PMID- 35487005
OWN - NLM
STAT- MEDLINE
DCOM- 20220530
LR  - 20220531
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 435
DP  - 2022 Aug 5
TI  - A portable solar light-driven biophotoelectrocatalytic system for pollutant 
      removal powered by photovoltaic cells.
PG  - 128989
LID - S0304-3894(22)00778-6 [pii]
LID - 10.1016/j.jhazmat.2022.128989 [doi]
AB  - Photoelectrocatalytic (PEC) technology has been considered as one of the most 
      efficient advanced oxidation processes for wastewater treatment, but the 
      necessity of external electric power supply limits the portability of PEC system 
      for on-field applications. Herein, a portable solar-powered 
      biophotoelectrocatalytic system driven by photovoltaic (PV) cells was explored 
      for degradation of pollutant by coupling BiVO(4)/Fe(2)O(3)-deposited photoanode 
      and horseradish peroxidase (HRP)-immobilized cathode. The integration of PV cells 
      in this PEC device could not only avoid the necessary introduction of external 
      electric power supply, but also improve the utilization of solar irradiation. The 
      characterization of BiVO(4)/Fe(2)O(3) photoanode demonstrates that ultrathin 
      Fe(2)O(3) layer on BiVO(4) electrode could facilitate the holes transfer to the 
      surface efficiently and thus avoid charge recombination. After HRP was 
      immobilized on the cathode, the removal efficiency for 2,4-dichlorophenol 
      (2,4-DCP) was obviously promoted, attributed to the efficient HRP-catalyzed 
      oxidation reaction by in-situ generated H(2)O(2) from PEC process. Under natural 
      solar irradiation, the proposed portable biophotoelectrocatalytic device 
      exhibited a satisfying removal efficiency of 92.0% for 100 ppm of 2,4-DCP after 
      3-h treatment. The intermediate products formed during the degradation process 
      were identified by liquid chromatography-mass spectrometry, and possible 2,4-DCP 
      degradation pathway was also proposed.
CI  - Copyright (c) 2022 Elsevier B.V. All rights reserved.
FAU - Yan, Kai
AU  - Yan K
AD  - Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry 
      of Education), School of Chemistry and Chemical Engineering, Huazhong University 
      of Science and Technology, Luoyu Road 1037, Wuhan 430074, China.
FAU - Liu, Jianqiao
AU  - Liu J
AD  - Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry 
      of Education), School of Chemistry and Chemical Engineering, Huazhong University 
      of Science and Technology, Luoyu Road 1037, Wuhan 430074, China.
FAU - Qin, Jin
AU  - Qin J
AD  - Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry 
      of Education), School of Chemistry and Chemical Engineering, Huazhong University 
      of Science and Technology, Luoyu Road 1037, Wuhan 430074, China.
FAU - Zhang, Jingdong
AU  - Zhang J
AD  - Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry 
      of Education), School of Chemistry and Chemical Engineering, Huazhong University 
      of Science and Technology, Luoyu Road 1037, Wuhan 430074, China. Electronic 
      address: zhangjd@mail.hust.edu.cn.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20220421
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
RN  - 0 (Environmental Pollutants)
RN  - 3WHH0066W5 (Vanadates)
RN  - BBX060AN9V (Hydrogen Peroxide)
RN  - EC 1.11.1.- (Horseradish Peroxidase)
RN  - U015TT5I8H (Bismuth)
SB  - IM
MH  - Bismuth/chemistry
MH  - *Environmental Pollutants
MH  - Horseradish Peroxidase
MH  - Hydrogen Peroxide
MH  - *Solar Energy
MH  - Vanadates/chemistry
OTO - NOTNLM
OT  - 2,4-Dichlorophenol removal
OT  - BiVO(4)/Fe(2)O(3) photoanode
OT  - Peroxidase-catalyzed degradation
OT  - Photoelectrocatalysis
OT  - Solar photovoltaic cells
EDAT- 2022/04/30 06:00
MHDA- 2022/05/31 06:00
CRDT- 2022/04/29 18:13
PHST- 2021/12/17 00:00 [received]
PHST- 2022/03/12 00:00 [revised]
PHST- 2022/04/19 00:00 [accepted]
PHST- 2022/04/30 06:00 [pubmed]
PHST- 2022/05/31 06:00 [medline]
PHST- 2022/04/29 18:13 [entrez]
AID - S0304-3894(22)00778-6 [pii]
AID - 10.1016/j.jhazmat.2022.128989 [doi]
PST - ppublish
SO  - J Hazard Mater. 2022 Aug 5;435:128989. doi: 10.1016/j.jhazmat.2022.128989. Epub 
      2022 Apr 21.