PMID- 35480276
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220716
IS  - 2046-2069 (Electronic)
IS  - 2046-2069 (Linking)
VI  - 11
IP  - 48
DP  - 2021 Sep 6
TI  - Novel hydrophobic deep eutectic solvent for vortex-assisted liquid phase 
      microextraction of common acaricides in fruit juice followed by HPLC-UV 
      determination.
PG  - 30102-30108
LID - 10.1039/d1ra04781g [doi]
AB  - In the present research, several novel and natural hydrophobic deep eutectic 
      solvents (DESs) were prepared using methyltrioctylammonium chloride (MTOAC) as 
      the hydrogen bond acceptor (HBA) and different types of straight chain alcohols 
      as hydrogen bond donors (HBDs). One of the DESs composed of MTOAC and n-butanol 
      was advantageously used to develop a vortex-assisted liquid phase microextraction 
      (VALPME) method combined with high-performance liquid chromatography-ultraviolet 
      detection (HPLC-UV) for the determination of common acaricides in fruit juice 
      samples. Several important parameters influencing extraction efficiency were 
      investigated and optimized, including the type and volume of DES, sample solution 
      pH, effect of salt addition and, extraction and vortex time. Under optimal 
      experimental conditions, the method showed good linearity with the correlation 
      coefficients (R (2)) of 0.9986-0.9991 in the linear range of 2-300 mug L(-1), low 
      limits of detection of 0.5-1 mug L(-1) and acceptable extraction recoveries in the 
      range of 85-93%. The proposed method was successfully applied for the extraction 
      and preconcentration of trace acaricides in real fruit juice samples, and the 
      results demonstrated the potential of the synthesized DESs for the extraction and 
      determination of contaminants in aqueous samples.
CI  - This journal is (c) The Royal Society of Chemistry.
FAU - Rostami-Javanroudi, Setareh
AU  - Rostami-Javanroudi S
AD  - Research Center for Environmental Determinants of Health (RCEDH), Health 
      Institute, Kermanshah University of Medical Sciences Kermanshah Iran 
      n.fattahi@kums.ac.ir +988338263048 +989183364311.
FAU - Moradi, Masoud
AU  - Moradi M
AD  - Research Center for Environmental Determinants of Health (RCEDH), Health 
      Institute, Kermanshah University of Medical Sciences Kermanshah Iran 
      n.fattahi@kums.ac.ir +988338263048 +989183364311.
FAU - Sharafi, Kiomars
AU  - Sharafi K
AD  - Research Center for Environmental Determinants of Health (RCEDH), Health 
      Institute, Kermanshah University of Medical Sciences Kermanshah Iran 
      n.fattahi@kums.ac.ir +988338263048 +989183364311.
FAU - Fattahi, Nazir
AU  - Fattahi N
AUID- ORCID: 0000-0002-6750-7004
AD  - Research Center for Environmental Determinants of Health (RCEDH), Health 
      Institute, Kermanshah University of Medical Sciences Kermanshah Iran 
      n.fattahi@kums.ac.ir +988338263048 +989183364311.
LA  - eng
PT  - Journal Article
DEP - 20210909
PL  - England
TA  - RSC Adv
JT  - RSC advances
JID - 101581657
PMC - PMC9040733
COIS- There are no conflicts to declare.
EDAT- 2022/04/29 06:00
MHDA- 2022/04/29 06:01
PMCR- 2021/09/09
CRDT- 2022/04/28 06:28
PHST- 2021/06/20 00:00 [received]
PHST- 2021/08/31 00:00 [accepted]
PHST- 2022/04/28 06:28 [entrez]
PHST- 2022/04/29 06:00 [pubmed]
PHST- 2022/04/29 06:01 [medline]
PHST- 2021/09/09 00:00 [pmc-release]
AID - d1ra04781g [pii]
AID - 10.1039/d1ra04781g [doi]
PST - epublish
SO  - RSC Adv. 2021 Sep 9;11(48):30102-30108. doi: 10.1039/d1ra04781g. eCollection 2021 
      Sep 6.