PMID- 35919603 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20220805 IS - 2046-2069 (Electronic) IS - 2046-2069 (Linking) VI - 12 IP - 31 DP - 2022 Jul 6 TI - Dual determination of nitrite and iron by a single greener sequential injection spectrophotometric system employing a simple single aqueous extract from Areca catechu Linn. serving as a natural reagent. PG - 20110-20121 LID - 10.1039/d2ra03870f [doi] AB - Dual determination of nitrite and iron was proposed by using a single greener sequential injection (SI) spectrophotometric system employing a simple single aqueous extract from Areca catechu Linn. The extract served as a natural reagent to replace N-(1-naphthyl)ethylenediamine (NED) of the Griess reagent with nitrite and 1,10-phenanthroline with iron. The color products possessed analytical wavelengths at 430 and 560 nm, respectively. Conditions for the SI procedure were optimized using a univariate experimental design. Calibration ranges were up to 5.0 mg L(-1) and 10.0 mg L(-1) with limits of detection (LODs) of 0.04 mg L(-1) and 0.05 mg L(-1) for nitrite and iron(iii), respectively, and relative standard deviations (RSDs) being less than 3%. Recoveries of spiked standard nitrite and iron(iii) at 0.3 mg L(-1) and 0.5 mg L(-1) in water samples were 88 to 104% and 84 to 109%, respectively. The developed method successfully achieved dual determination of nitrite and total iron agreeing at a 95% confidence level with the reference methods of the conventional Griess assay and flame atomic absorption spectrometry (FAAS), respectively. The proposed method utilized locally available material from plants and serves the UN-SDGs. CI - This journal is (c) The Royal Society of Chemistry. FAU - Ponhong, Kraingkrai AU - Ponhong K AUID- ORCID: 0000-0002-6938-9208 AD - Multidisciplinary Research Unit of Pure and Applied Chemistry, Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahasarakham University Maha Sarakham 44150 Thailand. FAU - Siriangkhawut, Watsaka AU - Siriangkhawut W AUID- ORCID: 0000-0002-2409-7965 AD - Multidisciplinary Research Unit of Pure and Applied Chemistry, Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahasarakham University Maha Sarakham 44150 Thailand. FAU - Lee, Chang Young AU - Lee CY AUID- ORCID: 0000-0002-2757-8019 AD - School of Energy and Chemical Engineering, Ulsan National Institute of Science and Technology (UNIST) Ulsan 44919 Republic of Korea. FAU - Teshima, Norio AU - Teshima N AD - Department of Applied Chemistry, Aichi Institute of Technology 1247 Yachigusa, Yakusa-cho Toyota 470-0392 Japan. FAU - Grudpan, Kate AU - Grudpan K AD - Department of Chemistry, Faculty of Science and Center of Excellence for Innovation in Analytical Science and Technology for Biodiversity-based Economic and Society, Chiang Mai University Chiang Mai 50200 Thailand. FAU - Supharoek, Sam-Ang AU - Supharoek SA AD - Department of Medical Science, Mahidol University Amnatcharoen Campus Amnat Charoen 37000 Thailand. AD - Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Mahidol University Bangkok 10400 Thailand samang.sup@mahidol.ac.th. LA - eng PT - Journal Article DEP - 20220711 PL - England TA - RSC Adv JT - RSC advances JID - 101581657 PMC - PMC9272472 COIS- There are no conflicts to declare. EDAT- 2022/08/04 06:00 MHDA- 2022/08/04 06:01 PMCR- 2022/07/11 CRDT- 2022/08/03 02:10 PHST- 2022/06/23 00:00 [received] PHST- 2022/06/25 00:00 [accepted] PHST- 2022/08/03 02:10 [entrez] PHST- 2022/08/04 06:00 [pubmed] PHST- 2022/08/04 06:01 [medline] PHST- 2022/07/11 00:00 [pmc-release] AID - d2ra03870f [pii] AID - 10.1039/d2ra03870f [doi] PST - epublish SO - RSC Adv. 2022 Jul 11;12(31):20110-20121. doi: 10.1039/d2ra03870f. eCollection 2022 Jul 6.