PMID- 35531521
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220716
IS  - 2046-2069 (Electronic)
IS  - 2046-2069 (Linking)
VI  - 9
IP  - 51
DP  - 2019 Sep 18
TI  - Magnetic molecularly imprinted polymers for the detection of aminopyralid in milk 
      using dispersive solid-phase extraction.
PG  - 29998-30006
LID - 10.1039/c9ra05782j [doi]
AB  - A method for dummy molecular imprinting-magnetic dispersive solid-phase 
      extraction (MI-MDSPE) coupled with liquid chromatography-tandem mass spectrometry 
      (LC-MS/MS) was developed for the selective determination of aminopyralid in milk. 
      The magnetic material and polymers were combined via a series of modifications in 
      Fe(3)O(4). Fe(3)O(4)@SiO(2)-NH(2)@MIP, Fe(3)O(4)@SiO(2)-COOH@MIP and two types of 
      aminopyralid-specific magnetic molecularly imprinted polymers (MMIPs) were 
      prepared on the surface of magnetic nanoparticles modified with amino and 
      carboxyl groups. The morphology and magnetic properties of the polymer were 
      characterized. Fe(3)O(4)@SiO(2)-NH(2)@MIP exhibits not only good dispersibility 
      and magnetic properties, but also an outstanding recognition pattern to the 
      target analyte. Adsorption experiments demonstrated that 
      Fe(3)O(4)@SiO(2)-NH(2)@MIP, with a high specific surface area and fast mass 
      transfer rate, had a higher affinity than Fe(3)O(4)@SiO(2)-COOH@MIP towards 
      aminopyralid. Under the optimized MI-MDSPE conditions, the method had good 
      linearity (R (2) > 0.9972), excellent recoveries (83.3-90%), and good precision 
      (relative standard deviations (RSDs) < 12.6%). This method has limits of 
      detection (LOD) and quantification (LOQ) of 0.231 and 0.77 mug kg(-1), 
      respectively, indicating that these MMIPs can be used to analyse trace levels of 
      aminopyralid in real samples.
CI  - This journal is (c) The Royal Society of Chemistry.
FAU - He, Yahui
AU  - He Y
AD  - Beijing Technology and Business University 100048 P. R. China hyh@btbu.edu.cn 
      +86-1068985456 +86-1068985456.
AD  - Institute of Quality Standards & Testing Technology for Agro-Products, Chinese 
      Academy of Agricultural Sciences Beijing 100081 P. R. China sheyongxin@caas.cn 
      +86-1082106567 +86-1082106513.
FAU - Tan, Sijia
AU  - Tan S
AD  - Institute of Quality Standards & Testing Technology for Agro-Products, Chinese 
      Academy of Agricultural Sciences Beijing 100081 P. R. China sheyongxin@caas.cn 
      +86-1082106567 +86-1082106513.
FAU - Abd Ei-Aty, A M
AU  - Abd Ei-Aty AM
AUID- ORCID: 0000-0001-6596-7907
AD  - Department of Pharmacology, Faculty of Veterinary Medicine, Cairo University 
      12211-Giza Egypt.
AD  - Department of Medical Pharmacology, Medical Faculty, Ataturk University 
      25240-Erzurum Turkey.
FAU - Hacimuftuoglu, Ahmet
AU  - Hacimuftuoglu A
AD  - Department of Medical Pharmacology, Medical Faculty, Ataturk University 
      25240-Erzurum Turkey.
FAU - She, Yongxin
AU  - She Y
AUID- ORCID: 0000-0003-4039-9186
AD  - Institute of Quality Standards & Testing Technology for Agro-Products, Chinese 
      Academy of Agricultural Sciences Beijing 100081 P. R. China sheyongxin@caas.cn 
      +86-1082106567 +86-1082106513.
LA  - eng
PT  - Journal Article
DEP - 20190923
PL  - England
TA  - RSC Adv
JT  - RSC advances
JID - 101581657
PMC - PMC9072149
COIS- Authors have declared no conflicts of interest.
EDAT- 2019/09/23 00:00
MHDA- 2019/09/23 00:01
PMCR- 2019/09/23
CRDT- 2022/05/09 04:35
PHST- 2019/07/25 00:00 [received]
PHST- 2019/09/17 00:00 [accepted]
PHST- 2022/05/09 04:35 [entrez]
PHST- 2019/09/23 00:00 [pubmed]
PHST- 2019/09/23 00:01 [medline]
PHST- 2019/09/23 00:00 [pmc-release]
AID - c9ra05782j [pii]
AID - 10.1039/c9ra05782j [doi]
PST - epublish
SO  - RSC Adv. 2019 Sep 23;9(51):29998-30006. doi: 10.1039/c9ra05782j. eCollection 2019 
      Sep 18.