PMID- 35746260 OWN - NLM STAT- MEDLINE DCOM- 20220627 LR - 20220716 IS - 1424-8220 (Electronic) IS - 1424-8220 (Linking) VI - 22 IP - 12 DP - 2022 Jun 13 TI - One-Step Co-Electrodeposition of Copper Nanoparticles-Chitosan Film-Carbon Nanoparticles-Multiwalled Carbon Nanotubes Composite for Electroanalysis of Indole-3-Acetic Acid and Salicylic Acid. LID - 10.3390/s22124476 [doi] LID - 4476 AB - A sensitive simultaneous electroanalysis of phytohormones indole-3-acetic acid (IAA) and salicylic acid (SA) based on a novel copper nanoparticles-chitosan film-carbon nanoparticles-multiwalled carbon nanotubes (CuNPs-CSF-CNPs-MWCNTs) composite was reported. CNPs were prepared by hydrothermal reaction of chitosan. Then the CuNPs-CSF-CNPs-MWCNTs composite was facilely prepared by one-step co-electrodeposition of CuNPs and CNPs fixed chitosan residues on modified electrode. Scanning electron microscope (SEM), transmission electron microscopy (TEM), selected area electron diffraction (SAED), energy dispersive spectroscopy (EDS), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and linear sweep voltammetry (LSV) were used to characterize the properties of the composite. Under optimal conditions, the composite modified electrode had a good linear relationship with IAA in the range of 0.01-50 muM, and a good linear relationship with SA in the range of 4-30 muM. The detection limits were 0.0086 muM and 0.7 muM (S/N = 3), respectively. In addition, the sensor could also be used for the simultaneous detection of IAA and SA in real leaf samples with satisfactory recovery. FAU - Kuang, Yiwen AU - Kuang Y AD - College of Bioscience and Biotechnology, Hunan Agricultural University, Changsha 410128, China. FAU - Li, Mengxue AU - Li M AD - College of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, China. FAU - Hu, Shiyu AU - Hu S AD - College of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, China. FAU - Yang, Lu AU - Yang L AD - College of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, China. FAU - Liang, Zhanning AU - Liang Z AD - College of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, China. FAU - Wang, Jiaqi AU - Wang J AD - College of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, China. FAU - Jiang, Hongmei AU - Jiang H AD - College of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, China. FAU - Zhou, Xiaoyun AU - Zhou X AD - College of Bioscience and Biotechnology, Hunan Agricultural University, Changsha 410128, China. FAU - Su, Zhaohong AU - Su Z AUID- ORCID: 0000-0001-7616-0770 AD - College of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, China. LA - eng GR - 2020JJ4346/Natural Science Foundation of Hunan Province/ GR - 20K063/Foundation of Department of Education of Hunan Province/ GR - 2019JGYB130/Degree & Postgraduate Education Reform Project of Hunan Province/ GR - No Number/Foundation of Yunnan Key Laboratory of Tobacco Chemistry, R&D Center of China Tobacco Yunnan Industrial Co., Ltd./ PT - Journal Article DEP - 20220613 PL - Switzerland TA - Sensors (Basel) JT - Sensors (Basel, Switzerland) JID - 101204366 RN - 0 (Indoleacetic Acids) RN - 0 (Nanotubes, Carbon) RN - 6U1S09C61L (indoleacetic acid) RN - 789U1901C5 (Copper) RN - 9012-76-4 (Chitosan) RN - O414PZ4LPZ (Salicylic Acid) SB - IM MH - *Biosensing Techniques MH - *Chitosan/chemistry MH - Copper/chemistry MH - Electrochemical Techniques MH - Electrodes MH - Electroplating MH - Indoleacetic Acids MH - Limit of Detection MH - *Nanoparticles MH - *Nanotubes, Carbon/chemistry MH - Salicylic Acid MH - Spectroscopy, Fourier Transform Infrared PMC - PMC9228024 OTO - NOTNLM OT - carbon nanoparticles OT - chitosan film OT - copper nanoparticles OT - electroanalysis of indole-3-acetic acid and salicylic acid OT - multiwalled carbon nanotubes COIS- The authors declare no conflict of interest. EDAT- 2022/06/25 06:00 MHDA- 2022/06/28 06:00 PMCR- 2022/06/13 CRDT- 2022/06/24 01:40 PHST- 2022/04/26 00:00 [received] PHST- 2022/06/07 00:00 [revised] PHST- 2022/06/10 00:00 [accepted] PHST- 2022/06/24 01:40 [entrez] PHST- 2022/06/25 06:00 [pubmed] PHST- 2022/06/28 06:00 [medline] PHST- 2022/06/13 00:00 [pmc-release] AID - s22124476 [pii] AID - sensors-22-04476 [pii] AID - 10.3390/s22124476 [doi] PST - epublish SO - Sensors (Basel). 2022 Jun 13;22(12):4476. doi: 10.3390/s22124476.