PMID- 35392418 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20220409 IS - 2296-2646 (Print) IS - 2296-2646 (Electronic) IS - 2296-2646 (Linking) VI - 10 DP - 2022 TI - In Situ Reduced Graphene Oxide and Polyvinyl Alcohol Nanocomposites With Enhanced Multiple Properties. PG - 856556 LID - 10.3389/fchem.2022.856556 [doi] LID - 856556 AB - The nanocomposites formed by graphene oxide (GO) and carbazate-modified polyvinyl alcohol (PVA-N) were developed to investigate their multiple properties for wide applications. Their physicochemical characterizations confirmed that the in situ reduced GO (rGO) not only decreased the crystallization but also induced the porous structures inside the nanocomposites. Significantly, it revealed that the comprehensive performance of PVA-N2-2%GO consisted of PVA-N2 with the carbazate degree of substitution (DS) of 7% and the weight ratio (wt%) of 2% GO displayed 79% of tensile elongation and tensile strength of 5.96 N/mm(2) (MPa) by tensile testing, glass transition temperature (Tg) of 60.8 degrees C and decomposition temperature (Td) of 303.5 degrees C by TGA and DSC, surface contact angle at 89.4 +/- 2.1 degrees , and electrical conductivity of 9.95 x 10(-11) S/cm. The abovementioned comprehensive performance was enhanced with the increased amount of in situ rGO, contributed by the high DS of the carbazate group in PVA-N and high amount of GO. The rGO by in situ reduction was the main driving force for enhancing the multiple properties inside the nanocomposites. CI - Copyright (c) 2022 Hu, Liu, Wang, Feng, Gao and Song. FAU - Hu, Wenwen AU - Hu W AD - Guangxi Engineering Center in Biomedical Materials for Tissue and Organ Regeneration, the First Affiliated Hospital of Guangxi Medical University, Nanning, China. AD - Guangxi Collaborative Innovation Center of Regenerative Medicine and Medical Bioresource Development and Application, the First Affiliated Hospital of Guangxi Medical University, Nanning, China. FAU - Liu, Shuhan AU - Liu S AD - Guangxi Engineering Center in Biomedical Materials for Tissue and Organ Regeneration, the First Affiliated Hospital of Guangxi Medical University, Nanning, China. AD - Guangxi Collaborative Innovation Center of Regenerative Medicine and Medical Bioresource Development and Application, the First Affiliated Hospital of Guangxi Medical University, Nanning, China. FAU - Wang, Zhonghai AU - Wang Z AD - Information and Management College, Guangxi Medical University, Nanning, China. FAU - Feng, Xianjing AU - Feng X AD - Guangxi Engineering Center in Biomedical Materials for Tissue and Organ Regeneration, the First Affiliated Hospital of Guangxi Medical University, Nanning, China. AD - Pharmaceutical College, Guangxi Medical University, Nanning, China. FAU - Gao, Ming AU - Gao M AD - Guangxi Engineering Center in Biomedical Materials for Tissue and Organ Regeneration, the First Affiliated Hospital of Guangxi Medical University, Nanning, China. AD - Guangxi Collaborative Innovation Center of Regenerative Medicine and Medical Bioresource Development and Application, the First Affiliated Hospital of Guangxi Medical University, Nanning, China. FAU - Song, Fangming AU - Song F AD - Guangxi Engineering Center in Biomedical Materials for Tissue and Organ Regeneration, the First Affiliated Hospital of Guangxi Medical University, Nanning, China. AD - Guangxi Collaborative Innovation Center of Regenerative Medicine and Medical Bioresource Development and Application, the First Affiliated Hospital of Guangxi Medical University, Nanning, China. LA - eng PT - Journal Article DEP - 20220322 PL - Switzerland TA - Front Chem JT - Frontiers in chemistry JID - 101627988 PMC - PMC8980314 OTO - NOTNLM OT - electrical conductivity OT - graphene oxide1 OT - in situ reduction OT - nanocomposites OT - polyvinyl alcohol COIS- The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest. EDAT- 2022/04/09 06:00 MHDA- 2022/04/09 06:01 PMCR- 2022/01/01 CRDT- 2022/04/08 05:21 PHST- 2022/01/18 00:00 [received] PHST- 2022/02/28 00:00 [accepted] PHST- 2022/04/08 05:21 [entrez] PHST- 2022/04/09 06:00 [pubmed] PHST- 2022/04/09 06:01 [medline] PHST- 2022/01/01 00:00 [pmc-release] AID - 856556 [pii] AID - 10.3389/fchem.2022.856556 [doi] PST - epublish SO - Front Chem. 2022 Mar 22;10:856556. doi: 10.3389/fchem.2022.856556. eCollection 2022.