PMID- 35540481
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220716
IS  - 2046-2069 (Electronic)
IS  - 2046-2069 (Linking)
VI  - 8
IP  - 19
DP  - 2018 Mar 13
TI  - Determination of six organophosphorus pesticides in water samples by 
      three-dimensional graphene aerogel-based solid-phase extraction combined with gas 
      chromatography/mass spectrometry.
PG  - 10277-10283
LID - 10.1039/c7ra13316b [doi]
AB  - In the present study, a three-dimensional graphene aerogel (3D-GA), synthesised 
      by chemical reduction of an aqueous solution of graphene oxides (GOs) with 
      ethylenediaminethermal by a simple water bath method followed by freeze-drying 
      treatment, was used for the solid-phase extraction (SPE) of six organophosphorus 
      pesticides (OPPs) (i.e. trichlorfon, dimethoate, ethoprophos, parathion, 
      fenitrothion and fenthion) from water samples. The target analytes were extracted 
      using packed SPE cartridges and then eluted with tetrahydrofuran. The eluate was 
      collected and dried with high-purity nitrogen gas at room temperature. After 
      redissolving in acetone, the residue was analysed using gas chromatography/mass 
      spectrometry (GC/MS). The proposed method demonstrated a good linearity between 
      0.5 and 500 mug L(-1) with the correlation coefficient of 0.9990-0.9998. The 
      limits of detection (LODs) (S/N = 3) and the limits of quantification (LOQs) (S/N 
      = 10) for the six OPPs pesticides were in the range of 0.12-0.58 mug L(-1) and 
      0.41-1.96 mug L(-1), respectively. The accuracy of the present method was 
      evaluated by measuring the recovery of the spiked samples, which ranged from 
      93.8% to 104.2% with relative standard deviations (RSDs) of 1.1-5.6%. The 
      established method was successfully applied to the determination of the target 
      analytes in environmental water samples including tap water, river water, 
      drinking water and lake water, demonstrating its great potential for the 
      determination of OPPs in water.
CI  - This journal is (c) The Royal Society of Chemistry.
FAU - Sun, P
AU  - Sun P
AD  - Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, 
      School of Chemistry and Materials Science, Heilongjiang University Harbin 150080 
      China chyflian@hlju.edu.cn.
AD  - Analytical Centre, Heilongjiang Bayi Agricultural University Daqing163319 China.
FAU - Gao, Y L
AU  - Gao YL
AD  - Analytical Centre, Heilongjiang Bayi Agricultural University Daqing163319 China.
FAU - Xu, C
AU  - Xu C
AD  - Analytical Centre, Heilongjiang Bayi Agricultural University Daqing163319 China.
FAU - Lian, Y F
AU  - Lian YF
AUID- ORCID: 0000-0002-5217-514X
AD  - Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education, 
      School of Chemistry and Materials Science, Heilongjiang University Harbin 150080 
      China chyflian@hlju.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20180313
PL  - England
TA  - RSC Adv
JT  - RSC advances
JID - 101581657
PMC - PMC9078834
COIS- There are no conflicts to declare.
EDAT- 2018/03/13 00:00
MHDA- 2018/03/13 00:01
PMCR- 2018/03/13
CRDT- 2022/05/11 03:55
PHST- 2017/12/13 00:00 [received]
PHST- 2018/03/05 00:00 [accepted]
PHST- 2022/05/11 03:55 [entrez]
PHST- 2018/03/13 00:00 [pubmed]
PHST- 2018/03/13 00:01 [medline]
PHST- 2018/03/13 00:00 [pmc-release]
AID - c7ra13316b [pii]
AID - 10.1039/c7ra13316b [doi]
PST - epublish
SO  - RSC Adv. 2018 Mar 13;8(19):10277-10283. doi: 10.1039/c7ra13316b. eCollection 2018 
      Mar 13.