PMID- 35339080
OWN - NLM
STAT- MEDLINE
DCOM- 20220504
LR  - 20220504
IS  - 1873-7072 (Electronic)
IS  - 0308-8146 (Linking)
VI  - 386
DP  - 2022 Aug 30
TI  - QuEChERS-based analytical methods developed for LC-MS/MS multiresidue 
      determination of pesticides in representative crop fatty matrices: Olives and 
      sunflower seeds.
PG  - 132558
LID - S0308-8146(22)00520-9 [pii]
LID - 10.1016/j.foodchem.2022.132558 [doi]
AB  - Oilseed crops are greatly extended all over the world. Their high fat content can 
      interfere during pesticide multiresidue analysis through liquid 
      chromatography-tandem mass spectrometry (LC-MS/MS). This work aimed at overcoming 
      this issue by developing and validating two QuEChERS-based methods for LC-MS/MS 
      determination of 42 pesticides in two fatty food matrices: olives and sunflower 
      seeds. Optimization of the extraction method was achieved following a 2(6-2) 
      fractional factorial design in a highly cost-effective way. Validation of the 
      multi-residue methods demonstrated improved limits of detection, below the 
      established maximum residue levels (MRLs) for almost all compounds, good 
      precision, and trueness, in compliance with SANTE guidelines. Application of 
      these methods to the analysis of real samples from the Iberian Peninsula showed 
      the presence of some pesticides of relevant environmental concern, including four 
      compounds contained in the Pesticide Action Network International list of highly 
      hazardous pesticides, found at levels between 0.03 ng/g and 104 ng/g.
CI  - Copyright (c) 2022 The Authors. Published by Elsevier Ltd.. All rights reserved.
FAU - Garcia-Vara, Manuel
AU  - Garcia-Vara M
AD  - Water, Environmental and Food Chemistry Unit (ENFOCHEM), Department of 
      Environmental Chemistry, Institute of Environmental Assessment and Water Research 
      (IDAEA-CSIC), C/ Jordi Girona 18-26, 08034 Barcelona, Spain.
FAU - Postigo, Cristina
AU  - Postigo C
AD  - Water, Environmental and Food Chemistry Unit (ENFOCHEM), Department of 
      Environmental Chemistry, Institute of Environmental Assessment and Water Research 
      (IDAEA-CSIC), C/ Jordi Girona 18-26, 08034 Barcelona, Spain.
FAU - Palma, Patricia
AU  - Palma P
AD  - Department of Technologies and Applied Sciences, Polytechnic Institute of Beja, 
      Portugal; Institute of Earth Sciences, University of Evora, Evora, Portugal.
FAU - Bleda, Maria Jose
AU  - Bleda MJ
AD  - Institute for Advanced Chemistry of Catalonia (IQAC-CSIC), Jordi Girona 18-26, 
      E-08034 Barcelona, Spain.
FAU - Lopez de Alda, Miren
AU  - Lopez de Alda M
AD  - Water, Environmental and Food Chemistry Unit (ENFOCHEM), Department of 
      Environmental Chemistry, Institute of Environmental Assessment and Water Research 
      (IDAEA-CSIC), C/ Jordi Girona 18-26, 08034 Barcelona, Spain. Electronic address: 
      miren.lopezdealda@idaea.csic.es.
LA  - eng
PT  - Journal Article
DEP - 20220225
PL  - England
TA  - Food Chem
JT  - Food chemistry
JID - 7702639
RN  - 0 (Pesticide Residues)
RN  - 0 (Pesticides)
SB  - IM
MH  - Chromatography, Liquid/methods
MH  - *Helianthus
MH  - *Olea/chemistry
MH  - *Pesticide Residues/analysis
MH  - *Pesticides/analysis
MH  - Seeds/chemistry
MH  - Solid Phase Extraction
MH  - Tandem Mass Spectrometry/methods
OTO - NOTNLM
OT  - Agrochemicals
OT  - Herbicides
OT  - Insecticides
OT  - Liquid chromatography-tandem mass spectrometry
OT  - Pesticide residue analysis
OT  - Sample pre-treatment
EDAT- 2022/03/27 06:00
MHDA- 2022/05/06 06:00
CRDT- 2022/03/26 20:12
PHST- 2021/08/19 00:00 [received]
PHST- 2022/02/23 00:00 [revised]
PHST- 2022/02/23 00:00 [accepted]
PHST- 2022/03/27 06:00 [pubmed]
PHST- 2022/05/06 06:00 [medline]
PHST- 2022/03/26 20:12 [entrez]
AID - S0308-8146(22)00520-9 [pii]
AID - 10.1016/j.foodchem.2022.132558 [doi]
PST - ppublish
SO  - Food Chem. 2022 Aug 30;386:132558. doi: 10.1016/j.foodchem.2022.132558. Epub 2022 
      Feb 25.