PMID- 35407795 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20220419 IS - 1996-1944 (Print) IS - 1996-1944 (Electronic) IS - 1996-1944 (Linking) VI - 15 IP - 7 DP - 2022 Mar 27 TI - Microstructure and Antimicrobial Properties of Zr-Cu-Ti Thin-Film Metallic Glass Deposited Using High-Power Impulse Magnetron Sputtering. LID - 10.3390/ma15072461 [doi] LID - 2461 AB - Zr-Cu based thin-film metallic glass (TFMG) has good glass-forming ability and the addition of a third element can create a chaotic system capable of inhibiting the nucleation and growth of crystals. This study focused on TFMGs made with Zr, Cu, and Ti in various compositions deposited via high-impulse magnetron sputtering on silicon and 304 stainless-steel substrates. Detailed analysis was performed on the microstructure and surface characteristics of the resulting coatings. Transmission electron microscopy revealed that the multilayer structure changed to a nanocrystalline structure similar to an amorphous coating. The excellent hydrophobicity of Zr-Cu-Ti TFMGs can be attributed to their ultra-smooth surface without any grain boundaries. The excellent antimicrobial effects can be attributed to a hydrophobic surface resisting cell adhesion and the presence of copper ions, which are lethal to microbes. FAU - Tang, Jian-Fu AU - Tang JF AD - Department of Electro-Optical Engineering, National Taipei University of Technology, Taipei City 106, Taiwan. FAU - Huang, Po-Yuan AU - Huang PY AD - Department of Materials Engineering, Ming Chi University of Technology, New Taipei City 243, Taiwan. FAU - Lin, Ja-Hon AU - Lin JH AUID- ORCID: 0000-0003-3271-7033 AD - Department of Electro-Optical Engineering, National Taipei University of Technology, Taipei City 106, Taiwan. FAU - Liu, Ting-Wei AU - Liu TW AD - Department of Materials Engineering, Ming Chi University of Technology, New Taipei City 243, Taiwan. FAU - Yang, Fu-Chi AU - Yang FC AD - Center for Plasma and Thin Film Technologies, Ming Chi University of Technology, New Taipei City 243, Taiwan. FAU - Chang, Chi-Lung AU - Chang CL AUID- ORCID: 0000-0003-2448-1163 AD - Department of Materials Engineering, Ming Chi University of Technology, New Taipei City 243, Taiwan. AD - Center for Plasma and Thin Film Technologies, Ming Chi University of Technology, New Taipei City 243, Taiwan. LA - eng GR - MOST 109-2221-E-131-019, MOST 109-2622-E-131- 003-CC3, MOST 110-2221-E-131-006 and MOST 110-2222-E-027-008- MY3./Ministry of Science and Technology Taiwan/ PT - Journal Article DEP - 20220327 PL - Switzerland TA - Materials (Basel) JT - Materials (Basel, Switzerland) JID - 101555929 PMC - PMC8999468 OTO - NOTNLM OT - TFMGs OT - ZrCuTi OT - antimicrobial effect OT - multilayer OT - nanocrystalline COIS- The authors declare no conflict of interest. EDAT- 2022/04/13 06:00 MHDA- 2022/04/13 06:01 PMCR- 2022/03/27 CRDT- 2022/04/12 01:08 PHST- 2022/03/07 00:00 [received] PHST- 2022/03/25 00:00 [revised] PHST- 2022/03/25 00:00 [accepted] PHST- 2022/04/12 01:08 [entrez] PHST- 2022/04/13 06:00 [pubmed] PHST- 2022/04/13 06:01 [medline] PHST- 2022/03/27 00:00 [pmc-release] AID - ma15072461 [pii] AID - materials-15-02461 [pii] AID - 10.3390/ma15072461 [doi] PST - epublish SO - Materials (Basel). 2022 Mar 27;15(7):2461. doi: 10.3390/ma15072461.