PMID- 35631911
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220716
IS  - 2073-4360 (Electronic)
IS  - 2073-4360 (Linking)
VI  - 14
IP  - 10
DP  - 2022 May 16
TI  - Dithiocarbamates as Effective Reversible Addition-Fragmentation Chain Transfer 
      Agents for Controlled Radical Polymerization of 1-Vinyl-1,2,4-triazole.
LID - 10.3390/polym14102029 [doi]
LID - 2029
AB  - Narrow dispersed poly(1-vinyl-1,2,4-triazole) (PVT) was synthesized by reversible 
      addition-fragmentation chain transfer (RAFT) polymerization of 
      1-vinyl-1,2,4-triazole (VT). AIBN as the initiator and dithiocarbamates, 
      xanthates, and trithiocarbonates as the chain transfer agents (CTA) were used. 
      Dithiocarbamates proved to be the most efficient in VT polymerization. Gel 
      permeation chromatography was used to determine the molecular weight distribution 
      and polydispersity of the synthesized polymers. The presence of the CTA 
      stabilizing and leaving groups in the PVT was confirmed by (1)H and (13)C NMR 
      spectroscopy. The linear dependence of the degree of polymerization on time 
      confirms the conduct of radical polymerization in a controlled mode. The VT 
      conversion was over 98% and the PVT number average molecular weight ranged from 
      11 to 61 kDa. The polydispersity of the synthesized polymers reached 1.16. The 
      occurrence of the controlled radical polymerization was confirmed by monitoring 
      the degree of polymerization over time.
FAU - Pozdnyakov, Alexander S
AU  - Pozdnyakov AS
AUID- ORCID: 0000-0002-9365-3697
AD  - A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian 
      Academy of Sciences, 1 Favorsky Str., Irkutsk 664033, Russia.
FAU - Kuznetsova, Nadezhda P
AU  - Kuznetsova NP
AD  - A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian 
      Academy of Sciences, 1 Favorsky Str., Irkutsk 664033, Russia.
FAU - Semenova, Tatyana A
AU  - Semenova TA
AD  - A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian 
      Academy of Sciences, 1 Favorsky Str., Irkutsk 664033, Russia.
FAU - Bolgova, Yuliya I
AU  - Bolgova YI
AD  - A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian 
      Academy of Sciences, 1 Favorsky Str., Irkutsk 664033, Russia.
FAU - Ivanova, Anastasia A
AU  - Ivanova AA
AD  - A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian 
      Academy of Sciences, 1 Favorsky Str., Irkutsk 664033, Russia.
FAU - Trofimova, Olga M
AU  - Trofimova OM
AD  - A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian 
      Academy of Sciences, 1 Favorsky Str., Irkutsk 664033, Russia.
FAU - Emel'yanov, Artem I
AU  - Emel'yanov AI
AUID- ORCID: 0000-0001-5025-5843
AD  - A.E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian 
      Academy of Sciences, 1 Favorsky Str., Irkutsk 664033, Russia.
LA  - eng
GR  - 21-73-00259/Russian Science Foundation/
PT  - Journal Article
DEP - 20220516
PL  - Switzerland
TA  - Polymers (Basel)
JT  - Polymers
JID - 101545357
PMC - PMC9147191
OTO - NOTNLM
OT  - 1-vinyl-1,2,4-triazole
OT  - chain transfer agents
OT  - controlled radical polymerization
OT  - dithiocarbamates
OT  - trithiocarbonates
OT  - xanthates
COIS- The authors declare no conflict of interest.
EDAT- 2022/05/29 06:00
MHDA- 2022/05/29 06:01
PMCR- 2022/05/16
CRDT- 2022/05/28 01:40
PHST- 2022/04/29 00:00 [received]
PHST- 2022/05/12 00:00 [revised]
PHST- 2022/05/14 00:00 [accepted]
PHST- 2022/05/28 01:40 [entrez]
PHST- 2022/05/29 06:00 [pubmed]
PHST- 2022/05/29 06:01 [medline]
PHST- 2022/05/16 00:00 [pmc-release]
AID - polym14102029 [pii]
AID - polymers-14-02029 [pii]
AID - 10.3390/polym14102029 [doi]
PST - epublish
SO  - Polymers (Basel). 2022 May 16;14(10):2029. doi: 10.3390/polym14102029.