PMID- 35839989
OWN - NLM
STAT- MEDLINE
DCOM- 20220928
LR  - 20220928
IS  - 1879-1298 (Electronic)
IS  - 0045-6535 (Linking)
VI  - 307
IP  - Pt 1
DP  - 2022 Nov
TI  - Amorphous Co@TiO(2) heterojunctions: A high-performance and stable catalyst for 
      the efficient degradation of sulfamethazine via peroxymonosulfate activation.
PG  - 135681
LID - S0045-6535(22)02174-9 [pii]
LID - 10.1016/j.chemosphere.2022.135681 [doi]
AB  - Persulfate-based advanced oxidation processes (AOPs) cannot easily achieve the 
      efficient degradation of persistent organic pollutants (POPs) with high 
      stability. In this study, a simple in situ precipitation method was used to 
      prepare an amorphous Co@TiO(2) heterojunction catalyst. The deposition of Co 
      oxide on TiO(2), which is relatively nontoxic, efficiently activated 
      peroxymonosulfate (PMS) to degrade sulfamethazine (SMT) and reduce the leaching 
      of Co ions (0.915%). A catalytic system prepared using 0.3 g L(-1) Co@TiO(2) and 
      0.5 g L(-1) PMS could degrade SMT within 30 min with a degradation rate of 95.8%. 
      Co@TiO(2) could activate PMS over a wide pH range (5.00-9.00) to efficiently 
      degrade other antibiotics and dyes. Radical-capture experiments and electron 
      paramagnetic resonance analysis suggested that SMT degradation occurs through a 
      combination of the free radical and non-radical pathways, in which singlet 
      (1)O(2) played a major role. Owing to the novelty of the proposed composite 
      materials, the degradation path of SMT, which was determined through liquid 
      chromatography-mass spectrometry, differed from that reported previously. This 
      study provides not only an advanced and renewable catalyst for SMT degradation 
      but also a feasible strategy for designing materials for AOPs.
CI  - Copyright (c) 2022 Elsevier Ltd. All rights reserved.
FAU - Zhang, Yunqiu
AU  - Zhang Y
AD  - Institute for Ecological Research and Pollution Control of Plateau Lakes, School 
      of Ecology and Environmental Science, Yunnan University, Kunming, 650504, PR 
      China.
FAU - He, Zhuang
AU  - He Z
AD  - Institute for Ecological Research and Pollution Control of Plateau Lakes, School 
      of Ecology and Environmental Science, Yunnan University, Kunming, 650504, PR 
      China.
FAU - Zhou, Jing
AU  - Zhou J
AD  - Institute of Eco-environmental and Soil Sciences, Guangdong Academy of Sciences, 
      Guangzhou, 510650, PR China.
FAU - Huang, Yimin
AU  - Huang Y
AD  - Institute for Ecological Research and Pollution Control of Plateau Lakes, School 
      of Ecology and Environmental Science, Yunnan University, Kunming, 650504, PR 
      China.
FAU - Li, Wenyan
AU  - Li W
AD  - Joint Institute for Environmental Research and Education, College of Resources 
      and Environment, South China Agricultural University, Guangzhou, 510642, PR 
      China.
FAU - Li, Yongtao
AU  - Li Y
AD  - Joint Institute for Environmental Research and Education, College of Resources 
      and Environment, South China Agricultural University, Guangzhou, 510642, PR 
      China.
FAU - Li, Yuanxin
AU  - Li Y
AD  - Institute for Ecological Research and Pollution Control of Plateau Lakes, School 
      of Ecology and Environmental Science, Yunnan University, Kunming, 650504, PR 
      China.
FAU - Bi, Huilin
AU  - Bi H
AD  - Institute for Ecological Research and Pollution Control of Plateau Lakes, School 
      of Ecology and Environmental Science, Yunnan University, Kunming, 650504, PR 
      China.
FAU - Chang, Fengqin
AU  - Chang F
AD  - Institute for Ecological Research and Pollution Control of Plateau Lakes, School 
      of Ecology and Environmental Science, Yunnan University, Kunming, 650504, PR 
      China. Electronic address: changfq@ynu.edu.cn.
FAU - Zhang, Hucai
AU  - Zhang H
AD  - Institute for Ecological Research and Pollution Control of Plateau Lakes, School 
      of Ecology and Environmental Science, Yunnan University, Kunming, 650504, PR 
      China.
FAU - Hu, Guangzhi
AU  - Hu G
AD  - Institute for Ecological Research and Pollution Control of Plateau Lakes, School 
      of Ecology and Environmental Science, Yunnan University, Kunming, 650504, PR 
      China. Electronic address: guangzhihu@ynu.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20220712
PL  - England
TA  - Chemosphere
JT  - Chemosphere
JID - 0320657
RN  - 0 (Anti-Bacterial Agents)
RN  - 0 (Coloring Agents)
RN  - 0 (Peroxides)
RN  - 15FIX9V2JP (titanium dioxide)
RN  - 22047-43-4 (peroxymonosulfate)
RN  - 48U51W007F (Sulfamethazine)
RN  - D1JT611TNE (Titanium)
SB  - IM
MH  - Anti-Bacterial Agents/chemistry
MH  - Coloring Agents
MH  - Peroxides/chemistry
MH  - *Persistent Organic Pollutants
MH  - *Sulfamethazine/chemistry
MH  - Titanium
OTO - NOTNLM
OT  - Advance oxidation process
OT  - Amorphous heterostructure
OT  - Peroxymonosulfate activation
OT  - Sulfamethazine degradation
COIS- Declaration of competing interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2022/07/16 06:00
MHDA- 2022/09/28 06:00
CRDT- 2022/07/15 19:25
PHST- 2022/05/25 00:00 [received]
PHST- 2022/07/08 00:00 [revised]
PHST- 2022/07/10 00:00 [accepted]
PHST- 2022/07/16 06:00 [pubmed]
PHST- 2022/09/28 06:00 [medline]
PHST- 2022/07/15 19:25 [entrez]
AID - S0045-6535(22)02174-9 [pii]
AID - 10.1016/j.chemosphere.2022.135681 [doi]
PST - ppublish
SO  - Chemosphere. 2022 Nov;307(Pt 1):135681. doi: 10.1016/j.chemosphere.2022.135681. 
      Epub 2022 Jul 12.