PMID- 35803143
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220907
IS  - 1095-7103 (Electronic)
IS  - 0021-9797 (Linking)
VI  - 626
DP  - 2022 Nov 15
TI  - Li(3)Bi/LiF/Li(2)O derived from mechanical rolling of Li metal with BiOF 
      nanoplates as stable filler for dendrite-free Li metal batteries.
PG  - 435-444
LID - S0021-9797(22)01158-4 [pii]
LID - 10.1016/j.jcis.2022.06.167 [doi]
AB  - Li is attractive anode for next-generation high-energy batteries. The high 
      chemical activity, dendrite growth, and huge volume fluctuation of Li hinder its 
      practical application. In this work, a Li-BiOF composite anode (LBOF) is obtained 
      by combining Li metal with BiOF nanoplates through facile folding and mechanical 
      cold rolling. Further, Li(3)Bi/LiF/Li(2)O filler is formed by the in-situ 
      reactions of BiOF with contacted Li. In the filler, the Li(3)Bi, with high ionic 
      conductivity and a lithiophilic nature, provides a mutually permeable channel for 
      Li(+) diffusion. The low surface diffusion energy barrier of Li(3)Bi and LiF can 
      further promote the uniform deposition of Li. The conductive lithiophilic filler 
      can reduce the local current density and provide a spatial limitation to the 
      deposited Li. Consequently, the symmetrical LBOF||LBOF cell can cycle stably at 
      1 mA cm(-2) for over 1300 h. Additionally, the surface of LBOF is flat with 
      suppressed dendrite formation and free of dead Li accumulation, and the change in 
      electrode volume is significantly alleviated. Furthermore, the LBOF||LiFePO(4) 
      full battery can maintain a stable cycle of more than 200 times with high 
      capacity retention of 88.7% in a corrosive ester-based electrolyte. This simple 
      mechanical approach is compatible with the current industrial route and is 
      inspiring to solve the long-standing lithium-dendrite problem.
CI  - Copyright (c) 2022 Elsevier Inc. All rights reserved.
FAU - Fu, Xuelian
AU  - Fu X
AD  - Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, School of 
      Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430205, 
      China; Guangdong Provincial Key Laboratory of Optical Information Materials and 
      Technology, South China Academy of Advanced Optoelectronics, South China Normal 
      University, Guangzhou 510006, China.
FAU - Shang, Chaoqun
AU  - Shang C
AD  - Hubei Key Laboratory of Plasma Chemistry and Advanced Materials, School of 
      Materials Science and Engineering, Wuhan Institute of Technology, Wuhan 430205, 
      China. Electronic address: chaoqun.shang@foxmail.com.
FAU - Zhou, Guofu
AU  - Zhou G
AD  - Guangdong Provincial Key Laboratory of Optical Information Materials and 
      Technology, South China Academy of Advanced Optoelectronics, South China Normal 
      University, Guangzhou 510006, China.
FAU - Wang, Xin
AU  - Wang X
AD  - Guangdong Provincial Key Laboratory of Optical Information Materials and 
      Technology, South China Academy of Advanced Optoelectronics, South China Normal 
      University, Guangzhou 510006, China. Electronic address: wangxin@scnu.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20220630
PL  - United States
TA  - J Colloid Interface Sci
JT  - Journal of colloid and interface science
JID - 0043125
SB  - IM
OTO - NOTNLM
OT  - BiOF nanoplates
OT  - Dendrite suppression
OT  - Electron/ion conduction
OT  - Li(3)Bi/LiF/Li(2)O filler
OT  - Mechanical cold rolling
COIS- Declaration of Competing Interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2022/07/09 06:00
MHDA- 2022/07/09 06:01
CRDT- 2022/07/08 18:29
PHST- 2022/04/28 00:00 [received]
PHST- 2022/06/17 00:00 [revised]
PHST- 2022/06/28 00:00 [accepted]
PHST- 2022/07/09 06:00 [pubmed]
PHST- 2022/07/09 06:01 [medline]
PHST- 2022/07/08 18:29 [entrez]
AID - S0021-9797(22)01158-4 [pii]
AID - 10.1016/j.jcis.2022.06.167 [doi]
PST - ppublish
SO  - J Colloid Interface Sci. 2022 Nov 15;626:435-444. doi: 
      10.1016/j.jcis.2022.06.167. Epub 2022 Jun 30.