PMID- 35446656
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20220425
LR  - 20220506
IS  - 1095-9203 (Electronic)
IS  - 0036-8075 (Linking)
VI  - 376
IP  - 6591
DP  - 2022 Apr 22
TI  - Organometallic-functionalized interfaces for highly efficient inverted perovskite 
      solar cells.
PG  - 416-420
LID - 10.1126/science.abm8566 [doi]
AB  - Further enhancing the performance and stability of inverted perovskite solar 
      cells (PSCs) is crucial for their commercialization. We report that the 
      functionalization of multication and halide perovskite interfaces with an 
      organometallic compound, ferrocenyl-bis-thiophene-2-carboxylate (FcTc(2)), 
      simultaneously enhanced the efficiency and stability of inverted PSCs. The 
      resultant devices achieved a power conversion efficiency of 25.0% and maintained 
      >98% of their initial efficiency after continuously operating at the maximum 
      power point for 1500 hours under simulated AM1.5 illumination. Moreover, the 
      FcTc(2)-functionalized devices passed the international standards for mature 
      photovoltaics (IEC61215:2016) and have exhibited high stability under the damp 
      heat test (85 degrees C and 85% relative humidity).
FAU - Li, Zhen
AU  - Li Z
AUID- ORCID: 0000-0003-2756-321X
AD  - Department of Chemistry, City University of Hong Kong, Kowloon 999077, Hong Kong.
FAU - Li, Bo
AU  - Li B
AUID- ORCID: 0000-0001-7844-8161
AD  - Department of Chemistry, City University of Hong Kong, Kowloon 999077, Hong Kong.
FAU - Wu, Xin
AU  - Wu X
AUID- ORCID: 0000-0003-2513-1296
AD  - Department of Chemistry, City University of Hong Kong, Kowloon 999077, Hong Kong.
FAU - Sheppard, Stephanie A
AU  - Sheppard SA
AD  - Department of Chemistry, Imperial College London, White City Campus, London, UK.
FAU - Zhang, Shoufeng
AU  - Zhang S
AUID- ORCID: 0000-0001-6034-5041
AD  - Department of Chemistry, City University of Hong Kong, Kowloon 999077, Hong Kong.
FAU - Gao, Danpeng
AU  - Gao D
AD  - Department of Chemistry, City University of Hong Kong, Kowloon 999077, Hong Kong.
FAU - Long, Nicholas J
AU  - Long NJ
AUID- ORCID: 0000-0002-8298-938X
AD  - Department of Chemistry, Imperial College London, White City Campus, London, UK.
FAU - Zhu, Zonglong
AU  - Zhu Z
AUID- ORCID: 0000-0002-8285-9665
AD  - Department of Chemistry, City University of Hong Kong, Kowloon 999077, Hong Kong.
AD  - Hong Kong Institute of Clean Energy, City University of Hong Kong, Kowloon 
      999077, Hong Kong.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20220421
PL  - United States
TA  - Science
JT  - Science (New York, N.Y.)
JID - 0404511
SB  - IM
EDAT- 2022/04/22 06:00
MHDA- 2022/04/26 06:00
CRDT- 2022/04/21 17:11
PHST- 2022/04/21 17:11 [entrez]
PHST- 2022/04/22 06:00 [pubmed]
PHST- 2022/04/26 06:00 [medline]
AID - 10.1126/science.abm8566 [doi]
PST - ppublish
SO  - Science. 2022 Apr 22;376(6591):416-420. doi: 10.1126/science.abm8566. Epub 2022 
      Apr 21.