PMID- 35870524 OWN - NLM STAT- MEDLINE DCOM- 20221229 LR - 20221229 IS - 1873-6424 (Electronic) IS - 0269-7491 (Linking) VI - 309 DP - 2022 Sep 15 TI - Effects of composite environmental materials on the passivation and biochemical effectiveness of Pb and Cd in soil: Analyses at the ex-planta of the Pak-choi root and leave. PG - 119812 LID - S0269-7491(22)01026-0 [pii] LID - 10.1016/j.envpol.2022.119812 [doi] AB - Passivation of soil heavy metals using environmental materials is an important method or important in situ remediation measure. There are more studies on inorganic environmental materials for heavy metal passivation, but not enough studies on organic and their composite environmental materials with inorganic ones. In order to reveal the passivation effect of coal-based ammoniated humic acid (CAHA), biochemical humic acid (BHA), biochar (BC) and other organic types and inorganic environmental materials such as zeolites (ZL) on soil heavy metals and their biological effectiveness. The microstructures of these materials were analyzed by Scanning electron microscope (SEM). The main components of the environmental materials were analyzed by Energy dispersive spectrometer (EDS), Fourier transforms infrared spectroscopy (FT-IR) and X-ray diffraction spectrum (XRD) to elucidate the mechanism of passivation of heavy metals in soil by these environmental materials. The study was conducted to investigate the effects of different types of environmental materials and their combinations on the passivation effect and biological effectiveness of Pb and Cd complex contamination in soil by means of soil incubation and pot experiments using single-factor and multifactor multilevel orthogonal experimental designs. Soil incubation experiments proved that the effective state of soil Pb and Cd in T(7) was reduced by 13.40% and 11.07%, respectively. The extreme difference analysis determined the optimized formulation of soil lead and cadmium passivation as BHA: CAHA: BC: ZL = 3.5:5:20:10. The pot experiment proved that the application of composite environmental materials led to the reduction of lead and cadmium content and increase of biomass of Pak-choi, and the optimal dosage of optimized composite environmental materials was 23.1 g/kg. CI - Copyright (c) 2022 Elsevier Ltd. All rights reserved. FAU - Wang, An AU - Wang A AD - School of Chemical and Environmental Engineering, China University of Mining and Technology-Beijing, Beijing, 100083, China. FAU - Wang, Yao AU - Wang Y AD - School of Chemical and Environmental Engineering, China University of Mining and Technology-Beijing, Beijing, 100083, China. FAU - Zhao, Peng AU - Zhao P AD - School of Chemical and Environmental Engineering, China University of Mining and Technology-Beijing, Beijing, 100083, China. FAU - Huang, Zhanbin AU - Huang Z AD - School of Chemical and Environmental Engineering, China University of Mining and Technology-Beijing, Beijing, 100083, China. Electronic address: zbhuang2003@163.com. LA - eng PT - Journal Article DEP - 20220720 PL - England TA - Environ Pollut JT - Environmental pollution (Barking, Essex : 1987) JID - 8804476 RN - 00BH33GNGH (Cadmium) RN - 16291-96-6 (Charcoal) RN - 0 (Coal) RN - 0 (Humic Substances) RN - 2P299V784P (Lead) RN - 0 (Metals, Heavy) RN - 0 (Soil) RN - 0 (Soil Pollutants) RN - 1318-02-1 (Zeolites) SB - IM MH - Cadmium/analysis MH - Charcoal MH - Coal/analysis MH - Humic Substances/analysis MH - Lead/analysis MH - *Metals, Heavy/analysis MH - Soil MH - *Soil Pollutants/analysis MH - Spectroscopy, Fourier Transform Infrared MH - *Zeolites OTO - NOTNLM OT - Biochemical effectiveness OT - Environmental materials OT - Humic acid OT - Pak-choi OT - Passivation EDAT- 2022/07/24 06:00 MHDA- 2022/08/17 06:00 CRDT- 2022/07/23 19:23 PHST- 2022/04/17 00:00 [received] PHST- 2022/06/09 00:00 [revised] PHST- 2022/07/16 00:00 [accepted] PHST- 2022/07/24 06:00 [pubmed] PHST- 2022/08/17 06:00 [medline] PHST- 2022/07/23 19:23 [entrez] AID - S0269-7491(22)01026-0 [pii] AID - 10.1016/j.envpol.2022.119812 [doi] PST - ppublish SO - Environ Pollut. 2022 Sep 15;309:119812. doi: 10.1016/j.envpol.2022.119812. Epub 2022 Jul 20.