PMID- 35714292
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220715
IS  - 1861-471X (Electronic)
IS  - 1861-471X (Linking)
VI  - 17
IP  - 14
DP  - 2022 Jul 15
TI  - High-Quality N-Doped Graphene with Controllable Nitrogen Bonding Configurations 
      Derived from Ionic Liquids.
PG  - e202200192
LID - 10.1002/asia.202200192 [doi]
AB  - Controllable nitrogen doping is an effective way to regulate the electronic 
      properties of graphene and further to facilitate its wider application. However, 
      the synthesis of high-quality nitrogen-doped graphene (NG) with a controllable 
      nitrogen configuration still faces considerable challenges. In this work, we 
      present for the first time a simple method for the one-step synthesis of NG with 
      ionic liquids (ILs) as precursors, which avoids the defects introduced by 
      secondary doping and simplifies the process. Using 1-Ethyl-3-methylimidazolium 
      dicyanamide (EMIM-dca) as the precursor, we obtained a high-quality NG with few 
      defects (I(D) /I(G) is 0.83), nitrogen content (4.11 at%), and graphite-N 
      proportion of 92% at a growth temperature of 1000  degrees C and field effect transistors 
      (FETs) fabricated on SiO(2) /Si substrates using the NG exhibited typical n-type 
      semiconductor behavior in air. Our findings bring more inspiration for the 
      controllable growth of high-quality graphitic N-doped graphene, thereby promoting 
      its application possibilities in numerous fields.
CI  - (c) 2022 Wiley-VCH GmbH.
FAU - Li, Shuang
AU  - Li S
AD  - Department of Chemistry, College of Science, Shanghai University, 99 Shang-Da 
      Road, 200444, Shanghai, P. R. China.
FAU - Liu, Mincong
AU  - Liu M
AD  - Department of Physics, College of Science, Shanghai University, 99 Shang-Da Road, 
      200444, Shanghai, P. R. China.
FAU - Wang, Xiulian
AU  - Wang X
AD  - Department of Chemistry, College of Science, Shanghai University, 99 Shang-Da 
      Road, 200444, Shanghai, P. R. China.
FAU - Ye, Guohua
AU  - Ye G
AD  - Department of Chemistry, College of Science, Shanghai University, 99 Shang-Da 
      Road, 200444, Shanghai, P. R. China.
FAU - Peng, Yan
AU  - Peng Y
AD  - Department of Chemistry, College of Science, Shanghai University, 99 Shang-Da 
      Road, 200444, Shanghai, P. R. China.
FAU - Zhao, Yufeng
AU  - Zhao Y
AUID- ORCID: 0000-0003-0899-5367
AD  - Institute for Sustainable Energy, Shanghai University, 99 Shang-Da Road, 200444, 
      Shanghai, P. R. China.
FAU - Guan, Shiyou
AU  - Guan S
AUID- ORCID: 0000-0003-2136-2265
AD  - Department of Chemistry, College of Science, Shanghai University, 99 Shang-Da 
      Road, 200444, Shanghai, P. R. China.
LA  - eng
PT  - Journal Article
DEP - 20220617
PL  - Germany
TA  - Chem Asian J
JT  - Chemistry, an Asian journal
JID - 101294643
SB  - IM
OTO - NOTNLM
OT  - N-doped graphene
OT  - controllable nitrogen bond configuration
OT  - graphitic N
OT  - high-quality
OT  - ionic liquids
EDAT- 2022/06/18 06:00
MHDA- 2022/06/18 06:01
CRDT- 2022/06/17 15:42
PHST- 2022/05/21 00:00 [revised]
PHST- 2022/02/27 00:00 [received]
PHST- 2022/06/18 06:00 [pubmed]
PHST- 2022/06/18 06:01 [medline]
PHST- 2022/06/17 15:42 [entrez]
AID - 10.1002/asia.202200192 [doi]
PST - ppublish
SO  - Chem Asian J. 2022 Jul 15;17(14):e202200192. doi: 10.1002/asia.202200192. Epub 
      2022 Jun 17.