Materials, Green 
      Catalysis Center, and College of Chemistry, Zhengzhou University, Zhengzhou 
      450001, China.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20220318
PL  - United States
TA  - J Am Chem Soc
JT  - Journal of the American Chemical Society
JID - 7503056
RN  - 0 (Coloring Agents)
SB  - IM
MH  - *Coloring Agents
MH  - Fluorescence Resonance Energy Transfer
MH  - *Luminescence
EDAT- 2022/03/19 06:00
MHDA- 2022/04/29 06:00
CRDT- 2022/03/18 17:15
PHST- 2022/03/19 06:00 [pubmed]
PHST- 2022/04/29 06:00 [medline]
PHST- 2022/03/18 17:15 [entrez]
AID - 10.1021/jacs.1c12767 [doi]
PST - ppublish
SO  - J Am Chem Soc. 2022 Mar 30;144(12):5389-5399. doi: 10.1021/jacs.1c12767. Epub 
      2022 Mar 18.