PMID- 35934023
OWN - NLM
STAT- MEDLINE
DCOM- 20220929
LR  - 20220929
IS  - 1879-1026 (Electronic)
IS  - 0048-9697 (Linking)
VI  - 849
DP  - 2022 Nov 25
TI  - Evaluation of sample preparation methods for suspect and non-target screening in 
      water, sediment, and biota samples using gas chromatography coupled to 
      high-resolution mass spectrometry.
PG  - 157835
LID - S0048-9697(22)04934-8 [pii]
LID - 10.1016/j.scitotenv.2022.157835 [doi]
AB  - In this study, the sample preparation methods were proposed for the suspect and 
      non-target screening (SNTS) using gas chromatography coupled to high-resolution 
      mass spectrometry in the aquatic environment. The pretreatment methods were 
      evaluated based on detection rates, recoveries, and screening detection limits 
      (SDLs) for 316 substances spiked into surface water, sediment, and biota samples. 
      The detection rates of the spiked compounds were 92.1 % and 98.7 % by the sample 
      preparation methods for water (solid-phase extraction using HLB cartridge) and 
      sediment (ultrasonic extraction (USE) with HLB cartridge clean-up), respectively. 
      Similarly, USE with HLB cartridge clean-up gave the highest detection rate (87.9 
      %) for biota samples; however, additional pretreatment method using deactivated 
      silica gel clean-up was necessary for the detection of persistent organic 
      pollutants (POPs). The SDL ranges of spiked compounds by the suggested 
      pretreatment methods were 0.01-23.5 ng/L for surface water, 0.02-37.5 ng/g dry 
      weight for sediment, and 0.01-12.2 ng/g wet weight for biota. Although some 
      pollutants, such as POPs had SDLs that were higher than the levels normally 
      detected in the aquatic environment as reported in previous studies, the 
      analytical methods suggested in the present study were satisfactory for the SNTS 
      of most pollutants originated from anthropogenic sources.
CI  - Copyright (c) 2022 Elsevier B.V. All rights reserved.
FAU - Sim, Wonjin
AU  - Sim W
AD  - Institute for Environment and Energy, Pusan National University, Busan 46241, 
      Republic of Korea. Electronic address: onejiny@pusan.ac.kr.
FAU - Choi, Sol
AU  - Choi S
AD  - Department of Civil and Environmental Engineering, Pusan National University, 
      Busan 46241, Republic of Korea.
FAU - Lee, Heon-Jun
AU  - Lee HJ
AD  - Department of Civil and Environmental Engineering, Pusan National University, 
      Busan 46241, Republic of Korea.
FAU - Kim, Kyungtae
AU  - Kim K
AD  - National Institute of Environmental Research, Incheon 22689, Republic of Korea. 
      Electronic address: pooh7231@korea.kr.
FAU - Park, Kyunghwa
AU  - Park K
AD  - National Institute of Environmental Research, Incheon 22689, Republic of Korea. 
      Electronic address: mirrorpark@korea.kr.
FAU - Oh, Jeong-Eun
AU  - Oh JE
AD  - Institute for Environment and Energy, Pusan National University, Busan 46241, 
      Republic of Korea; Department of Civil and Environmental Engineering, Pusan 
      National University, Busan 46241, Republic of Korea. Electronic address: 
      jeoh@pusan.ac.kr.
LA  - eng
PT  - Journal Article
DEP - 20220805
PL  - Netherlands
TA  - Sci Total Environ
JT  - The Science of the total environment
JID - 0330500
RN  - 0 (Environmental Pollutants)
RN  - 0 (Water Pollutants, Chemical)
RN  - 059QF0KO0R (Water)
RN  - 60650-90-0 (Silica Gel)
SB  - IM
MH  - Biota
MH  - *Environmental Pollutants/analysis
MH  - Gas Chromatography-Mass Spectrometry
MH  - Geologic Sediments/chemistry
MH  - Mass Spectrometry
MH  - Persistent Organic Pollutants
MH  - Silica Gel
MH  - Solid Phase Extraction
MH  - Water/analysis
MH  - *Water Pollutants, Chemical/analysis
OTO - NOTNLM
OT  - Biota
OT  - Gas chromatography coupled to high-resolution mass spectrometry
OT  - Sample preparation
OT  - Sediment
OT  - Suspect and non-target screening
OT  - Water
COIS- Declaration of competing interest The authors declare that they have no known 
      competing financial interests or personal relationships that could have appeared 
      to influence the work reported in this paper.
EDAT- 2022/08/08 06:00
MHDA- 2022/09/30 06:00
CRDT- 2022/08/07 19:32
PHST- 2022/06/23 00:00 [received]
PHST- 2022/07/31 00:00 [revised]
PHST- 2022/08/01 00:00 [accepted]
PHST- 2022/08/08 06:00 [pubmed]
PHST- 2022/09/30 06:00 [medline]
PHST- 2022/08/07 19:32 [entrez]
AID - S0048-9697(22)04934-8 [pii]
AID - 10.1016/j.scitotenv.2022.157835 [doi]
PST - ppublish
SO  - Sci Total Environ. 2022 Nov 25;849:157835. doi: 10.1016/j.scitotenv.2022.157835. 
      Epub 2022 Aug 5.