PMID- 35516273 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20220716 IS - 2046-2069 (Electronic) IS - 2046-2069 (Linking) VI - 10 IP - 73 DP - 2020 Dec 17 TI - Attenuation of Cr/Pb in bauxite leachates by bentonite-polymer composite geosynthetic clay liners. PG - 44672-44678 LID - 10.1039/d0ra06921c [doi] AB - Three commercially available bentonite-polymer composite geosynthetic clay liners (BPC GCLs) were selected for hydraulic conductivity testing, respectively permeated by two types of bauxite leachates with high alkalinity (pH > 12) and high ionic strength (620.3 mM). The influence of BPC GCLs on the attenuation behavior of Cr/Pb in the bauxite leachates was analyzed. The BPC GCLs with a low hydraulic conductivity (k < 10(-10) m s(-1)) retard the migration of Cr and Pb and the Cr had a higher mobility than Pb in the BPC GCLs. Scanning electron microscope (SEM) microstructure analysis showed that the migration and attenuation behavior of Cr/Pb mainly depended on the chemical properties of the leachates, polymer content and the microstructure of the polymer. Higher attenuation of heavy metals was obtained with bauxite leachates having higher ionic strength. Sufficient polymer content is needed to ensure BPC GCLs have adequately low hydraulic conductivity to suppress attenuation of heavy metals. The gelatinous structure associated with hydrated linear or crosslinked polymer diminishes when the polymer in a BPC is in contact with bauxite leachates. Compromising the hydrogel structure promotes polymer elution and leaves pore space open, resulting in attenuation of heavy metals. CI - This journal is (c) The Royal Society of Chemistry. FAU - Li, Qin AU - Li Q AUID- ORCID: 0000-0001-8665-9356 AD - School of Geosciences and Environmental Engineering, Southwest Jiaotong University Chengdu China pdp0330@swjtu.cn. FAU - Peng, Daoping AU - Peng D AD - School of Geosciences and Environmental Engineering, Southwest Jiaotong University Chengdu China pdp0330@swjtu.cn. FAU - Wu, Zheng AU - Wu Z AD - School of Geosciences and Environmental Engineering, Southwest Jiaotong University Chengdu China pdp0330@swjtu.cn. FAU - Huang, Tao AU - Huang T AD - School of Geosciences and Environmental Engineering, Southwest Jiaotong University Chengdu China pdp0330@swjtu.cn. LA - eng PT - Journal Article DEP - 20201217 PL - England TA - RSC Adv JT - RSC advances JID - 101581657 PMC - PMC9058447 COIS- There are no conflicts to declare. EDAT- 2020/12/17 00:00 MHDA- 2020/12/17 00:01 PMCR- 2020/12/17 CRDT- 2022/05/06 05:41 PHST- 2020/08/13 00:00 [received] PHST- 2020/12/03 00:00 [accepted] PHST- 2022/05/06 05:41 [entrez] PHST- 2020/12/17 00:00 [pubmed] PHST- 2020/12/17 00:01 [medline] PHST- 2020/12/17 00:00 [pmc-release] AID - d0ra06921c [pii] AID - 10.1039/d0ra06921c [doi] PST - epublish SO - RSC Adv. 2020 Dec 17;10(73):44672-44678. doi: 10.1039/d0ra06921c. eCollection 2020 Dec 17.