PMID- 35708808 OWN - NLM STAT- MEDLINE DCOM- 20221026 LR - 20221026 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 29 IP - 52 DP - 2022 Nov TI - Millettia pinnata plant pod extract-mediated synthesis of Bi(2)O(3) for degradation of water pollutants. PG - 79253-79271 LID - 10.1007/s11356-022-21435-z [doi] AB - In this study, plant extract obtained from pods of Millettia pinnata plant species was employed for nanosynthesis of Bi(2)O(3). The as-synthesized semiconductor metal oxide nanoparticles were analyzed using various characterization tools such as X-ray diffraction (XRD), Scanning electron microscope (SEM), ultra violet-visible (UV-Vis), Fourier transform infrared (FTIR), Zeta potential, Raman, and X-ray photoelectron spectroscopy (XPS). The characterization results designate the formation of alpha and beta forms of Bi(2)O(3). FESEM images demonstrate rod and flake-like nanostructures ranging from 25 to 70 nm. The green synthesized nanomaterial was found efficient for reduction of 4-nitro phenol (4-NP) and 4-nitro aniline (4-NA). However, it showed better performance toward the reduction of 4-NA. Photocatalytic investigations demonstrated that the green synthesized nanophotocatalyst was capable in degrading Amido Black 10B (AB-10B) dye efficiently under visible light illumination. 98.83% degradation of AB-10B dye was achieved within 120 min of irradiation under optimum conditions of photocatalyst dose and dye concentration. Active species trapping experiments revealed prominent role of superoxide radicals (*O(2)(-)) while hydroxyl radicals (*OH) played considerable role in the AB-10B photocatalytic degradation process. Moreover, the photostability and reusability assessment study ascertained good performance of the catalyst after four runs of successive cycles. CI - (c) 2022. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature. FAU - Meena, Parmeshwar Lal AU - Meena PL AD - Department of Chemistry, University of Rajasthan, Jaipur, 302004, India. parmeshwar1978@gmail.com. FAU - Surela, Ajay Kumar AU - Surela AK AD - Department of Chemistry, University of Rajasthan, Jaipur, 302004, India. FAU - Saini, Jitendra Kumar AU - Saini JK AD - Department of Chemistry, University of Rajasthan, Jaipur, 302004, India. FAU - Chhachhia, Lata Kumari AU - Chhachhia LK AD - S.R.K.P. Govt. P.G. College, Kishangarh, Ajmer, 305801, India. LA - eng PT - Journal Article DEP - 20220616 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - 0 (Water Pollutants) RN - 0 (Plant Extracts) RN - 11062-77-4 (Superoxides) RN - SZT789770M (Amido Black) RN - 0 (Naphthol Blue Black) RN - 0 (Oxides) RN - 0 (Aniline Compounds) RN - 0 (Phenols) SB - IM MH - *Millettia MH - *Water Pollutants MH - Plant Extracts MH - Superoxides MH - Amido Black MH - Catalysis MH - Oxides MH - Aniline Compounds MH - Phenols OTO - NOTNLM OT - Amido black 10B dye OT - Bi2O3 OT - Catalytic reduction OT - Millettia pinnata OT - Photocatalytic degradation OT - Water pollutants EDAT- 2022/06/17 06:00 MHDA- 2022/10/27 06:00 CRDT- 2022/06/16 11:57 PHST- 2022/04/04 00:00 [received] PHST- 2022/06/08 00:00 [accepted] PHST- 2022/06/17 06:00 [pubmed] PHST- 2022/10/27 06:00 [medline] PHST- 2022/06/16 11:57 [entrez] AID - 10.1007/s11356-022-21435-z [pii] AID - 10.1007/s11356-022-21435-z [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2022 Nov;29(52):79253-79271. doi: 10.1007/s11356-022-21435-z. Epub 2022 Jun 16.