PMID- 35931295 OWN - NLM STAT- MEDLINE DCOM- 20220929 LR - 20220929 IS - 1879-0003 (Electronic) IS - 0141-8130 (Linking) VI - 219 DP - 2022 Oct 31 TI - Effects of beeswax emulsified by octenyl succinate starch on the structure and physicochemical properties of acid-modified starchfilms. PG - 262-272 LID - S0141-8130(22)01675-0 [pii] LID - 10.1016/j.ijbiomac.2022.07.235 [doi] AB - This work aimed to develop a novel strategy to modulate the distribution of beeswax in acid-modified starch films via tuning octenyl succinate starch (OSS) ratios and to elucidate their structure-property relationships. The apparent viscosity and storage modulus of the film-forming solution decreased with the increase of OSS ratio. Attenuated total reflectance-fourier transform infrared (ATR-FTIR) spectroscopy revealed that the hydrogen bond in the film-forming network was cleaved with the presence of OSS. Scanning electron microscope (SEM), atomic force microscope (AFM), and X-ray diffraction (XRD) demonstrated that OSS ratio had an obvious effect on the formation and distribution of beeswax crystal particles. Uniform distribution of beeswax effectively enhanced the hydrophobicity and water barrier properties of films and performed preferable elongation at break but at the expense of tensile strength and optical properties. The films with higher OSS ratio (>12 %) presented higher thermal stability. This study provides new information on the rational design of emulsified films to obtain desirable physicochemical properties by tuning the distribution of beeswax. CI - Copyright (c) 2022 Elsevier B.V. All rights reserved. FAU - Liu, Ruiping AU - Liu R AD - College of Food Science and Engineering, Shandong Agricultural University, Engineering and Technology Center for Grain Processing of Shandong Province, Tai'an, PR China. FAU - Zhang, Rui AU - Zhang R AD - College of Food Science and Engineering, Shandong Agricultural University, Engineering and Technology Center for Grain Processing of Shandong Province, Tai'an, PR China. FAU - Zhai, Xiaosong AU - Zhai X AD - College of Food Science and Engineering, Shandong Agricultural University, Engineering and Technology Center for Grain Processing of Shandong Province, Tai'an, PR China. FAU - Li, Cheng AU - Li C AD - College of Food Science and Engineering, Shandong Agricultural University, Engineering and Technology Center for Grain Processing of Shandong Province, Tai'an, PR China. FAU - Hou, Hanxue AU - Hou H AD - College of Food Science and Engineering, Shandong Agricultural University, Engineering and Technology Center for Grain Processing of Shandong Province, Tai'an, PR China. FAU - Wang, Wentao AU - Wang W AD - College of Food Science and Engineering, Shandong Agricultural University, Engineering and Technology Center for Grain Processing of Shandong Province, Tai'an, PR China. Electronic address: wangwt@sdau.edu.cn. LA - eng PT - Journal Article DEP - 20220802 PL - Netherlands TA - Int J Biol Macromol JT - International journal of biological macromolecules JID - 7909578 RN - 0 (Succinates) RN - 0 (Waxes) RN - 059QF0KO0R (Water) RN - 28805-58-5 (octenyl succinate) RN - 2ZA36H0S2V (beeswax) RN - 9005-25-8 (Starch) SB - IM MH - Spectroscopy, Fourier Transform Infrared MH - *Starch/chemistry MH - Succinates MH - Tensile Strength MH - Water MH - *Waxes MH - X-Ray Diffraction OTO - NOTNLM OT - Acid-modified starch film OT - Beeswax OT - Octenyl succinate starch COIS- Declaration of competing interest The authors declare that they have no conflict of interest in the publication of this article. EDAT- 2022/08/06 06:00 MHDA- 2022/09/30 06:00 CRDT- 2022/08/05 19:26 PHST- 2022/05/27 00:00 [received] PHST- 2022/07/15 00:00 [revised] PHST- 2022/07/30 00:00 [accepted] PHST- 2022/08/06 06:00 [pubmed] PHST- 2022/09/30 06:00 [medline] PHST- 2022/08/05 19:26 [entrez] AID - S0141-8130(22)01675-0 [pii] AID - 10.1016/j.ijbiomac.2022.07.235 [doi] PST - ppublish SO - Int J Biol Macromol. 2022 Oct 31;219:262-272. doi: 10.1016/j.ijbiomac.2022.07.235. Epub 2022 Aug 2.