PMID- 35464822
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220716
IS  - 1083-6160 (Print)
IS  - 1520-586X (Electronic)
IS  - 1083-6160 (Linking)
VI  - 26
IP  - 4
DP  - 2022 Apr 15
TI  - Scale-Up of a Heterogeneous Photocatalytic Degradation Using a Photochemical 
      Rotor-Stator Spinning Disk Reactor.
PG  - 1279-1288
LID - 10.1021/acs.oprd.2c00012 [doi]
AB  - Many chemical reactions contain heterogeneous reagents, products, byproducts, or 
      catalysts, making their transposition from batch to continuous-flow processing 
      challenging. Herein, we report the use of a photochemical rotor-stator spinning 
      disk reactor (pRS-SDR) that can handle and scale solid-containing photochemical 
      reaction conditions in flow. Its ability to handle slurries was showcased for the 
      TiO(2)-mediated aerobic photodegradation of aqueous methylene blue. The use of a 
      fast rotating disk imposes high shear forces on the multiphase reaction mixture, 
      ensuring its homogenization, increasing the mass transfer, and improving the 
      irradiation profile of the reaction mixture. The pRS-SDR performance was also 
      compared to other lab-scale reactors in terms of water treated per reactor volume 
      and light power input.
CI  - (c) 2022 The Authors. Published by American Chemical Society.
FAU - Chaudhuri, Arnab
AU  - Chaudhuri A
AD  - Department of Chemical Engineering and Chemistry, Sustainable Process 
      Engineering, Eindhoven University of Technology (TU/e), 5612 AZ Eindhoven, The 
      Netherlands.
FAU - Zondag, Stefan D A
AU  - Zondag SDA
AUID- ORCID: 0000-0003-1463-4867
AD  - Flow Chemistry Group, van't Hoff Institute for Molecular Sciences (HIMS), 
      Universiteit van Amsterdam (UvA), 1098 XH Amsterdam, The Netherlands.
FAU - Schuurmans, Jasper H A
AU  - Schuurmans JHA
AD  - Department of Chemical Engineering and Chemistry, Sustainable Process 
      Engineering, Eindhoven University of Technology (TU/e), 5612 AZ Eindhoven, The 
      Netherlands.
FAU - van der Schaaf, John
AU  - van der Schaaf J
AUID- ORCID: 0000-0002-2856-8592
AD  - Department of Chemical Engineering and Chemistry, Sustainable Process 
      Engineering, Eindhoven University of Technology (TU/e), 5612 AZ Eindhoven, The 
      Netherlands.
FAU - Noel, Timothy
AU  - Noel T
AUID- ORCID: 0000-0002-3107-6927
AD  - Flow Chemistry Group, van't Hoff Institute for Molecular Sciences (HIMS), 
      Universiteit van Amsterdam (UvA), 1098 XH Amsterdam, The Netherlands.
LA  - eng
PT  - Journal Article
PT  - Review
DEP - 20220301
PL  - United States
TA  - Org Process Res Dev
JT  - Organic process research & development
JID - 9890443
PMC - PMC9017180
COIS- The authors declare no competing financial interest.
EDAT- 2022/04/26 06:00
MHDA- 2022/04/26 06:01
PMCR- 2022/04/19
CRDT- 2022/04/25 05:39
PHST- 2022/01/14 00:00 [received]
PHST- 2022/04/25 05:39 [entrez]
PHST- 2022/04/26 06:00 [pubmed]
PHST- 2022/04/26 06:01 [medline]
PHST- 2022/04/19 00:00 [pmc-release]
AID - 10.1021/acs.oprd.2c00012 [doi]
PST - ppublish
SO  - Org Process Res Dev. 2022 Apr 15;26(4):1279-1288. doi: 10.1021/acs.oprd.2c00012. 
      Epub 2022 Mar 1.