PMID- 35466514
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220628
IS  - 1521-3773 (Electronic)
IS  - 1433-7851 (Linking)
VI  - 61
IP  - 27
DP  - 2022 Jul 4
TI  - Pushing Lithium-Sulfur Batteries towards Practical Working Conditions through a 
      Cathode-Electrolyte Synergy.
PG  - e202203466
LID - 10.1002/anie.202203466 [doi]
AB  - The commercialization of lithium-sulfur (Li-S) batteries is still hindered by the 
      unsatisfactory cell performance under practical working conditions, which is 
      mainly caused by the sluggish cathode redox kinetics, severe polysulfide 
      shuttling, and poor Li stripping/plating reversibility. Herein, we report an 
      effective strategy by combining Se-doped S hosted in an ordered macroporous 
      framework with a highly fluorinated ether (HFE)-based electrolyte to 
      simultaneously address the aforementioned issues in both cathode and anode. A 
      reversible and stable high areal capacity of >5.4 mAh cm(-2) with high Coulombic 
      efficiency >99.2 % can be achieved under high areal Se/S loading (5.8 mg cm(-2) 
      ), while the underlying mechanism was further revealed through synchrotron X-ray 
      probes and Time-of-Flight Secondary Ion Mass Spectrometry (ToF-SIMS). The 
      practical application potential was further evaluated at low (0  degrees C) and high 
      (55  degrees C) temperatures under high areal Se/S loading (>5.0 mg cm(-2) ) and thin Li 
      metal (40 mum).
CI  - (c) 2022 Wiley-VCH GmbH.
FAU - Zhao, Chen
AU  - Zhao C
AD  - Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S 
      Cass Ave, Lemont, IL 60439, USA.
FAU - Daali, Amine
AU  - Daali A
AD  - Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S 
      Cass Ave, Lemont, IL 60439, USA.
FAU - Hwang, Inhui
AU  - Hwang I
AD  - X-ray Sciences Division, Argonne National Laboratory, 9700 S Cass Ave, Lemont, IL 
      60439, USA.
FAU - Li, Tianyi
AU  - Li T
AD  - X-ray Sciences Division, Argonne National Laboratory, 9700 S Cass Ave, Lemont, IL 
      60439, USA.
FAU - Huang, Xingkang
AU  - Huang X
AD  - Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S 
      Cass Ave, Lemont, IL 60439, USA.
FAU - Robertson, David
AU  - Robertson D
AD  - Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S 
      Cass Ave, Lemont, IL 60439, USA.
FAU - Yang, Zhenzhen
AU  - Yang Z
AD  - Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S 
      Cass Ave, Lemont, IL 60439, USA.
FAU - Trask, Steve
AU  - Trask S
AD  - Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S 
      Cass Ave, Lemont, IL 60439, USA.
FAU - Xu, Wenqian
AU  - Xu W
AD  - X-ray Sciences Division, Argonne National Laboratory, 9700 S Cass Ave, Lemont, IL 
      60439, USA.
FAU - Sun, Cheng-Jun
AU  - Sun CJ
AD  - X-ray Sciences Division, Argonne National Laboratory, 9700 S Cass Ave, Lemont, IL 
      60439, USA.
FAU - Xu, Gui-Liang
AU  - Xu GL
AUID- ORCID: 0000-0001-9969-883X
AD  - Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S 
      Cass Ave, Lemont, IL 60439, USA.
FAU - Amine, Khalil
AU  - Amine K
AD  - Chemical Sciences and Engineering Division, Argonne National Laboratory, 9700 S 
      Cass Ave, Lemont, IL 60439, USA.
AD  - Materials Science and Engineering, Stanford University, Stanford, CA 94305, USA.
AD  - Institute for Research& Medical Consultations, Imam Abdulrahman Bin Faisal 
      University (IAU), Dammam, Saudi Arabia.
LA  - eng
GR  - DE-AC02-06CH11357/U.S. Department of Energy/
PT  - Journal Article
DEP - 20220505
PL  - Germany
TA  - Angew Chem Int Ed Engl
JT  - Angewandte Chemie (International ed. in English)
JID - 0370543
SB  - IM
OTO - NOTNLM
OT  - Highly Fluorinated Electrolyte
OT  - Li Metal
OT  - Li-S Batteries
OT  - Pouch Cells
OT  - Solid-Electrolyte Interphase
EDAT- 2022/04/26 06:00
MHDA- 2022/04/26 06:01
CRDT- 2022/04/25 06:16
PHST- 2022/03/07 00:00 [received]
PHST- 2022/04/26 06:00 [pubmed]
PHST- 2022/04/26 06:01 [medline]
PHST- 2022/04/25 06:16 [entrez]
AID - 10.1002/anie.202203466 [doi]
PST - ppublish
SO  - Angew Chem Int Ed Engl. 2022 Jul 4;61(27):e202203466. doi: 
      10.1002/anie.202203466. Epub 2022 May 5.