PMID- 35694477 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20220716 IS - 2470-1343 (Electronic) IS - 2470-1343 (Linking) VI - 7 IP - 22 DP - 2022 Jun 7 TI - Au-Based Thin-Film Metallic Glasses for Propagating Surface Plasmon Resonance-Based Sensor Applications. PG - 18780-18785 LID - 10.1021/acsomega.2c01565 [doi] AB - We deposited Au-Cu-Si, an Au-based thin-film metallic glass (TFMG) of approximately 50 nm thickness, as the activation layer for propagating surface plasmon resonance (PSPR)-based sensors on a BK7 glass substrate to substitute the commonly used gold layer. The film composition was tuned to yield the maximum Au content ( approximately 65 at %), while the structure remained amorphous. The results showed that the Au-based TFMG could support surface plasmon resonance and gave rise to the extinction in the angle-resolved reflection spectrum. Using deionized water and ethyl alcohol with the refractive index difference of approximately 0.03 as the analytes, the angle shift given by Au-based TFMG was 4 degrees compared to 5 degrees given by the Au film. Hence, Au-based TFMG is feasible to be used as the activation layer in PSPR-based sensors. Compared to the Au film, Au-based TFMG has the advantages of being less expensive, lacking grain boundary scattering, better adhesion to the substrate, and higher resistance to scratch and corrosion because of its amorphous structure with excellent mechanical properties. CI - (c) 2022 The Authors. Published by American Chemical Society. FAU - Wang, Cheng AU - Wang C AD - Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan. FAU - Chen, Pin-Jie AU - Chen PJ AD - Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan. FAU - Hsueh, Chun-Hway AU - Hsueh CH AUID- ORCID: 0000-0002-6477-7148 AD - Department of Materials Science and Engineering, National Taiwan University, Taipei 10617, Taiwan. LA - eng PT - Journal Article DEP - 20220526 PL - United States TA - ACS Omega JT - ACS omega JID - 101691658 PMC - PMC9178754 COIS- The authors declare no competing financial interest. EDAT- 2022/06/14 06:00 MHDA- 2022/06/14 06:01 PMCR- 2022/05/26 CRDT- 2022/06/13 03:33 PHST- 2022/03/15 00:00 [received] PHST- 2022/05/19 00:00 [accepted] PHST- 2022/06/13 03:33 [entrez] PHST- 2022/06/14 06:00 [pubmed] PHST- 2022/06/14 06:01 [medline] PHST- 2022/05/26 00:00 [pmc-release] AID - 10.1021/acsomega.2c01565 [doi] PST - epublish SO - ACS Omega. 2022 May 26;7(22):18780-18785. doi: 10.1021/acsomega.2c01565. eCollection 2022 Jun 7.