PMID- 35919599
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20220805
IS  - 2046-2069 (Electronic)
IS  - 2046-2069 (Linking)
VI  - 12
IP  - 31
DP  - 2022 Jul 6
TI  - Study of the effect of in situ minerals on the pyrolysis of oil shale in Fushun, 
      China.
PG  - 20239-20250
LID - 10.1039/d2ra02822k [doi]
AB  - Herein, the effect of Fushun oil shale minerals on its kerogen has been 
      investigated. The samples were obtained under non-isothermal conditions at 
      different final temperatures. Scanning electron microscope (SEM) analysis 
      revealed that the silicates were layered and the carbonates were tightly bound to 
      each other. The combination of silicates and carbonates led to close combination 
      of minerals and organic matter and the organic matter was contained in the 
      minerals. The Brunner-Emmet-Teller (BET) experiments conclude that during the 
      non-isothermal pyrolysis process, the specific surface area increased, and then, 
      decreased, which proves the adsorption effect of silicates on oil shale pyrolysis 
      products and the adsorption effect of carbonates was weak. The activation energy 
      of four samples was calculated via Flynn-Wall-Ozawa (FWO) and Friedman kinetic 
      analysis under different heating rates in a non-isothermal process, wherein the 
      average activation energy of the sample containing silicate was 177.60 kJ mol(-1) 
      at minimum while that of carbonate was 250.45 kJ mol(-1) at maximum, which proves 
      that the catalytic promotion effect of silicate was greater than the inhibition 
      effect of carbonate. The pyrolysis products obtained by Flash pyrolysis-gas 
      chromatography-mass spectrometry (Py-GC/MS) under isothermal pyrolysis conditions 
      were primarily composed of aliphatic hydrocarbon structures, which had different 
      degrees of impact on the production of heteroatoms. This work provides a reliable 
      theoretical basis for future studies on the influence of minerals on pyrolysis of 
      organic matter in oil shale.
CI  - This journal is (c) The Royal Society of Chemistry.
FAU - Xinmin, Wang
AU  - Xinmin W
AD  - Engineering Research Centre of Oil Shale Comprehensive Utilization, Ministry of 
      Education, Northeast Electric Power University Jilin City Jilin 132012 China 
      rlx888@126.com.
FAU - Qing, Wang
AU  - Qing W
AUID- ORCID: 0000-0002-9840-6492
AD  - Engineering Research Centre of Oil Shale Comprehensive Utilization, Ministry of 
      Education, Northeast Electric Power University Jilin City Jilin 132012 China 
      rlx888@126.com.
FAU - Chunlei, Wu
AU  - Chunlei W
AD  - Engineering Research Centre of Oil Shale Comprehensive Utilization, Ministry of 
      Education, Northeast Electric Power University Jilin City Jilin 132012 China 
      rlx888@126.com.
LA  - eng
PT  - Journal Article
DEP - 20220713
PL  - England
TA  - RSC Adv
JT  - RSC advances
JID - 101581657
PMC - PMC9277521
COIS- There are no conflicts to declare.
EDAT- 2022/08/04 06:00
MHDA- 2022/08/04 06:01
PMCR- 2022/07/13
CRDT- 2022/08/03 02:10
PHST- 2022/05/04 00:00 [received]
PHST- 2022/07/04 00:00 [accepted]
PHST- 2022/08/03 02:10 [entrez]
PHST- 2022/08/04 06:00 [pubmed]
PHST- 2022/08/04 06:01 [medline]
PHST- 2022/07/13 00:00 [pmc-release]
AID - d2ra02822k [pii]
AID - 10.1039/d2ra02822k [doi]
PST - epublish
SO  - RSC Adv. 2022 Jul 13;12(31):20239-20250. doi: 10.1039/d2ra02822k. eCollection 
      2022 Jul 6.