PMID- 35816420 OWN - NLM STAT- MEDLINE DCOM- 20221003 LR - 20221026 IS - 2162-2906 (Electronic) IS - 1096-2247 (Linking) VI - 72 IP - 10 DP - 2022 Oct TI - Analysis and discussion on formation and control of dioxins generated from municipal solid waste incineration process. PG - 1063-1082 LID - 10.1080/10962247.2022.2100843 [doi] AB - Dioxins are a kind of persistent organic pollutants (POPs) with extremely toxic. Municipal solid waste incineration (MSWI) process has become one of the most dominant discharge sources of dioxins. A comprehensive discussion about dioxin formation mechanisms was reviewed in this paper, and the mechanisms of high-temperature gas-phase reaction and "de novo" synthesis were systematically illustrated in the form of diagrams. What's more, the effects of various influencing factors on the formation of PCDD/Fs were briefly analyzed in the form of a table. We believed that temperature, catalyst, chlorine source, carbon source, oxygen concentration and moisture were necessary factors for PCDD/Fs formation. Control technologies of dioxins in MSWI process were summarized subsequently from three stages: pre-combustion, in-combustion and post-combustion, and a device for synergistic removal of dioxins based on multi-field force coupling and technical routes for controlling dioxin emissions were proposed, so as to provide mechanisms and methods for effectively reducing the emission concentration of dioxins. An introduction was also conducted of dioxin control technologies in municipal solid waste incineration fly ash (MSWI-FA) in this paper, and their mechanisms, advantages, disadvantages and technical maturity were illustrated in the form of diagrams, which can provide theory and reference for in-depth research of follow-up scholars and industrial application of dioxin control technologies. Finally, current research hotspots, challenges and future research directions were proposed.Implications: In this paper, the main research contents and achievements are as follows: With the emphasis placed on the formation mechanism of dioxins and effects of various influencing factors on the formation of PCDD/Fs. The control technology of dioxins in MSWI process is summarized subsequently from three stages: pre-combustion, in-combustion and post-combustion.A device for synergistic removal of dioxins based on multi-field force coupling and technical routes for controlling dioxin emissions are proposed.A systematic review is conducted of the research progress on control technologies of dioxins in MSWI fly ash in the most recent years.The mechanisms, advantages, disadvantages and technical maturity of PCDD/Fs degradation technologies in MSWI fly ash are illustrated in the form of diagrams.Current research hotspots, challenges and future research directions are proposed. FAU - Zhao, Bowen AU - Zhao B AD - Hebei Key Laboratory of Power Plant Flue Gas Multi-Pollutants Control, Department of Environmental Science and Engineering, North China Electric Power University, Baoding, China. FAU - Hu, Xiude AU - Hu X AD - State Key Laboratory of High-efficiency Utilization of Coal and Green Chemical Engineering, Ningxia University, Yinchuan, China. FAU - Lu, Jianyi AU - Lu J AD - Hebei Key Laboratory of Power Plant Flue Gas Multi-Pollutants Control, Department of Environmental Science and Engineering, North China Electric Power University, Baoding, China. LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PT - Review PT - Systematic Review DEP - 20220805 PL - United States TA - J Air Waste Manag Assoc JT - Journal of the Air & Waste Management Association (1995) JID - 9503111 RN - 0 (Benzofurans) RN - 0 (Coal Ash) RN - 0 (Dibenzofurans) RN - 0 (Dibenzofurans, Polychlorinated) RN - 0 (Dioxins) RN - 0 (Polychlorinated Dibenzodioxins) RN - 0 (Solid Waste) RN - 4R7X1O2820 (Chlorine) RN - 7440-44-0 (Carbon) RN - S88TT14065 (Oxygen) SB - IM MH - *Benzofurans/analysis MH - Carbon MH - Chlorine/analysis MH - Coal Ash/analysis MH - Dibenzofurans/analysis MH - Dibenzofurans, Polychlorinated/analysis MH - *Dioxins/analysis MH - Incineration MH - Oxygen/analysis MH - Persistent Organic Pollutants MH - *Polychlorinated Dibenzodioxins/analysis MH - Solid Waste/analysis EDAT- 2022/07/12 06:00 MHDA- 2022/10/04 06:00 CRDT- 2022/07/11 12:32 PHST- 2022/07/12 06:00 [pubmed] PHST- 2022/10/04 06:00 [medline] PHST- 2022/07/11 12:32 [entrez] AID - 10.1080/10962247.2022.2100843 [doi] PST - ppublish SO - J Air Waste Manag Assoc. 2022 Oct;72(10):1063-1082. doi: 10.1080/10962247.2022.2100843. Epub 2022 Aug 5.