PMID- 35526482
OWN - NLM
STAT- MEDLINE
DCOM- 20220609
LR  - 20220609
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 246
DP  - 2022 Aug 15
TI  - Evaluation of the variation in relative response factors of GC-MS analysis with 
      the internal standard methods: Application for the alcoholic products quality 
      control.
PG  - 123518
LID - S0039-9140(22)00314-9 [pii]
LID - 10.1016/j.talanta.2022.123518 [doi]
AB  - This paper focuses on the evaluation of variation of relative response factors 
      (RRFs) obtained by two internal standard (IS) methods that are used to control 
      the quality of alcoholic products. A standard IS method using 1-pentanol was 
      compared with an "Ethanol as IS" method. The variation of RRF values for both 
      methods was determined using standard solutions based on 20, 40 and 96% 
      ethanol-water matrices. For this purpose, solutions of the ten most abundant 
      volatile compounds were analysed at four different concentrations (250, 500, 1000 
      and 5000 mg L(-1) absolute alcohol, AA) within these matrices. Each solution was 
      measured four times by gas chromatography-mass spectrometry (GC-MS) in single ion 
      monitoring (SIM) mode under repeatability conditions. Our results showed that for 
      the 40% and 96% matrices, the ethanol and standard IS methods showed similar 
      relative standard deviations (RSDs) variation of no more than 2% within the 
      250-1000 mg L(-1) AA volatile compounds concentration range. For the 20% matrix 
      as well as for the 250-5000 mg L(-1) AA concentration range the resulting 
      variation in calibration factors reaches 10% for both methods. As for the whole 
      range of 20-96% alcohol by volume (ABV) and 250-5000 mg L(-1) AA volatile 
      concentration range, the resultant RRFs for the standard IS method (8% RSD) were 
      more stable than those for the ethanol IS method (almost 40% RSD). Nonlinearity 
      of the signal-to-amount dependence was also assessed with respect to the 
      injection and detection processes.
CI  - Copyright (c) 2022 Elsevier B.V. All rights reserved.
FAU - Korban, Anton
AU  - Korban A
AD  - Faculty of Science, Department of Analytical Chemistry, Charles University, 
      Hlavova 2030/8, 128 40, Prague 2, Czech Republic; Chemistry Faculty, Department 
      of Analytical Chemistry, Belarusian State University, Leningradskaya 14, 220050, 
      Minsk, Belarus; Institute for Nuclear Problems of Belarusian State University, 
      220006, Bobruyskaya Str., 11, Minsk, Belarus. Electronic address: 
      karbonat7@gmail.com.
FAU - Cabala, Radomir
AU  - Cabala R
AD  - Faculty of Science, Department of Analytical Chemistry, Charles University, 
      Hlavova 2030/8, 128 40, Prague 2, Czech Republic. Electronic address: 
      cabala@natur.cuni.cz.
FAU - Egorov, Vladimir
AU  - Egorov V
AD  - Chemistry Faculty, Department of Analytical Chemistry, Belarusian State 
      University, Leningradskaya 14, 220050, Minsk, Belarus. Electronic address: 
      egorvv@bsu.by.
FAU - Bosakova, Zuzana
AU  - Bosakova Z
AD  - Faculty of Science, Department of Analytical Chemistry, Charles University, 
      Hlavova 2030/8, 128 40, Prague 2, Czech Republic. Electronic address: 
      zuzana.bosakova@natur.cuni.cz.
FAU - Charapitsa, Siarhei
AU  - Charapitsa S
AD  - Institute for Nuclear Problems of Belarusian State University, 220006, 
      Bobruyskaya Str., 11, Minsk, Belarus. Electronic address: svcharapitsa@tut.by.
LA  - eng
PT  - Journal Article
DEP - 20220430
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
RN  - 059QF0KO0R (Water)
RN  - 3K9958V90M (Ethanol)
SB  - IM
MH  - *Ethanol
MH  - Gas Chromatography-Mass Spectrometry/methods
MH  - Quality Control
MH  - *Water
OTO - NOTNLM
OT  - Alcoholic products
OT  - Calibration
OT  - Ethanol as IS
OT  - GC-MS
OT  - Internal standard method
OT  - Quality control
OT  - Relative response factors
EDAT- 2022/05/09 06:00
MHDA- 2022/06/10 06:00
CRDT- 2022/05/08 18:16
PHST- 2021/12/03 00:00 [received]
PHST- 2022/04/26 00:00 [revised]
PHST- 2022/04/28 00:00 [accepted]
PHST- 2022/05/09 06:00 [pubmed]
PHST- 2022/06/10 06:00 [medline]
PHST- 2022/05/08 18:16 [entrez]
AID - S0039-9140(22)00314-9 [pii]
AID - 10.1016/j.talanta.2022.123518 [doi]
PST - ppublish
SO  - Talanta. 2022 Aug 15;246:123518. doi: 10.1016/j.talanta.2022.123518. Epub 2022 
      Apr 30.