PMID- 35495276
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20231102
IS  - 2046-2069 (Electronic)
IS  - 2046-2069 (Linking)
VI  - 10
IP  - 8
DP  - 2020 Jan 24
TI  - Direct observation of dimethyl sulfide trapped by MOF proving efficient removal 
      of sulfur impurities.
PG  - 4710-4714
LID - 10.1039/c9ra09702c [doi]
AB  - Here, we report the adsorptive removal of trace amounts of dimethyl sulfide (DMS) 
      using metal-organic frameworks (MOFs). Cu(2+)-based MOFs with open metal sites 
      (OMSs), [Cu(3)(btc)(2)] (HKUST-1), where btc = 1,3,5-benzenetricarboxylate, and 
      without OMSs, [Cu(2)(bdc)(2)(dabco)] (Cu-JAST-1), where bdc = 
      1,4-benzenedicarboxylate and dabco = 1,4-diazabicyclo[2.2.2]octane, were 
      investigated for the removal of DMS to compare their performance with that of 
      Ag-Y zeolite, which is currently widely used in industry. HKUST-1 exhibited a 
      considerably higher adsorption capacity for DMS than the other adsorbents, which 
      was confirmed by breakthrough measurements. The adsorption state of DMS with 
      HKUST-1 was directly revealed by single-crystal X-ray diffraction (SXRD) analysis 
      and in situ Raman spectroscopy. In addition, it was shown that DMS can be removed 
      by HKUST-1 even under humid conditions.
CI  - This journal is (c) The Royal Society of Chemistry.
FAU - Morita, Masashi
AU  - Morita M
AUID- ORCID: 0000-0002-0194-3380
AD  - Technology Innovation Division, Panasonic Corporation 3-1-1 Yagumo-naka-machi 
      Moriguchi City Osaka 570-8501 Japan.
AD  - Department of Chemistry and Biotechnology, School of Engineering, Nagoya 
      University Chikusa-ku Nagoya 464-8603 Japan 
      ryotaro.matsuda@chembio.nagoya-u.ac.jp.
FAU - Yonezu, Akira
AU  - Yonezu A
AUID- ORCID: 0000-0003-4455-8973
AD  - Department of Chemistry and Biotechnology, School of Engineering, Nagoya 
      University Chikusa-ku Nagoya 464-8603 Japan 
      ryotaro.matsuda@chembio.nagoya-u.ac.jp.
FAU - Kusaka, Shinpei
AU  - Kusaka S
AUID- ORCID: 0000-0001-7718-4387
AD  - Department of Chemistry and Biotechnology, School of Engineering, Nagoya 
      University Chikusa-ku Nagoya 464-8603 Japan 
      ryotaro.matsuda@chembio.nagoya-u.ac.jp.
FAU - Hori, Akihiro
AU  - Hori A
AUID- ORCID: 0000-0001-9846-8362
AD  - Department of Chemistry and Biotechnology, School of Engineering, Nagoya 
      University Chikusa-ku Nagoya 464-8603 Japan 
      ryotaro.matsuda@chembio.nagoya-u.ac.jp.
FAU - Ma, Yunsheng
AU  - Ma Y
AUID- ORCID: 0000-0002-9438-1232
AD  - Department of Chemistry and Biotechnology, School of Engineering, Nagoya 
      University Chikusa-ku Nagoya 464-8603 Japan 
      ryotaro.matsuda@chembio.nagoya-u.ac.jp.
FAU - Matsuda, Ryotaro
AU  - Matsuda R
AUID- ORCID: 0000-0002-7665-6212
AD  - Department of Chemistry and Biotechnology, School of Engineering, Nagoya 
      University Chikusa-ku Nagoya 464-8603 Japan 
      ryotaro.matsuda@chembio.nagoya-u.ac.jp.
AD  - Institute for Advanced Research, Nagoya University Chikusa-ku Nagoya 464-8603 
      Japan.
LA  - eng
PT  - Journal Article
DEP - 20200129
PL  - England
TA  - RSC Adv
JT  - RSC advances
JID - 101581657
PMC - PMC9049039
COIS- There are no conflicts to declare.
EDAT- 2020/01/29 00:00
MHDA- 2020/01/29 00:01
PMCR- 2020/01/29
CRDT- 2022/05/02 06:39
PHST- 2019/11/20 00:00 [received]
PHST- 2020/01/14 00:00 [accepted]
PHST- 2022/05/02 06:39 [entrez]
PHST- 2020/01/29 00:00 [pubmed]
PHST- 2020/01/29 00:01 [medline]
PHST- 2020/01/29 00:00 [pmc-release]
AID - c9ra09702c [pii]
AID - 10.1039/c9ra09702c [doi]
PST - epublish
SO  - RSC Adv. 2020 Jan 29;10(8):4710-4714. doi: 10.1039/c9ra09702c. eCollection 2020 
      Jan 24.