PMID- 35452989
OWN - NLM
STAT- MEDLINE
DCOM- 20220517
LR  - 20220519
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 434
DP  - 2022 Jul 15
TI  - Humic acid promoted activation of peroxymonosulfate by Fe(3)S(4) for degradation 
      of 2,4,6-trichlorophenol: An experimental and theoretical study.
PG  - 128913
LID - S0304-3894(22)00702-6 [pii]
LID - 10.1016/j.jhazmat.2022.128913 [doi]
AB  - Chlorophenols are difficult to degrade and biohazardous in the natural 
      environment. This study demonstrated that humic acid (HA) could promote Fe(3)S(4) 
      activation of peroxymonosulfate (PMS) to degrade 2,4,6-trichlorophenol (TCP), the 
      degradation efficiency of TCP was increased by 33%. The system of 
      Fe(3)S(4)-HA/PMS produced more reactive oxygen species, and *OH was the dominant 
      ROS. The genealogy of iron oxides together with S(0) on the Fe(3)S(4) surface 
      inhibited PMS activation leading to the significant reduction of TCP degraded (< 
      70%). These problems could be solved successfully through introducing HA, which 
      facilitated electron transfer and increased the continuous release of iron ions 
      by 2 times. In accordance with the determined density functional theory (DFT), 
      the degradation pathway was put forward, which indicated that TCP dechlorination 
      and oxidation to 2,6-dichloro-1,4-benzoquinone constituted the main degradation 
      pathway. Furthermore, the intermediates that were produced in the main 
      degradation processes of TCP showed lower toxicity than TCP according to results 
      that were obtained utilizing the calculations of quantitative structure-activity 
      relationship (QSAR) together with Toxicity Estimation Software Tool (TEST). Thus, 
      the Fe(3)S(4)-HA/PMS system was demonstrated to be an efficient and safe 
      technology for organic pollutant degradation in contaminated groundwater and 
      surface water environments.
CI  - Copyright (c) 2022 Elsevier B.V. All rights reserved.
FAU - Zhang, Jin
AU  - Zhang J
AD  - Institute for Environmental pollution and health, School of Environmental and 
      Chemical Engineering, Shanghai University, Shanghai 200444, PR China.
FAU - Wang, Chen
AU  - Wang C
AD  - Institute for Environmental pollution and health, School of Environmental and 
      Chemical Engineering, Shanghai University, Shanghai 200444, PR China. Electronic 
      address: wangchen0227@shu.edu.cn.
FAU - Huang, Nannan
AU  - Huang N
AD  - State Key Laboratory of Environmental Criteria and Risk Assessment, Chinese 
      Research Academy of Environmental Sciences, Beijing 10012, China.
FAU - Xiang, Minghui
AU  - Xiang M
AD  - Institute for Environmental pollution and health, School of Environmental and 
      Chemical Engineering, Shanghai University, Shanghai 200444, PR China.
FAU - Jin, Lide
AU  - Jin L
AD  - Institute for Environmental pollution and health, School of Environmental and 
      Chemical Engineering, Shanghai University, Shanghai 200444, PR China.
FAU - Yang, Zhiyuan
AU  - Yang Z
AD  - Institute for Environmental pollution and health, School of Environmental and 
      Chemical Engineering, Shanghai University, Shanghai 200444, PR China.
FAU - Li, Siyang
AU  - Li S
AD  - Institute for Environmental pollution and health, School of Environmental and 
      Chemical Engineering, Shanghai University, Shanghai 200444, PR China.
FAU - Lu, Zhen
AU  - Lu Z
AD  - Institute for Environmental pollution and health, School of Environmental and 
      Chemical Engineering, Shanghai University, Shanghai 200444, PR China.
FAU - Shi, Chongli
AU  - Shi C
AD  - Institute for Environmental pollution and health, School of Environmental and 
      Chemical Engineering, Shanghai University, Shanghai 200444, PR China.
FAU - Cheng, Biao
AU  - Cheng B
AD  - Institute for Environmental pollution and health, School of Environmental and 
      Chemical Engineering, Shanghai University, Shanghai 200444, PR China.
FAU - Xie, Haijiao
AU  - Xie H
AD  - Hangzhou Yanqu Information Technology Co., Ltd., Hangzhou, Zhejiang Province, 
      310003, PR China.
FAU - Li, Hui
AU  - Li H
AD  - Institute for Environmental pollution and health, School of Environmental and 
      Chemical Engineering, Shanghai University, Shanghai 200444, PR China. Electronic 
      address: huili2018@shu.edu.cn.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20220414
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
RN  - 0 (Chlorophenols)
RN  - 0 (Humic Substances)
RN  - 0 (Peroxides)
RN  - 0 (Sulfides)
RN  - 0 (greigite)
RN  - 22047-43-4 (peroxymonosulfate)
RN  - E1UOL152H7 (Iron)
RN  - MHS8C5BAUZ (2,4,6-trichlorophenol)
SB  - IM
MH  - *Chlorophenols
MH  - *Humic Substances
MH  - Iron
MH  - Models, Theoretical
MH  - Peroxides
MH  - Sulfides
OTO - NOTNLM
OT  - 2,4,6-trichlorophenol
OT  - Fe(3)S(4)-HA
OT  - Peroxymonosulfate
OT  - Reusability
EDAT- 2022/04/23 06:00
MHDA- 2022/05/18 06:00
CRDT- 2022/04/22 20:13
PHST- 2022/02/17 00:00 [received]
PHST- 2022/04/05 00:00 [revised]
PHST- 2022/04/11 00:00 [accepted]
PHST- 2022/04/23 06:00 [pubmed]
PHST- 2022/05/18 06:00 [medline]
PHST- 2022/04/22 20:13 [entrez]
AID - S0304-3894(22)00702-6 [pii]
AID - 10.1016/j.jhazmat.2022.128913 [doi]
PST - ppublish
SO  - J Hazard Mater. 2022 Jul 15;434:128913. doi: 10.1016/j.jhazmat.2022.128913. Epub 
      2022 Apr 14.