PMID- 35748110
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220706
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 14
IP  - 26
DP  - 2022 Jul 6
TI  - Highly Efficient Artificial Light-Harvesting Systems Constructed in an Aqueous 
      Solution Based on Twisted Cucurbit[14]Uril.
PG  - 29806-29812
LID - 10.1021/acsami.2c05599 [doi]
AB  - Relying on the supramolecular self-assembly of twisted cucurbit[14]urils 
      (tQ[14]), anthracene derivatives (ADPy), Nile red (NiR), and rhodamine B (RB), 
      highly efficient light-harvesting systems have been successfully designed in an 
      aqueous medium. The addition of tQ[14] causes ADPy to aggregate through 
      supramolecular self-assembly to form a supramolecular polymer (ADPy@tQ[14]) with 
      excellent aggregation-induced fluorescence and an interesting spherical external 
      morphology, making it a remarkable energy donor. Consequently, efficient 
      energy-transfer processes have occurred between ADPy@tQ[14] assembly and NiR and 
      RB, which both serve as effective energy acceptors while being loaded onto 
      ADPy@tQ[14]. In the case of NiR, the energy-transfer efficiency is up to 72.45%, 
      and the antenna effect is near 55.4 at a donor/acceptor ratio of 100:1, making it 
      close to the light-harvesting systems in nature. As a result, effective 
      water-soluble artificial light-harvesting systems are showing enormous 
      prospective as versatile platforms for simulating photosynthesis.
FAU - Luo, Yang
AU  - Luo Y
AD  - State Key Laboratory Breeding Base of Green Pesticide and Agricultural 
      Bioengineering, Key Laboratory of Green Pesticide and Agricultural 
      Bioengineering, Key Laboratory of Macrocyclic and Supramolecular Chemistry of 
      Guizhou Province, Guizhou University, Guiyang 550025, China.
FAU - Zhang, Wei
AU  - Zhang W
AD  - State Key Laboratory Breeding Base of Green Pesticide and Agricultural 
      Bioengineering, Key Laboratory of Green Pesticide and Agricultural 
      Bioengineering, Key Laboratory of Macrocyclic and Supramolecular Chemistry of 
      Guizhou Province, Guizhou University, Guiyang 550025, China.
FAU - Ren, Qian
AU  - Ren Q
AD  - State Key Laboratory Breeding Base of Green Pesticide and Agricultural 
      Bioengineering, Key Laboratory of Green Pesticide and Agricultural 
      Bioengineering, Key Laboratory of Macrocyclic and Supramolecular Chemistry of 
      Guizhou Province, Guizhou University, Guiyang 550025, China.
FAU - Tao, Zhu
AU  - Tao Z
AUID- ORCID: 0000-0002-8313-1430
AD  - State Key Laboratory Breeding Base of Green Pesticide and Agricultural 
      Bioengineering, Key Laboratory of Green Pesticide and Agricultural 
      Bioengineering, Key Laboratory of Macrocyclic and Supramolecular Chemistry of 
      Guizhou Province, Guizhou University, Guiyang 550025, China.
FAU - Xiao, Xin
AU  - Xiao X
AUID- ORCID: 0000-0001-6432-2875
AD  - State Key Laboratory Breeding Base of Green Pesticide and Agricultural 
      Bioengineering, Key Laboratory of Green Pesticide and Agricultural 
      Bioengineering, Key Laboratory of Macrocyclic and Supramolecular Chemistry of 
      Guizhou Province, Guizhou University, Guiyang 550025, China.
LA  - eng
PT  - Journal Article
DEP - 20220624
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
SB  - IM
OTO - NOTNLM
OT  - Nile red
OT  - anthracene derivative
OT  - cucurbit[n]urils
OT  - energy transfer
OT  - light-harvesting systems
EDAT- 2022/06/25 06:00
MHDA- 2022/06/25 06:01
CRDT- 2022/06/24 03:53
PHST- 2022/06/25 06:00 [pubmed]
PHST- 2022/06/25 06:01 [medline]
PHST- 2022/06/24 03:53 [entrez]
AID - 10.1021/acsami.2c05599 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2022 Jul 6;14(26):29806-29812. doi: 
      10.1021/acsami.2c05599. Epub 2022 Jun 24.