PMID- 35667509
OWN - NLM
STAT- MEDLINE
DCOM- 20220627
LR  - 20220627
IS  - 1879-1298 (Electronic)
IS  - 0045-6535 (Linking)
VI  - 304
DP  - 2022 Oct
TI  - Fabrication of 3D self-supported MoS(2)-Co-P/nickel foam electrode for 
      adsorption-electrochemical removal of Cr(Ⅵ).
PG  - 135209
LID - S0045-6535(22)01702-7 [pii]
LID - 10.1016/j.chemosphere.2022.135209 [doi]
AB  - Electrochemistry is considered to be one of the most efficient and 
      environment-friendly methods for removing highly toxic Cr (Ⅵ). In this study, a 
      3D self-supported MoS(2)-Co-P/nickel foam (NF) electrode was prepared via a 
      calcination-hydrothermal process to remove the Cr (Ⅵ) in aqueous medium. Scanning 
      electron microscope (SEM) analysis indicated that the pine-needle-like Co(2)P 
      nanoneedle and flower-like MoS(2) nanosheets were successfully loaded on the 
      three-dimensional (3D) framework of NF, which provided abundant active sites. The 
      electrode modified by Co, P and MoS(2) exhibited high removal efficiency of Cr 
      (Ⅵ) (96.9%) at pH 3.0, current of 0.128 mA and voltage of 2.5 V. Co, P and MoS(2) 
      have the synergistic promotion on the catalytic performance of electrodes, and 
      the reduction efficiency of Cr (Ⅵ) was greatly improved by 127.5 times relative 
      to pure NF. The enhanced removal of Cr (Ⅵ) was related to the coupling effect of 
      adsorption and electrocatalytic reduction. The mechanism study indicated that 
      electron (e(-)) is the active species of Cr (Ⅵ) reduction. The Cr (Ⅵ) removal 
      rate was maintained at 90 +/- 1% after five successive cycle experiments, 
      demonstrating good stability and potential industrial applications of 
      MoS(2)-Co-P/NF.
CI  - Copyright (c) 2022 Elsevier Ltd. All rights reserved.
FAU - Shen, Lidong
AU  - Shen L
AD  - School of Environmental Science and Engineering, Zhejiang Gongshang University, 
      Hangzhou, 310018, China.
FAU - Ding, Wenchen
AU  - Ding W
AD  - School of Environmental Science and Engineering, Zhejiang Gongshang University, 
      Hangzhou, 310018, China.
FAU - Li, Xuchun
AU  - Li X
AD  - School of Environmental Science and Engineering, Zhejiang Gongshang University, 
      Hangzhou, 310018, China.
FAU - Zhang, Yi
AU  - Zhang Y
AD  - School of Environmental Science and Engineering, Zhejiang Gongshang University, 
      Hangzhou, 310018, China.
FAU - Cong, Yanqing
AU  - Cong Y
AD  - School of Environmental Science and Engineering, Zhejiang Gongshang University, 
      Hangzhou, 310018, China. Electronic address: yqcong@zjsu.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20220603
PL  - England
TA  - Chemosphere
JT  - Chemosphere
JID - 0320657
RN  - 0R0008Q3JB (Chromium)
RN  - 18540-29-9 (chromium hexavalent ion)
RN  - 7OV03QG267 (Nickel)
RN  - 81AH48963U (Molybdenum)
SB  - IM
MH  - Adsorption
MH  - Chromium
MH  - Electrodes
MH  - *Molybdenum/chemistry
MH  - *Nickel/chemistry
OTO - NOTNLM
OT  - 3D pine-needle-like nanorods and flower-like nanosheets
OT  - Cr(Ⅵ) removal
OT  - MoS(2)-Co-P/NF
OT  - adsorption-electrocatalysis
EDAT- 2022/06/07 06:00
MHDA- 2022/06/28 06:00
CRDT- 2022/06/06 19:25
PHST- 2022/02/16 00:00 [received]
PHST- 2022/05/10 00:00 [revised]
PHST- 2022/05/31 00:00 [accepted]
PHST- 2022/06/07 06:00 [pubmed]
PHST- 2022/06/28 06:00 [medline]
PHST- 2022/06/06 19:25 [entrez]
AID - S0045-6535(22)01702-7 [pii]
AID - 10.1016/j.chemosphere.2022.135209 [doi]
PST - ppublish
SO  - Chemosphere. 2022 Oct;304:135209. doi: 10.1016/j.chemosphere.2022.135209. Epub 
      2022 Jun 3.