PMID- 35639179 OWN - NLM STAT- MEDLINE DCOM- 20220602 LR - 20220613 IS - 1436-5073 (Electronic) IS - 0026-3672 (Linking) VI - 189 IP - 6 DP - 2022 May 31 TI - Boron carbon oxynitride quantum dots-based ratio fluorescent nanoprobe assisted with smartphone for visualization detection of phosphate. PG - 238 LID - 10.1007/s00604-022-05331-4 [doi] AB - A ratio fluorescence nanoprobe was constructed by simple mixing BCNO QDs with 8-hydroxyquinoline-5-sulfonic acid (HQSA), which had an obvious fluorescence peak at 420 nm and a weak fluorescence peak at 500 nm, corresponding to the BCNO QDs and HQSA, respectively. This fluorescence probe takes stable fluorescence of BCNO QDs as an internal standard, based on HQSA chelating enhanced fluorescence and specificity of phosphate in the presence of Mg(2+), which realizes a rapid and sensitive detection of phosphate with good linearity in the range 0.3-50 muM and 50-100 muM and a detection limit of 0.073 muM. The recovery is between 94.1 and 111% and the relative standard deviations (RSDs) below 10%. At the same time, we took color photos of the reaction solution under 310-nm UV lamp with smartphones for visual detection through RGB data image analysis, which make the detection easier and faster. The proposed method provides a new strategy for the intelligent online detection of other targets in complex environment samples. CI - (c) 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Austria, part of Springer Nature. FAU - Qin, Ying AU - Qin Y AD - Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, College of Chemistry and Chemical Engineering, Hubei University, Wuhan, 430062, China. FAU - Li, Ziling AU - Li Z AD - School of Public Health, North China University of Science and Technology, No.21 Bohai Road, Caofeidian, Tangshan, 063210, Hebei, China. FAU - He, Yu AU - He Y AUID- ORCID: 0000-0002-8068-5825 AD - Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, College of Chemistry and Chemical Engineering, Hubei University, Wuhan, 430062, China. heyu@hubu.edu.cn. FAU - Wang, Manman AU - Wang M AD - School of Public Health, North China University of Science and Technology, No.21 Bohai Road, Caofeidian, Tangshan, 063210, Hebei, China. mmwangheuu@126.com. FAU - Song, Gongwu AU - Song G AD - Hubei Collaborative Innovation Center for Advanced Organic Chemical Materials, Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, College of Chemistry and Chemical Engineering, Hubei University, Wuhan, 430062, China. LA - eng GR - 21707030/National Natural Science Foundation of China/ GR - 82073608/National Natural Science Foundation of China/ PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20220531 PL - Austria TA - Mikrochim Acta JT - Mikrochimica acta JID - 7808782 RN - 0 (Phosphates) RN - 7440-44-0 (Carbon) RN - N9E3X5056Q (Boron) SB - IM MH - Boron MH - Carbon MH - Phosphates MH - *Quantum Dots MH - Smartphone OTO - NOTNLM OT - 8-Hydroxyquinoline-5-sulfonic acid OT - BCNO QDs OT - Phosphate OT - Ratio fluorescence detection OT - Smartphone detection EDAT- 2022/06/01 06:00 MHDA- 2022/06/03 06:00 CRDT- 2022/05/31 15:35 PHST- 2022/01/10 00:00 [received] PHST- 2022/05/08 00:00 [accepted] PHST- 2022/05/31 15:35 [entrez] PHST- 2022/06/01 06:00 [pubmed] PHST- 2022/06/03 06:00 [medline] AID - 10.1007/s00604-022-05331-4 [pii] AID - 10.1007/s00604-022-05331-4 [doi] PST - epublish SO - Mikrochim Acta. 2022 May 31;189(6):238. doi: 10.1007/s00604-022-05331-4.